MOBIL JET OIL II

SECTION 2: Hazards identification

2.2 Label elements

Not a hazardous substance or mixture.

2.3 Other hazards

None known.

2.1 Classification of the substance or mixture

1910.1200) Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Components Chemical name CAS-No. Concentration (% w/w) Tricresyl phosphate 1330-78-5 >= 1 - < 5 Eastman is committed to the safety, health and environment of our employees, our customers, and the communities we operate within. As part of this commitment, Eastman's Safety Data Sheets (SDS) are prepared in accordance with all applicable national and local regulations. The compositions of our documents reflect these requirements which include, but are not limited to, requirements under the Globally Harmonized System of Classification and Labeling (GHS). These compositions commonly involve the use of ranges versus specific analytical values. If you require a composition that is more 1 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 specific , please refer to the Certificate of Analysis, sales specification, or contact your Customer Service Representative. SECTION 4. FIRST AID MEASURES If inhaled : Move to fresh air. If breathing is difficult, give oxygen. Consult a physician if necessary. In case of skin contact : Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before reuse. If symptoms persist, call a physician. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if symptoms occur. If swallowed : Rinse mouth. Call a physician or poison control center immediately. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Most important symptoms : Prolonged skin contact may defat the skin and produce der- and effects, both acute and matitis. delayed Contact with hot product will cause thermal burns. Inhalation of thermal decomposition products may lead to adverse effects including pulmonary edema. Notes to physician : Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Foam Dry powder Carbon dioxide (CO2) Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread media fire. Hazardous combustion prod- : Carbon monoxide ucts Carbon dioxide (CO2) Oxides of phosphorus Further information : In case of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment : Wear an approved positive pressure self-contained breathing 2 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 for fire-fighters apparatus in addition to standard fire fighting gear. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : Ventilate the area. tive equipment and emer- Material can create slippery conditions. gency procedures Use personal protective equipment. Local authorities should be advised if significant spillages cannot be contained. Environmental precautions : Avoid release to the environment. Methods and materials for : Contain spillage, soak up with non-combustible absorbent containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Do not get in eyes. Do not get on skin or clothing. Wash thoroughly after handling. Do not breathe vapors or spray mist. Use only in area provided with appropriate exhaust ventilation. Drain or remove substance from equipment prior to break-in or maintenance. Wear appropriate personal protective equipment. Conditions for safe storage : Keep containers tightly closed in a cool, well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. 3 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Hand protection Material : Recommended gloves: Material : Nitrile rubber Remarks : Wear suitable gloves. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Eye protection : Wear safety glasses with side shields (or goggles). Protective measures : Ensure that eye flushing systems and safety showers are located close to the working place. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : amber Odor : No data available Odor Threshold : not determined pH : not determined Melting point/freezing point : -65 °F / -54 °C Boiling point/boiling range : not determined Flash point : 475 °F / 246 °C Method: Cleveland open cup Evaporation rate : not determined Flammability (solid, gas) : Not applicable Upper explosion limit / Upper : not determined flammability limit Lower explosion limit / Lower : not determined flammability limit Vapor pressure : not determined Relative vapor density : not determined 4 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Relative density : 0.997 Solubility(ies) Water solubility : insoluble Partition coefficient: n- : octanol/water No data available Autoignition temperature : not determined Decomposition temperature : not determined Viscosity Viscosity, dynamic : not determined Viscosity, kinematic : 26 mm2/s (104 °F / 40 °C) 5.19 mm2/s (212 °F / 100 °C) Explosive properties : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : