TALARISTM 4.5 F

SECTION 2: Hazards identification

OSHA • May be harmful if swallowed • May be harmful in contact with skin WARNING • May be harmful if inhaled • Causes eye irritation Manufactured for: Atticus, LLC 5000 CentreGreen Way, Suite 100 Cary, NC 27513 Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also call 1-844-685-9173 for emergency medical treatment information. IF SWALLOWED: Call a doctor or poison control center if you feel unwell. IF ON SKIN OR CLOTHING: Call a doctor or poison control center if you feel unwell. IF INHALED: Call a doctor or poison control center if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do, and continue rinsing. If eye irritation persists get medical advice / attention. 5. FIRE -FIGHTING MEASURES FLASH POINT: Not combustible (aqueous formulation). FIRE AND EXPLOSION HAZARDS: Thermal decomposition may produce toxic fumes (see Section 10). EXTINGUISHING MEDIUM: Water fog, foam, dry chemical or carbon dioxide (CO2). FIRE FIGHTING EQUIPMENT: Firefighters should be equipped with self-contained positive pressure breathing apparatus and full bunker gear. FIRE FIGHTING INSTRUCTIONS: Evacuate area of all unnecessary personnel and fight fire from a safe distance upwind. Contain contaminated water / firefighting water; do not allow to enter drains or waterways. Foam or dry chemical fire extinguishing systems are preferred to prevent environmental damage from excessive water runoff.

NFPA Ratings

Health – 1 / Flammability – 1 / Reactivity – 0 1 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Isolate area and keep unnecessary and unprotected personnel from entering. Wear suitable personal protective clothing and equipment as described in Section 8 of this document. ENVIRONMENTAL PRECAUTIONS: Control spill at the source and prevent material from entering soil, sewers, waterways or low areas. Large spills to soil or similar surfaces may require removal and disposal of topsoil. Contain contaminated water / firefighting water. SPILL CLEANUP: Pump free liquid into suitable closed containers for disposal. After decontamination, spill area can be washed with water. Collect washwater for approved disposal. Decontaminate tools and equipment following cleanup. 7. HANDLING AND STORAGE HANDLING: Avoid contact with skin, eyes or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove and wash contaminated clothing before reuse. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.

Storage

Store in the original container in a dry area. Do not store in a manner where cross-contamination with other pesticides, fertilizers, food or feed could occur. If spilled during storage or handling, absorb with sand or other inert material and dispose of absorbent in accordance with the instructions in Section 13. 8. EXPOSURE CONTROL / PERSONAL PROTECTION ENGINEERING CONTROLS: Facilities storing or utilizing this material should be equipped with an eyewash station and a safety shower. PROTECTIVE CLOTHING: Wear long-sleeved shirt, long pants, shoes, socks, chemical-resistant gloves made of any waterproof material, and a chemical resistant apron when handling this product. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Off-white liquid ODOR: Faint sulfur FLASHPOINT: > 94°C PH: 5.5 – 6.0 BULK DENSITY: 1.118 g/ml (9.75 lbs/gal) SOLUBILITY: Dispersible 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Excessive heat. CHEMICAL STABILITY: Stable under all normal use and storage conditions. INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: This product is chemically stable and no hazardous reactions should occur if stored and handled as prescribed / indicated. When thermally decomposed, may release oxides of carbon, nitrogen and sulfur. HAZARDOUS POLYMERIZATION: Will not occur. Manufactured for: Atticus, LLC 5000 CentreGreen Way, Suite 100 Cary, NC 27513

TOXICOLOGICAL INFORMATION

ORAL TOXICITY (RAT LD50): > 5,000 mg/kg DERMAL TOXICITY (RAT LD50): > 5,050 mg/kg INHALATION TOXICITY (RAT LC50): > 2.17 mg/L (4-hour) EYE IRRITATION: Practically non-irritating SKIN IRRITATION: Slightly irritating SKIN SENSITIZATION: Not a contact sensitizer CARCINOGENICITY: EPA: Not Listed NTP: Not Listed ACGIH: Not Listed OSHA: Not Listed IARC: Not Listed MUTAGENIC TOXICITY: No evidence of mutagenic effects during in vivo and in vitro assays. REPRODUCTIVE TOXICITY: Not known to cause reproductive or birth defects at normal exposure levels. 12. ECOLOGICAL INFORMATION Runoff may be hazardous to aquatic organisms. Do not contaminate water when disposing of equipment washwater or rinsate. The following information is for the active ingredient, Thiophanate-methyl: AQUATIC TOXICITY Bluegill (96-hour LC50): > 41 ppm Rainbow Trout (96-hour LC50): 8.3 ppm Daphnia (48-hour EC50): 5.4 ppm Mysid (96-hour LC50): 1.1 ppm AVIAN TOXICITY Bobwhite Quail (LC50): > 10,000 ppm Mallard Duck (LD50): 4,640 mg/kg OTHER TOXICITY Honey Bee (LD50): > 100 μg/bee