AVM Top Coat Sealer 620-A

Hazard statements (CLP)

H226, H317, H319, H332, H334, H351, H372

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture GHS US classification Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation:dust,mist) H332 Eye Irrit. 2A H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 Carc. 2 H351 STOT RE 1 H372

2.2 Label elements

GHS US labeling

Signal word

Danger

Hazard statements

H226 - Flammable liquid and vapor H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause an allergy or asthma symptoms or breathing difficulties if inhaled H351 - Suspected of causing cancer H372 - Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe mist, spray. P261 - Avoid breathing spray, mist. P264 - Wash hands, forearms and face, clothing thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P280 - Wear eye protection, face protection, protective clothing, protective gloves 01/22/2021 AVM Top Coat Sealer 620-A Page 1 P284 - [In case of inadequate ventilation] wear respiratory protection. P302+P352 - If on skin: Wash with plenty of soap and water. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P304+P341 - If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a physician or poison control center if you feel unwell. P314 - Get medical advice/attention if you feel unwell. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a poison center or doctor. P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards which do not result in classification

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS US classification Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation:dust,mist) H332 Eye Irrit. 2A H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 Carc. 2 H351 STOT RE 1 H372 2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) : Signal word (GHS US) : Danger Hazard statements (GHS US) : H226 - Flammable liquid and vapor H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause an allergy or asthma symptoms or breathing difficulties if inhaled H351 - Suspected of causing cancer H372 - Causes damage to organs through prolonged or repeated exposure Precautionary statements (GHS US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe mist, spray. P261 - Avoid breathing spray, mist. P264 - Wash hands, forearms and face, clothing thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P280 - Wear eye protection, face protection, protective clothing, protective gloves 01/22/2021 AVM Top Coat Sealer 620-A Page 1 P284 - [In case of inadequate ventilation] wear respiratory protection. P302+P352 - If on skin: Wash with plenty of soap and water. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P304+P341 - If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a physician or poison control center if you feel unwell. P314 - Get medical advice/attention if you feel unwell. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a poison center or doctor. P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer (CAS-No.) 53880-05-0 50 - 100 Titanium dioxide (CAS-No.) 13463-67-7 10 - 30 Propylene carbonate (CAS-No.) 108-32-7 7 - 13 Solvent naphtha, petroleum, medium aliphatic (CAS-No.) 64742-88-7 5 - 10 Isophorone diisocyanate (CAS-No.) 4098-71-9 1 - 5 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : If exposed or concerned, get medical attention/advice. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use. Never give anything to an unconscious person. First-aid measures after inhalation : IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if breathing is affected. If breathing is difficult, supply oxygen. First-aid measures after skin contact : IF ON SKIN (or clothing): Remove affected clothing and wash all exposed skin with water for at least 15 minutes. If irritation develops or persists, get medical attention. First-aid measures after eye contact : IF IN EYES: Immediately flush with plenty of water for at least 15 minutes. Remove contact lenses if present and easy to do so. Continue rinsing if pain, blinking, or irritation develops or persists, get medical attention. Continue rinsing. First-aid measures after ingestion : IF SWALLOWED: rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Get medical attention if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. Suspected of causing cancer. May cause an allergy or asthma symptoms or breathing difficulties if inhaled. Causes serious eye irritation. Harmful if inhaled. May cause an allergic skin reaction. Symptoms/effects after inhalation : Harmful if inhaled. May cause an allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/effects after skin contact : Causes skin irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : May cause gastrointestinal irritation. 01/22/2021 AVM Top Coat Sealer 620-A 2/9 Chronic symptoms : Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure. 4.3. Immediate medical attention and special treatment, if necessary No additional information available SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Foam. Alcohol foam. Carbon dioxide (CO2). Dry chemical powder. Unsuitable extinguishing media : If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous. 5.2. Specific hazards arising from the chemical Fire hazard : Flammable liquid and vapor. Explosion hazard : Excessive pressure or temperature may cause explosive rupture of containers. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Exercise caution when fighting any chemical fire. Do not dispose of fire-fighting water in the environment. Prevent human exposure to fire, fumes, smoke and products of combustion. Use cold water spray to cool fire-exposed containers to minimize risk of rupture. Protection during firefighting : Wear positive pressure NIOSH self-containted breathing apparatus. Avoid breathing smoke, fumes, and decomposition products. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Evacuate area. Keep upwind. Ventilate area. Spill should be handled by trained clean-up crews properly equipped with respiratory equipment and full chemical protective gear (see Section 8). In case of spills, beware of slippery floors and surfaces. Eliminate all sources of ignition. 6.1.1. For non-emergency personnel Protective equipment : Wear Protective equipment as described in Section 8. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Approved supplied-air respirator, in case of emergency. 6.2. Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Do not touch or walk on the spilled product. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for cleaning up : Remove all sources of ignition. Avoid breathing of vapors. Wear appropriate respirator and other protective clothing. Ventilate. Shut off source of leak only if safe to do so. Soak up with absorbent material, and place in non-leaking containers for proper disposal. Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier's safety data sheets. Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose of in compliance with all relevant, local, state, and federal laws and regulations regarding treatment. 6.4. Reference to other sections No additional information available 01/22/2021 AVM Top Coat Sealer 620-A 3/9 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : When handling, personal protective equipment should be utilized (see sections 6 & 8). All articles of clothing and protective equipment that may have come in contact with the material should be removed prior to entering eating areas. Individuals with a history of skin sensitization should avoid areas in which the material is employed. Avoid contact with skin, eyes and clothing. Do not ingest, breath in vapor or mist, or release into environment. Utilize tightly closed containers to store the material when not in use, the containers can be the original container or an approved alternative made from compatible material. Containers should not be reused. Avoid formation of dust and aerosols. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep container securely sealed when not in use. Containers that have been opened must be carefully resealed to prevent leakage. Empty containers retain residue and may be dangerous. Use non-sparking ventilation systems, approved explosion proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Ground and bond containers and receiving equipment. Avoid static electricity by grounding. Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all structures, transfer container and equipment to conform to the national electrical code. Use procedures that prevent static electrical sparks. Static electricity may accumulate and create a fire hazard. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer (53880-05-0) ACGIH Remark (ACGIH) OELs not established OSHA Remark (OSHA) PELs not established Titanium dioxide (13463-67-7) ACGIH ACGIH TWA (mg/m³) 10 mg/m³ ACGIH Remark (ACGIH) LRT irr; A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans: The agent is carcinogenic in experimental animals at a relatively high dose, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) that may not be relevant to worker exposure. Available epidemiologic studies do not confirm an increased risk of cancer in exposed humans. Available evidence does not suggest that the agent is likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure) ACGIH Regulatory reference ACGIH 2018 OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ total dust OSHA Regulatory reference (US-OSHA) OSHA Propylene carbonate (108-32-7) OSHA Remark (OSHA) OELs not established AGGIH Remark (AGIH) OELs not established Solvent naphtha, petroleum, medium aliphatic (64742-88-7) OSHA Remark (OSHA) OELs not established ACGIH Remark (ACGIH) OELs not established Isophorone diisocyanate (4098-71-9) ACGIH ACGIH TWA (ppm) 0.005 ppm ACGIH Remark (ACGIH) TLV® Basis: Resp sens 01/22/2021 AVM Top Coat Sealer 620-A 4/9 8.2. Appropriate engineering controls Appropriate engineering controls : Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof equipment with flammable materials. Ensure adequate ventilation, especially in confined areas. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment symbol(s): Personal protective equipment: Gloves. Protective goggles. Protective clothing. Hand protection: Use gloves chemically resistant to this material when prolonged or repeated contact could occur. Gloves should be classified under Standard EN 374 or ASTM F1296. Suggested glove materials are: Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, PVC or vinyl. Eye protection: Chemical goggles or full face shields are recommended to pretect against splash of liquids. Skin and body protection: Avoid skin contact by wearing chemically resistant suit protecting against chemicals, chemically resistant gloves, a chemically resistant apron and other protective equipment depending upon conditions of use. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Inspect gloves and contact equipment for chemical break- through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Respiratory protection: Use NIOSH (or other equivalent national standard) -approved dust/particulate respirator. Where vapor, mist, or dust exceed PELs or other applicable OELs, use NIOSH-approved respiratory protective equipment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Viscous liquid. Color : White Odor : Mild chemical Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : 149 °C Flash point : 52 °C Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : Slower than ether Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 °C : Heavier than air Relative density : 1.09 Specific gravity / density : 9.07 lb/gal Solubility : Reacts with water. 