None reasonably foreseeable. Chemical stability : Stable under normal conditions. Conditions to avoid : Keep away from sources of ignition - No smoking. Incompatible materials : Strong oxidizing agents Hazardous decomposition : Emits acrid smoke and fumes when heated to decomposition. products SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate (Rat): > 5,000 mg/kg Assessment: Not classified Remarks: Read-across from a similar material Acute inhalation toxicity : Acute toxicity estimate (Expert judgment): Exposure time: 4 h Assessment: Not classified Remarks: Read-across from a similar material Acute dermal toxicity : Acute toxicity estimate (Expert judgment): Assessment: Not 5 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 classified Remarks: Read-across from a similar material Components: Tricresyl phosphate: Acute oral toxicity : LD50 Oral (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.2 mg/l Exposure time: 4 h Acute dermal toxicity : LD50 Dermal (Rabbit): > 10,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Species : Rabbit Assessment : Not classified as hazardous. Result : slight Components: Tricresyl phosphate: Species : Rabbit Exposure time : 24 h Assessment : Not classified as hazardous. Result : Non-irritating to the skin. Serious eye damage/eye irritation Not classified based on available information. Product: Species : Rabbit Result : slight Assessment : Not classified Remarks : Read-across from a similar material Components: Tricresyl phosphate: Species : Rabbit Assessment : Not classified Respiratory or skin sensitization Skin sensitization Not classified based on available information. Respiratory sensitization Not classified based on available information. 6 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Product: Test Type : Skin Sensitization Species : Humans Assessment : Not classified Method : Human Repeat Insult Patch Test Result : non-sensitizing Remarks : Read-across from a similar material Components: Tricresyl phosphate: Test Type : Skin Sensitization Assessment : Not classified Germ cell mutagenicity Not classified based on available information. Product: Genotoxicity in vitro : Test Type: various Metabolic activation: Read-across from a similar material Result: Based on available data, the classification criteria are not met. Genotoxicity in vivo : Test Type: Mutagenicity Result: Based on available data, the classification criteria are not met. Remarks: Read-across from a similar material Components: Tricresyl phosphate: Genotoxicity in vitro : Test Type: various Result: Based on available data, the classification criteria are not met. Remarks: Not classified Genotoxicity in vivo : Test Type: various Result: Based on available data, the classification criteria are not met. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. Product: Effects on fertility : Remarks: No data available Reproductive toxicity - As- : No toxicity to reproduction sessment 7 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Components: Tricresyl phosphate: Reproductive toxicity - As- : May damage the unborn child. Suspected of damaging sessment fertility. STOT-single exposure Not classified based on available information. Product: Assessment : Based on available data, the classification criteria are not met. Components: Tricresyl phosphate: Assessment : Based on available data, the classification criteria are not met. STOT-repeated exposure Not classified based on available information. Product: Assessment : Based on available data, the classification criteria are not met. Components: Tricresyl phosphate: Assessment : Based on available data, the classification criteria are not met. Repeated dose toxicity Product: Remarks : No known significant effects or critical hazards. Components: Tricresyl phosphate: Species : Rat : 300 mg/l Aspiration toxicity Not classified based on available information. Product: Not classified Components: Tricresyl phosphate: Not classified 8 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Experience with human exposure Product: Inhalation : Remarks: None known. Skin contact : Remarks: No data available Eye contact : Remarks: No data available Ingestion : Remarks: None known. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : LC50 (Fish): Exposure time: 96 h Remarks: Not classified as hazardous. (limit of solubility in fresh water) Read-across from a similar material Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): aquatic invertebrates Exposure time: 48 h Remarks: Not classified as hazardous. (limit of solubility in fresh water) Read-across from a similar material Toxicity to algae/aquatic : NOEC (Pseudokirchneriella subcapitata (algae)): plants Exposure time: 72 h Remarks: Not classified as hazardous. (limit of solubility in fresh water) Read-across from a similar material Toxicity to fish (Chronic tox- : NOEC (Fish): icity) Remarks: Not classified as hazardous. (limit of solubility in fresh water) Read-across from a similar material Toxicity to daphnia and other : NOEC: aquatic invertebrates (Chron- Remarks: Not classified as hazardous. ic toxicity) (limit of solubility in fresh water) Read-across from a similar material Components: Tricresyl phosphate: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.6 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.146 mg/l aquatic invertebrates Exposure time: 48 h 9 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 M-Factor (Acute aquatic tox- : 1 icity) Persistence and degradability Product: Biodegradability : Result: Readily biodegradable. Biodegradation: 92.36 % Exposure time: 28 d Biochemical Oxygen De- : Remarks: No data available mand (BOD) Chemical Oxygen Demand : Remarks: No data available (COD) BOD/COD : Remarks: No data available Bioaccumulative potential Product: Bioaccumulation : Remarks: Mixture Not applicable Components: Tricresyl phosphate: Bioaccumulation : Bioconcentration factor (BCF): 2,000 Partition coefficient: n- : Pow: 860,000 octanol/water log Pow: 5.93 Mobility in soil Components: Tricresyl phosphate: Distribution among environ- : log Koc: 4.31 mental compartments Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. 10 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good Special precautions for user Not applicable SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity Components CAS-No. Component TPQ (lbs) SARA 311/312 Hazards : No SARA Hazards SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: TCSI : On the inventory, or in compliance with the inventory TSCA : All substances listed as active on the TSCA inventory AIIC : On the inventory, or in compliance with the inventory DSL : This product contains one or several components listed in the Canadian NDSL. ENCS : On the inventory, or in compliance with the inventory 11 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 NZIoC : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TSCA list No substances are subject to TSCA 12(b) export notification requirements. The following substance(s) is/are subject to a Significant New Use Rule: Amines, bis(C11-14-branched and linear alkyl) 900169-60-0 No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Further information NFPA 704: HMIS® IV: Flammability HEALTH / 1 FLAMMABILITY 1 Health 1 Instability 0 PHYSICAL HAZARD 0 HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz- ards or risks, and 4 representing signifi- cant hazards or risks. The "*" represents Special hazard a chronic hazard, while the "/" represents the absence of a chronic hazard. Full text of other abbreviations AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals 12 / 13 Eastman(TM) Turbo Oil 2197 Version Revision Date: SDS Number: Date of last issue: 07/02/2020 1.5 01/12/2023 150000097791 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza- tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi- cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre- vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth- erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern- ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Sources of key data used to : www.EastmanAviationSolutions.com compile the Material Safety Data Sheet Revision Date : 01/12/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8 13 / 13 ARITR-24-002 SDS – Skydrol PE 5 NAVAIR Public Release 2024-0350. DISTRIBUTION STATEMENT A - Approved for public release; distribution is unlimited. Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 SECTION 1. IDENTIFICATION Product name : Skydrol® PE-5 Product code : 34103-00, P3410305, P3410304, P3410302, P3410301, P3410306, P3410313, P3410312, P3410303, P3410311, P3410309, E3410301 Manufacturer or supplier's details Company name of supplier : Eastman Chemical Company Address : 200 South Wilcox Drive Kingsport TN 37660-5280 Telephone : (423) 229-2000 Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321 Recommended use of the chemical and restrictions on use Recommended use : Hydraulic fluids Restrictions on use : The Environmental Protection Agency prohibits processing and distribution of this chemical/product for any use other than: (1) In hydraulic fluids either for the aviation industry or to meet military specifications for safety and performance where no alternative chemical is available that meets U.S. Depart- ment of Defense specification requirements, (2) lubricants and greases, (3) new or replacement parts for motor and aero- space vehicles, (4) as