Premium Machine Dish Detergent

Hazard statements (CLP)

H290, H302, H314, H318

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

OSHA Classification of the Substance or Mixture Classification (GHS-US) Met. Corr. 1 H290 Acute Tox. 4 (Oral) H302 SkinCorr. 1A H314 EyeDam.1 H318

2.2 Label elements

GHS-US Labeling

Hazard pictograms

asos aso7

Signal word

Danger

Hazard statements

H290 - May be corrosive tometals H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage see section 16 SECTION4:FIRST AID MEASURES 4.1. Descriptionof First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feelunwell, seek medical advice (show the label if possible). First-aid MeasuresAfter Inhalation: Ifinhaled, removeto fresh airandkeep atrestin aposition comfortable forbreathing. If you feel unwell, seek medical advice. First-aid Measures After Skin Contact: Remove contaminated clothing. Inmediately flush skin with plenty of water for atleast 60 minutes. Immediately call aPOISON CENTER or doctor/physician. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contactlenses, if presentand easy to do. Continue rinsing for atleast60 minutes. Immediately calla POISON CENTER or doctor/physician. First-aid Measures After Ingestion: Rinsemouth. DoNOT induce vomiting. Immediately callaPOISONCENTER or doctor/physician. 4.2, Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Harmful if swallowed. Corrosive to eyes, respiratory system and skin. Symptoms/Injuries After Inhalation: Corrosive to the respiratory tract. Symptoms/Injuries After Skin Contact: Corrosive. Causes burns. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: Harmful if swallowed. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If medical advice is needed, have product container or label at hand. 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Not flammable. Explosion Hazard: Product is not explosive. Reactivity: The substance decomposes on heating, on contact with acids and under influence of light producing toxic and corrosive gases. The substance is astrong oxidantandreacts with combustible and reducing materials. 53. Advice forFirefighters

Precautionary statements

P234 - Keep only in original container. P260 - Do not breathe vapors, spray, mist. P264 - Wash hands, forearms, andexposedareas thoroughly afterhandling. P270 - Do not eat, drink or smoke when using this product. P280 - Wear eye protection, protective gloves, protective clothing. P301+P312-1F SWALLOWED: CallaPOISON CENTER or doctor/physician if you feel unwell. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353-IF ONSKIN (or hair): Remove/Take offimmediately all contaminated clothing. Rinse skin with water/shower. P304+P340-IFINHALED: Removepersontofresh airand keep atrestinaposition comfortable for breathing. P305+P351+P338-Ifineyes: Rinse cautiously with water for several minutes. Removecontactlenses, if present andeasy to do. Continuerinsing. P310 - Immediately call a POISON CENTER or doctor/physician. P321 - Specific treatment (see Section 4). P363 - Wash contaminated clothing before reuse. P390 - Absorb spillage to preventmaterial damage. P405 - Store locked up. P406 - Store in corrosive resistant container with a resistant inner liner. P501 - Dispose of contents/container according tolocal, regional, national, and international regulations. EN (EngiishUS) i according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 23. Fire Exercise caution when fighting any chemical fire Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water courses. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. EN EngiishUS) 217 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations ECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures GeneralMeasures: Donotallowcontactwith metals. Donotgetineyes,onskin, oronclothing. Do NOT breathe(dust, vapor, mist, gas). 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. Stop leak if safe to do so. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Cautiously neutralize spilled liquid. Absorb and/or contain spill with inert material, then place in suitable container. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. 6.4. Reference to OtherSections See heading 8, Exposure Controls and Personal Protection. ECTION 7: HANDLING AND STORAGE 7.1. Precautions for SafeHandling Additional Hazards When Processed: Ammonium or nitrogen containing compounds can react with the sodium hypochlorite in this product releasing toxic chlorine gas. Hygiene Measures: Handle in accordancewith good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations.

2.3 Other hazards

Corrosive to the respiratory tract 24.

Ingredient(s) with unknown acute toxicity

No data available 3.1. Substance Not applicable 3.2. Mixture Name

Product definition

%

Classification (GHS-US)

Sodium hydroxide (CAS No) 1310-73-2 | 16.286 | Met. Corr. 1, H290 AcuteTox.4(Oral), H302 Skin Corr. 1A, H314 Eye Dam. 1, H318 AquaticAcute 3, H402 Phosphonic acid, [nitrilotris(methylene)]tris-, | (CAS No) 2235-43-0 | 3.52 Eye Irrit. 2A, H319 pentasodium salt Tetrasodium EDTA (CAS No) 64-02-8 1.763 Comb. Dust, H232 Acute Tox. 4 (Oral), H302 Acute Tox.4 (Inhalation:dust,mist), H332 Eye Dam. 1,H318 Adquatic Acute 2, H401

Storage

Conditions Storein adry, cool and well-ventilated place. Keep container closed when notin use. Storage areas should be periodically checked for corrosion and integrity. Incompatible Products: Metals. Reducing agents. Strong acids. Special Rules on Packaging: Store in original container or corrosive resistant and/or lined container. 7.3. Specific End Use(s) Commercial dish machine detergent. For professional use only. ECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Sodium hydroxide (1310-73-2) USA ACGIH] ACGIH Ceiling (mg/m?®) 2mgm® USA NIOSH| NIOSH REL (ceiling) (mg/m?) 2mgm® USAIDLH | US IDLH (mg/m?) 10 mg/m®

Further information

When using, do not eat, drink or smoke. EN EngiishUS) 3 No additional information available ECTION 1 ABILITY AND REACTIVITY 10.1 Reactivity: The substance decomposes on heating, on contact with acids and underinfluence of light producing toxic and corrosive gasesincluding. The substanceis a strong oxidant and reacts with combustible andreducingmaterials. 10.2 Chemical Stability: Stable underrecommendedhandling and storage conditions (see section 7). 10.3 Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 104 Conditions to Avoid: Directsunlight. Extremely high orlow temperatures. Contactwith metallicsubstances. 10.5 Incompatible Materials: Metals. Reducing agents. Strong acids. 10.6 Hazardous Decomposition Products: Carbon oxides (CO, C Sodium oxides. ECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information On Toxicological Effects Acute Toxicity: Harmful if swallowed. Premium Machine Dish Detergent ATE (Oral) [ 500.00 mg/kg body weight Sodium hydroxide (1310-73-2) LD50 Oral Rat 140 - 340 mgkg ATE (Oral) 140.00 mg/kg body weight Tetrasodium EDTA (64-02-8) LD50 Oral Rat 1780 mg/kg ATE (Dust/Mist) 1.50 mg/l/dh Skin Corrosion/Irritation Causes severe skinburnsand eyedamage. (pH 14) Serious Eye Damage/Irritation Causes serious eye damage. (pH 14) Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified

Appearance/Odor

Red None OdorThreshold No data available pH 14 Relative Evaporation Rate (butylacetate=1) Nodataavailable Melting Point Nodataavailable Freezing Point Nodataavailable Boiling Point Nodataavailable FlashPoint None Auto-ignition Temperature Nodataavailable Decomposition Temperature Nodataavailable Flammability (solid,gas) Nodataavailable Vapor Pressure Nodataavailable Relative Vapor Densityat20°C Nodataavailable Relative Density 1.3 (water =1) Solubility Soluble in water Partition coefficient: n-octanol/water Nodataavailable Viscosity Nodataavailable

Aspiration hazard

Not classified Symptoms/Injuries After Inhalation: Corrosive to the respiratory tract. Symptoms/Injuries After Skin Contact: Corrosive. Causes burns. Symptoms/Injuries After Eye Contact: Causesserious eye damage. Symptoms/Injuries After Ingestion: Harmful if swallowed. EN EngiishUS) a7 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations ECTION12: ECOLOGICAL INFORMATION 12.1. Toxicity Sodium hydroxide (1310-73-2) LC50 Fish 1 [40mgi Tetrasodium EDTA (64-02-8) LC50 Fish 1 41 mg/l (Exposure time 96 h - Species Lepomis macrochirus [static]) LC 50 Fish 2 59.8 mg/l (Exposure time 96 h - Species Pimephales promelas [static]) ErC50 (algae) 2.77 mg/l (72hr species: Desmodesmus subspicatus) 12.2. Persistence and Degradability No additional information available 12.3. Bioaccumulative Potential Tetrasodium EDTA (64-02-8) Log Pow [ 5.01 (calculated) 124. Mobility in Soil No additional information available

Other hazards

No additional informationavailable 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, andinternational regulations. RCRA Waste Code: D002 (Corrosive Material). ECTION 14: TRANSPORT INFORMATION 14.1 In Accordance withDOT ProperShipping Name COMPOUNDS, CLEANING LIQUID (contains sodium hydroxide) HazardClass 18 Identification Number NA1760 Label Codes 18 Packing Group Bl ERGNumber 1154 14.2 In Accordance withIMDG ProperShipping Name CORROSIVE LIQUID, N.O.S. (contains sodium hydroxide) HazardClass 18 Identification Number UN1760 Packing Group Bl Label Codes 18 EmS-No.(Fire) :F-A EmS-No.(Spillage) :S-B 14.3 In Accordance withIATA ProperShipping Name CORROSIVE LIQUID, N.O.S. (contains sodiumhydroxide) Packing Group Bl Identification Number UN1760 HazardClass 18 Label Codes 18 ERG Code (IATA) 8L 15.1 US Federal Regulations Premium Machine Dish Detergent SARA Section 311/312 Hazard Classes ‘ Immediate (acute) health hazard Sodium hydroxide (1310-73-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Tetrasodium EDTA (64-02-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phosphonic acid, [nifrilotris(methylene)]tris-, pentasodium salt (2235-43-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory EN EngiishUS) 507 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 15.2 US State Regulations Sodium hydroxide (1310-73-2) U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr) U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) S. - Idaho - Occupational Exposure Limits - TWAs U.S. - Louisiana - Reportable Quantity List for Pollutants U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S.-Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 RTK-U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan

2.1 Classification of the substance or mixture

Classification (GHS-US) Met. Corr. 1 H290 Acute Tox. 4 (Oral) H302 SkinCorr. 1A H314 EyeDam.1 H318