01/22/2021 AVM Top Coat Sealer 620-A 5/9 Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information VOC content : 0.42 lb/gal SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Material is stable at standard temperature and pressure. 10.3. Possibility of hazardous reactions Will not occur under normal conditions but under high temperatures in the presence of alkalis, tertiary amines, and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers. 10.4. Conditions to avoid Heat, high temperature, open flame, sparks, moisture. Contact with incompatible materials in a closed system will cause liberation of carbon dioxide and buildup of pressure. 10.5. Incompatible materials This product with react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is slow under 50 °C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Material can react with strong oxidizing agents. 10.6. Hazardous decomposition products Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be formed during combustion. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Harmful if inhaled. Titanium dioxide (13463-67-7) LD50 oral rat > 10000 mg/kg Propylene carbonate (108-32-7) LD50 oral rat 29000 mg/kg (Source: IUCLID) LD50 dermal rabbit > 20 ml/kg (Source: NLM_CIP) Solvent naphtha, petroleum, medium aliphatic (64742-88-7) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit 3000 mg/kg LC50 Inhalation - Rat > 5.28 mg/l/4h Isophorone diisocyanate (4098-71-9) LD50 oral rat 1097 mg/kg LD50 dermal rabbit 1060 - 4780 mg/kg LC50 Inhalation - Rat 0.135 mg/l/4h (mist) Skin corrosion/irritation : Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. Causes mild skin irritation. Does not meet classification criteria. 01/22/2021 AVM Top Coat Sealer 620-A 6/9 Serious eye damage/irritation : Causes serious eye irritation. Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause conjunctivitis. Any level of contact should not be left untreated. Causes serious eye irritation Respiratory or skin sensitization : May cause an allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. Titanium dioxide (13463-67-7) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Not classified STOT-single exposure : Not classified STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Viscosity, kinematic : No data available Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. Suspected of causing cancer. May cause an allergy or asthma symptoms or breathing difficulties if inhaled. Causes serious eye irritation. Harmful if inhaled. May cause an allergic skin reaction. Symptoms/effects after inhalation : Harmful if inhaled. May cause an allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/effects after skin contact : Causes skin irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : May cause gastrointestinal irritation. Chronic symptoms : Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure. 0001333-86-4 CARBON BLACK CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon black for which there is inadequate human evidence, but sufficient animal evidence. Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function. SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Containers used for disposal of this material should be identified as waster and note the contents of the waste. Do not mix material with other waste containing strong oxidizing agents. Waste containers should be tightly sealed and kept away from high heat environments. Disposal of material should proceed in a manner which prevents environmental release into food sources, soil, waterways, drains and sewers. Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Do not allow the product to be released into the environment. Empty containers retain product residue which may exhibit hazards for material, therefore do not pressurize, cut, glaze, weld, or use for other purposes. Return drums to reclamation centers for proper cleaning and reuse. 01/22/2021 AVM Top Coat Sealer 620-A 7/9 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1263 Paint, 3, III UN-No.(DOT) : UN1263 Proper Shipping Name (DOT) : Paint Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : III - Minor Danger Hazard labels (DOT) : 3 - Flammable liquid DOT Quantity Limitations Passenger aircraft/rail : 60 L (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 : 220 L CFR 175.75) DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. Emergency Response Guide (ERG) Number : 128 Other information : No supplementary information available. Transportation of Dangerous Goods Not applicable Transport by sea (IMDG) Transport document description (IMDG) : UN 1263 PAINT, 3, III UN-No. (IMDG) : 1263 Proper Shipping Name (IMDG) : PAINT Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : III - substances presenting low danger Limited quantities (IMDG) : 5 L Air transport (IATA) Transport document description (IATA) : UN 1263 Paint, 3, III UN-No. (IATA) : 1263 Proper Shipping Name (IATA) : Paint Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : III - Minor Danger SECTION 15: Regulatory information 15.1. US Federal regulations AVM Top Coat Sealer 620-A All chemical substances in this product are listed as “Active” in the EPA (Environmental Protection Agency) “TSCA Inventory Notification (Active- Inactive) Requirements Rule” (“the Final Rule”). as of Feb. 2019 or are otherwise exempt. SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids) Health hazard - Serious eye damage or eye irritation Health hazard - Respiratory or skin sensitization Health hazard - Specific target organ toxicity (single or repeated exposure) Health hazard - Carcinogenicity 15.2. International regulations No additional information available 01/22/2021 AVM Top Coat Sealer 620-A 8/9 15.3. US State regulations