an intermediate in the manufacture of cyanoacrylate glue, (5) in specialised engine air filters for lo- comotive and marine applications, and (6) in adhesives and sealants before January 6, 2025, after which use in adhesives and sealants is prohibited. In addition, all persons are prohib- ited from releasing PIP (3:1) to water during manufacturing, processing and distribution in commerce, and must follow all existing regulations and best practices to prevent the release of PIP (3:1) to water during the commercial use of PIP (3:1). SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity (Oral) : Category 4 Skin irritation : Category 2 Carcinogenicity : Category 2 1 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Reproductive toxicity (Oral) : Category 2 Specific target organ toxicity : Category 2 (Adrenal gland) - repeated exposure GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : H302 Harmful if swallowed. H315 Causes skin irritation. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child if swallowed. H373 May cause damage to organs (Adrenal gland) through prolonged or repeated exposure. Precautionary Statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P362 Take off contaminated clothing and wash before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards None known. 2 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Components Chemical name CAS-No. Concentration (% w/w) Tributyl phosphate 126-73-8 58 - 68 Triisobutyl phosphate 126-71-6 8 - 10 Phenol, isopropylated, phosphate 68937-41-7 5 - < 10 (3:1) triphenylphosphate 115-86-6 1.3 - 1.9 7-Oxabicyclo[4.1.0]heptane-3- 62256-00-2 5.5 - 6.5 carboxylic acid, 2-ethylhexyl ester butylated hydroxytoluene 128-37-0 0.1 - 1 SECTION 4. FIRST AID MEASURES If inhaled : Move to fresh air. Call a physician or poison control center immediately. In case of skin contact : Wash off with soap and plenty of water. Wash contaminated clothing before re-use. Get medical attention. Thoroughly clean shoes before reuse. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed : Seek medical advice. Most important symptoms : Harmful if swallowed. and effects, both acute and Causes skin irritation. delayed Suspected of causing cancer. Suspected of damaging fertility or the unborn child if swal- lowed. May cause damage to organs through prolonged or repeated exposure. Notes to physician : Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Carbon dioxide (CO2) Dry chemical Water spray Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread media fire. Hazardous combustion prod- : Carbon monoxide ucts Carbon dioxide (CO2) oxides of phosphorus 3 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Further information : None known. Special protective equipment : Wear an approved positive pressure self-contained breathing for fire-fighters apparatus in addition to standard fire fighting gear. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : Wear appropriate personal protective equipment. tive equipment and emer- Avoid breathing mist or vapors. gency procedures Local authorities should be advised if significant spillages cannot be contained. Environmental precautions : Prevent further leakage or spillage if safe to do so. Clear up spills immediately and dispose of waste safely. Avoid release to the environment. Methods and materials for : Prevent runoff from entering drains, sewers, or streams. containment and cleaning up Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against : None known. fire and explosion Advice on safe handling : Avoid inhalation of vapor or mist. Do not get on skin or clothing. Avoid contact with skin, eyes and clothing. Do not swallow. Ensure adequate ventilation. Wash thoroughly after handling. Conditions for safe storage : Keep tightly closed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Components CAS-No. Value type Control parame- Basis (Form of ters / Permissible exposure) concentration Tributyl phosphate 126-73-8 TWA (Inhal- 5 mg/m3 ACGIH able fraction and vapor) TWA 0.2 ppm NIOSH REL 2.5 mg/m3 TWA 5 mg/m3 OSHA Z-1 TWA 0.2 ppm OSHA P0 2.5 mg/m3 triphenylphosphate 115-86-6 TWA 3 mg/m3 ACGIH 4 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 TWA 3 mg/m3 NIOSH REL TWA 3 mg/m3 OSHA Z-1 TWA 3 mg/m3 OSHA P0 Engineering measures : Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Hand protection Remarks : Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations. Eye protection : Wear safety glasses with side shields (or goggles). Skin and body protection : Wear suitable protective clothing. Protective measures : Remove respiratory and skin/eye protection only after vapors have been cleared from the area. Ensure that eye flushing systems and safety showers are located close to the working place. Use personal protective equipment as required. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : oily 5 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Color : purple Odor : odorless Odor Threshold : not determined pH : not determined Melting point/range : < -80 °F / -62 °C Boiling point/boiling range : not determined Flash point : 340 °F / 171 °C Method: Cleveland open cup Evaporation rate : not determined Flammability (solid, gas) : Not applicable Upper explosion limit / Upper : not determined flammability limit Lower explosion limit / Lower : not determined flammability limit Vapor pressure : 0.4 hPa (77 °F / 25 °C) Relative vapor density : not determined Relative density : 0.9956 (77 °F / 25 °C) Density : 995 kg/m3 (77 °F / 25 °C) Autoignition temperature : 795 °F / 424 °C Method: ASTM D2155 Decomposition temperature : not determined Viscosity Viscosity, dynamic : not determined Viscosity, kinematic : 9.02 - 10.02 mm2/s (100 °F / 38 °C) Explosive properties : Not classified Oxidizing properties : Not classified SECTION 10. STABILITY AND REACTIVITY 6 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Reactivity : None reasonably foreseeable. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Stable tions Conditions to avoid : None known. Incompatible materials : Strong oxidizing agents Hazardous decomposition : Carbon dioxide (CO2) products Carbon monoxide SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Harmful if swallowed. Product: Acute oral toxicity : Remarks: Harmful if swallowed. Acute inhalation toxicity : Remarks: No significant adverse effects were reported Acute dermal toxicity : Remarks: No significant adverse effects were reported Components: Tributyl phosphate: Acute oral toxicity : LD50 Oral (Rat, male and female): 1,553 mg/kg Assessment: Harmful if swallowed. LD50 Oral (Rat, male and female): 1,400 mg/kg Acute inhalation toxicity : LC50 (Rat, male and female): > 4.242 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala- tion toxicity Acute dermal toxicity : LD50 Dermal (Rabbit, male and female): > 3,100 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Triisobutyl phosphate: Acute inhalation toxicity : LC50 (Rat): > 5.14 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala- tion toxicity Acute dermal toxicity : LD50 Dermal (Rabbit): > 5,000 mg/kg 7 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Assessment: The substance or mixture has no acute dermal toxicity Phenol, isopropylated, phosphate (3:1): Acute oral toxicity : LD50 Oral (Rat): > 5,000 mg/kg Assessment: The substance or mixture has no acute oral tox- icity Acute inhalation toxicity : LC50 (Rat): > 200 mg/m3 Exposure time: 1 h Assessment: The substance or mixture has no acute inhala- tion toxicity Acute dermal toxicity : LD50 Dermal (Rabbit): > 10,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity triphenylphosphate: Acute oral toxicity : LD50 Oral (Rat, male): > 6,400 mg/kg Acute dermal toxicity : LD50 Dermal (Guinea pig, male): > 5,000 mg/kg 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Acute oral toxicity : LD50 Oral (Rat, male and female): 4,470 mg/kg Acute dermal toxicity : LD50 Dermal (Rabbit, male and female): > 7,940 mg/kg butylated hydroxytoluene: Acute oral toxicity : LD50 Oral (Rat): > 6,000 mg/kg Acute dermal toxicity : LD50 Dermal (Guinea pig): > 20,000 mg/kg Skin corrosion/irritation Causes skin irritation. Product: Remarks : Causes skin irritation. Components: Tributyl phosphate: Species : Rabbit Exposure time : 4 h Assessment : Causes skin irritation. Result : irritating Triisobutyl phosphate: Species : Rabbit Exposure time : 4 h 8 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Result : Mild skin irritation Phenol, isopropylated, phosphate (3:1): Species : Rabbit Assessment : Not classified triphenylphosphate: Species : Guinea pig Remarks : Non-irritating to the skin. 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Species : Rabbit Exposure time : 24 h Assessment : Not classified as hazardous. Result : slight to moderate irritation butylated hydroxytoluene: Species : Rabbit Exposure time : 24 h Result : very slight Serious eye damage/eye irritation Not classified based on available information. Components: Tributyl phosphate: Species : Rabbit Result : slight irritation Exposure time : 24 h Assessment : Not classified Triisobutyl phosphate: Species : Rabbit Result : slight Assessment : Not classified Phenol, isopropylated, phosphate (3:1): Species : Rabbit Result : none Assessment : Not classified triphenylphosphate: Species : Rabbit Result : slight 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Species : Rabbit 9 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Result : slight irritation Exposure time : 24 h Assessment : Not classified butylated hydroxytoluene: Species : Rabbit Result : none Respiratory or skin sensitization Skin sensitization Not classified based on available information. Respiratory sensitization Not classified based on available information. Product: Test Type : OECD 429: LLNA Species : Mouse Result : Not a skin sensitizer. Components: Tributyl phosphate: Test Type : Skin Sensitization Species : Guinea pig Assessment : Not classified Result : Does not cause skin sensitization. Test Type : Skin Sensitization Species : Humans Assessment : Not classified Result : Does not cause skin sensitization. Triisobutyl phosphate: Test Type : OECD 406: Guinea pig sensitization Species : Guinea pig Method : OECD 406: Guinea pig sensitization Result : May cause sensitization by skin contact. 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Test Type : Skin Sensitization Species : Guinea pig Result : May cause sensitization by skin contact. butylated hydroxytoluene: Test Type : Skin sensitization Species : Guinea pig Result : non-sensitizing 10 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Germ cell mutagenicity Not classified based on available information. Components: Tributyl phosphate: Genotoxicity in vitro : Test Type: Mutagenicity - Bacterial Metabolic activation: +/- activation Method: Bacterial Reverse Mutation Assay Result: negative Test Type: Mutagenicity - Mammalian Metabolic activation: +/- activation Method: In vitro Mammalian Chromosome Aberration Test Result: equivocal Genotoxicity in vivo : Species: Rat (male and female) Application Route: oral: gavage Method: Mammalian Bone Marrow Chromosome Aberration Test Result: negative Triisobutyl phosphate: Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test) Metabolic activation: +/- activation Method: Bacterial Reverse Mutation Assay Result: negative Genotoxicity in vivo : Result: negative 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Genotoxicity in vitro : Test Type: Salmonella typhimurium assay (Ames test) Metabolic activation: +/- activation Method: Bacterial Reverse Mutation Assay Result: negative Test Type: Mutagenicity - Mammalian Metabolic activation: +/- activation Method: In vitro Mammalian Chromosome Aberration Test Result: equivocal Test Type: Mutagenicity - Mammalian Metabolic activation: +/- activation Method: In vitro Mammalian Cell Gene Mutation Test Result: negative Genotoxicity in vivo : Species: Rat (male and female) Application Route: intraperitoneal injection Method: Mammalian Bone Marrow Chromosome Aberration Test Result: equivocal 11 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Carcinogenicity Suspected of causing cancer. Components: Tributyl phosphate: Species : Rat, male and female Application Route : Ingestion Method : EPA OTS 798.3300 Remarks : Limited evidence of a carcinogenic effect. May cause cancer. IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Suspected of damaging fertility or the unborn child if swallowed. Components: Phenol, isopropylated, phosphate (3:1): Effects on fertility : Species: Rat, male and female Application Route: Oral General Toxicity Parent: NOAEL: 25 milligram per kilogram Remarks: Suspected of damaging fertility or the unborn child. triphenylphosphate: Reproductive toxicity - As- : Based on available data, the classification criteria are not met. sessment STOT-single exposure Not classified based on available information. Components: Tributyl phosphate: Assessment : Based on available data, the classification criteria are not met. Triisobutyl phosphate: Assessment : Not classified Phenol, isopropylated, phosphate (3:1): Remarks : Not classified due to data which are conclusive although insuf- ficient for classification. 12 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 STOT-repeated exposure May cause damage to organs (Adrenal gland) through prolonged or repeated exposure. Components: Tributyl phosphate: Assessment : Based on available data, the classification criteria are not met. Triisobutyl phosphate: Assessment : Not classified Phenol, isopropylated, phosphate (3:1): Assessment : May cause damage to organs through prolonged or repeated exposure. Repeated dose toxicity Components: Tributyl phosphate: Species : Mouse, male and female : 75 mg/kg Application Route : in feed Exposure time : 90 days Triisobutyl phosphate: Species : Rat, male : 68.4 mg/kg Application Route : Oral Study Exposure time : 90 days Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components: Triisobutyl phosphate: Not classified 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Not applicable Routes of exposure Product: Inhalation : Remarks: May cause damage to organs through prolonged or 13 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 repeated exposure. Skin contact : Remarks: Causes skin irritation. Eye contact : Remarks: None known. Ingestion : Remarks: Harmful if swallowed. Further information Product: Remarks : None known. