1,3-Dichloropropene, cis + trans

Hazard statements (CLP)

H225, H301+H311+H331, H304, H315, H317, H319, H334, H335, H341, H350, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid Colorless Chloroform-like Emergency Overview Highly flammable liquid and vapor. Toxic if swallowed. May be fatal if swallowed and enters airways. Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer. Classification of the substance or mixture Flammable liquids Category 2 Aspiration Toxicity Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 3 Acute Inhalation Toxicity - Vapors Category 3 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - (single exposure) Category 3 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity Category 1 Label Elements

Signal word

Danger Hazard Statements H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation H410 - Very toxic to aquatic life with long lasting effects H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H341 - Suspected of causing genetic defects H350 - May cause cancer H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection/ face protection P284 - In case of inadequate ventilation wear respiratory protection

Response

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Vapors may cause flash fire or explosion. Highly flammable.

Health hazards

Toxic if swallowed. Aspiration hazard if swallowed - can enter lungs and cause damage. Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Toxic if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer.

Environmental hazards

Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to terrestrial invertebrates. Toxicity to Soil Dwelling Organisms. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Flammable liquids. Category 2 Aspiration Toxicity Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 3 Acute Inhalation Toxicity - Vapors Category 3 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - (single exposure) Category 3 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity