WAX IN STYRENE (Wax 135 Solution)

Hazard statements (CLP)

H226, H315, H320, H332, H335, H336

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Classified as Hazardous according to the New Zealand Hazardous Substances Regulations. Classified as Dangerous Goods for transport according to New Zealand Standard. This product is classified as: Xn, Harmful. Xi, irritating. F, Flammable. Hazardous according to the criteria of SWA. Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.

ADG classification

Class 3

UN Number

1993, Flammable Liquid, N.O.S. EPA New Zealand Approval Code: HSR001221

HSNO Classifications

3.1C Flammable Liquid 6.1E Acute Toxicity, Oral/Dermal 6.1D Acute Toxicity, Inhalation 6.3A Substance that is corrosive or irritating to the skin 6.4A Substance that is corrosive or irritating to the eye 6.6B Suspected human mutagen 6.7B Suspected human carcinogen 6.9B May cause damage to target organs through prolonged/repeated exposure 9.1C Aquatic ecotoxicity, Fish

Hazard statements

H226: Flammable liquid and vapour. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness.

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. -No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P243: Take precautionary measures against static discharge. P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTRE or doctor is you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers at landfill. Emergency Overview Physical Description & Colour: Colourless hazy liquid. Odour: Characteristic styrene odour.

Health hazards

Acute exposure to styrene in humans results in respiratory effects, such as mucous membrane irritation, eye irritation, and gastrointestinal effects. Styrene vapour causes mild irritation of the nose and throat at concentrations around 100 ppm, definite irritation at 350-500 ppm and severe irritation at about 500 ppm. Symptoms such as headache, dizziness and fatigue (similar in some ways to drunkenness) are reported at concentrations above 100-200 ppm. Other symptoms such as slower reaction times, reduced manual dexterity, and impaired co-ordination and balance can be observed at concentrations above 200 ppm. Styrene liquid can cause mild to severe irritation of the eyes in splashing occurs. Styrene liquid defats the skin and can cause dermatitis. Product is irritating to eyes and skin, harmful if inhaled, repeated exposure may cause skin dryness or cracking, vapours may cause drowsiness and dizziness.

Potential health effects

Inhalation: Short Term Exposure: High vapour pressures may cause drowsiness and dizziness. In addition, product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: Vapours may cause drowsiness and dizziness. Skin Contact: Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However, product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: Repeated exposure may cause skin dryness or cracking. Eye Contact: Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long terms ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: Styrene is classed 2B IARC – possibly carcinogenic to humans. See the IARC website for further details. A web address has not been provided as addresses frequently change.