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Tributyl phosphate: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 4.2 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.8 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic : EC50 (Desmodesmus subspicatus (green algae)): 1.1 mg/l plants Exposure time: 72 h Toxicity to fish (Chronic tox- : NOEC (Oncorhynchus mykiss (rainbow trout)): 0.82 mg/l icity) Exposure time: 95 d 1.7 mg/l Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 1.3 mg/l aquatic invertebrates (Chron- Exposure time: 21 d ic toxicity) Triisobutyl phosphate: Toxicity to fish : EC50 (Danio rerio (zebra fish)): > 12.6 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 24 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic : ErC50 (Pseudokirchneriella subcapitata (algae)): 14.3 mg/l plants Exposure time: 72 h EC10 (Pseudokirchneriella subcapitata (algae)): 10.4 mg/l Exposure time: 72 h 14 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Phenol, isopropylated, phosphate (3:1): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.36 mg/l Exposure time: 96 h LC50 (Cyprinodon variegatus (sheepshead minnow)): > 1.3 mg/l Exposure time: 96 h Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 1 mg/l aquatic invertebrates Exposure time: 48 h LC50 (Mysidopsis bahia (opossum shrimp)): > 1 mg/l Toxicity to algae/aquatic : NOEC (Desmodesmus subspicatus (green algae)): 0.25 - 2.5 plants mg/l Exposure time: 72 h Test Type: Alga, Growth Inhibition Test M-Factor (Acute aquatic tox- : 1 icity) M-Factor (Chronic aquatic : 1 toxicity) triphenylphosphate: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.4 mg/l Exposure time: 96 h Toxicity to daphnia and other : LC50 (Americamysis): > 0.18 - < 0.32 mg/l aquatic invertebrates Exposure time: 96 h Toxicity to algae/aquatic : NOEC (Pseudokirchneriella subcapitata (algae)): 0.25 mg/l plants Exposure time: 72 h Toxicity to fish (Chronic tox- : EC10 (Oncorhynchus mykiss (rainbow trout)): 0.037 mg/l icity) Exposure time: 30 d Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.254 mg/l aquatic invertebrates (Chron- Exposure time: 21 d ic toxicity) 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.9 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 6.5 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic : ErC50 (Pseudokirchneriella subcapitata (algae)): 2.6 mg/l plants Exposure time: 72 h NOEC (Pseudokirchneriella subcapitata (algae)): 0.11 mg/l Exposure time: 72 h 15 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Toxicity to microorganisms : EC50: 2.6 mg/l Exposure time: 72 h butylated hydroxytoluene: Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 0.57 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.48 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (algae)): > 0.24 mg/l plants Exposure time: 72 h NOEC (Pseudokirchneriella subcapitata (algae)): 0.24 mg/l Exposure time: 72 h Toxicity to fish (Chronic tox- : NOEC (Oryzias latipes (Orange-red killifish)): 0.053 mg/l icity) Exposure time: 30 d Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.069 mg/l aquatic invertebrates (Chron- Exposure time: 21 d ic toxicity) Persistence and degradability Components: Tributyl phosphate: Biodegradability : Result: Readily biodegradable. Triisobutyl phosphate: Biodegradability : Result: Readily biodegradable. Biodegradation: 70 - 80 % Exposure time: 28 d Method: Ready Biodegradability: CO2 Evolution Test Phenol, isopropylated, phosphate (3:1): Biodegradability : Remarks: Not readily biodegradable. triphenylphosphate: Biodegradability : Result: Readily biodegradable. 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 2-ethylhexyl ester: Biodegradability : Concentration: 100 mg/l Method: Ready Biodegradability: Modified MITI Test (I) Remarks: Readily biodegradable 16 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Bioaccumulative potential Components: Tributyl phosphate: Bioaccumulation : Species: Cyprinus carpio (Carp) Bioconcentration factor (BCF): 20 Exposure time: 56 d Method: OECD Test Guideline 305 Bioconcentration factor (BCF): 35 Exposure time: 38 d Partition coefficient: n- : Pow: 10,100 octanol/water Triisobutyl phosphate: Bioaccumulation : Remarks: Bioaccumulation is unlikely. Partition coefficient: n- : log Pow: 3.72 octanol/water Phenol, isopropylated, phosphate (3:1): Bioaccumulation : Remarks: Potential bioaccumulation triphenylphosphate: Partition coefficient: n- : log Pow: 4.63 octanol/water Mobility in soil Components: Phenol, isopropylated, phosphate (3:1): Distribution among environ- : log Koc: 3.43 - 3.93 mental compartments Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : This product meets the criteria for a synthetic used oil under the U.S. EPA Standards for the Management of Used Oil (40 CFR 279). Those standards govern recycling and disposal in lieu of 40 CFR 260 -272 of the Federal hazardous waste program in states that have adopted these used oil regulations. Consult your attorney or appropriate regulatory official to be sure these standards have been adopted in your state. Recycle or burn in accordance with the applicable 17 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 standards. Dispose of in accordance with local regulations. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (triphenyl phosphate) Class : 9 Packing group : III Labels : Miscellaneous Packing instruction (cargo : 964 aircraft) Packing instruction (passen- : 964 ger aircraft) Remarks : Shipping in package sizes of less than 5 L (liquids) or 5 KG (solids) may lead to a non-regulated classification. IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (triphenyl phosphate) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes Remarks : Shipping in package sizes of less than 5 L (liquids) or 5 KG (solids) may lead to a non-regulated classification. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR UN/ID/NA number : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (triphenyl phosphate) Class : 9 Packing group : III Labels : CLASS 9 ERG Code : 171 Marine pollutant : yes(triphenyl phosphate) Remarks : Above applies only to containers over 119 gallons or 450 liters. Not regulated if shipped in packages less than or equal to 119 gallons (450 liters). 18 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Skin corrosion or irritation Carcinogenicity Reproductive toxicity Specific target organ toxicity (single or repeated exposure) Acute toxicity (any route of exposure) SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AIIC : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory TSCA : All substances listed as active on the TSCA inventory TSCA list The following substance(s) is/are subject to a Significant New Use Rule: Potassium decafluo- 67584-42-3 ro(pentafluoroethyl)cyclohexanesulphonate The following substance(s) is/are subject to TSCA 12(b) export notification requirements: Phenol, isopropylated, phosphate (3:1) 68937-41-7 The following substance(s) is/are subject to TSCA - 6 Risk Management Rules List of Chemicals: 19 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 Phenol, isopropylated, phosphate (3:1) 68937-41-7 The Environmental Protection Agency prohibits processing and distribution of this chemical/product for any use other than: (1) In hydraulic fluids either for the aviation industry or to meet military specifications for safety and performance where no alternative chemical is available that meets U.S. Department of Defense specification requirements, (2) lubricants and greases, (3) new or replacement parts for motor and aerospace vehicles, (4) as an intermediate in the manufacture of cyanoacrylate glue, (5) in specialised engine air filters for locomotive and marine applications, and (6) in adhesives and sealants before January 6, 2025, after which use in adhesives and sealants is prohibited. In addition, all persons are prohibited from releasing PIP (3:1) to water during manufacturing, processing and distribution in commerce, and must follow all existing regulations and best practices to prevent the release of PIP (3:1) to water during the commercial use of PIP (3:1). SECTION 16. OTHER INFORMATION Further information NFPA 704: HMIS® IV: Flammability HEALTH * 2 1 FLAMMABILITY 1 Health Instability 2 0 PHYSICAL HAZARD 0 HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz- ards or risks, and 4 representing signifi- cant hazards or risks. The "*" represents Special hazard a chronic hazard, while the "/" represents the absence of a chronic hazard. Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA P0 / TWA : 8-hour time weighted average OSHA Z-1 / TWA : 8-hour time weighted average 20 / 21 Skydrol® PE-5 Version Revision Date: SDS Number: Date of last issue: 08/03/2020 3.0 07/02/2021 150000093410 Date of first issue: 09/06/2016 PRD SDSUS / Z8 / 0001 AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza- tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi- cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre- vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth- erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern- ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Revision Date : 07/02/2021 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8 21 / 21