Foaming Hand Soap

Hazard statements (CLP)

H315, H319, H402, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

OSHA 21. Classificationofthe Substance orMixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2A H319 Aquatic Acute 3 H402 Aquatic Chronic 3 H412 Full text of H-phrases: see section 16

2.2 Label elements

GHS-US Labeling

Hazard pictograms

e

Signal word

Wamning

Hazard statements

H315 - Causes skin irritation. H319-Causesserious eyeirritation. H402 - Harmful to aquatic life. H412 - Harmful to aquatic life with long lasting effects. see section 16 SECTION4:FIRSTAIDMEASURES 4.1. DescriptionofFirstAidMeasures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). First-aid Measures After Inhalation: If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. First-aid Measures After Skin Contact: Remove contaminatedclothing. Drench affectedareawith water for atleast 15 minutes. Obtain medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Rinse cautiously withwater for atleast 15 minutes. Remove contactlenses, if presentand easy to do. Continue rinsing. Obtain medical attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Inmediately call a POISON CENTER or doctor/physician. 4.2. Mostimportant symptoms and effects, both acute and delayed Symptoms/Injuries: Causes skin irritation. Causes serious eye irritation. Symptoms/injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries Afteringestion: Ingestionislikely tobe harmful orhave adverse effects. Chronic Symptoms: None expected under normal conditions of use. 4.3. Indication of Any Inmediate Medical Attentionand Special Treatment Needed If medical advice is needed, have product container or label at hand. 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable ExtinguishingMedia: Donotuseaheavywater stream. Use ofheavy stream of water may spreadfire. 5.2. SpecialHazardsArising Fromthe SubstanceorMixture Fire Hazard: Not lammable. Explosion Hazard: Product is not explosive. Reactivity: Reacts exothermically with (some) acids. 5.3. Advice for Firefighters

Precautionary statements

P264 - Wash hands, forearms, and exposed areas thoroughly after handling. P273 - Avoid release to the environment. P280 - Wear protective clothing, protective gloves, eye protection. P302+P352-IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Removecontactlenses, if presentandeasy to do. Continuerinsing. P321 - Specific freatment (see Section 4 on this SDS). P332+P313- If skiniritation occurs: Get medical advice/attention. P337+P313-Ifeyeirritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations. 23. Fire Exercise caution when fighting any chemical fire Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water courses. Protection During Firefighting: Donot enter fire areawithout proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all eye and skin contact and do not breathe vapor and mist. 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For EmergencyResponders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. Stop leak if safe to do so. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 0412712015 EN (Engish US) 3/9

2.3 Other hazards

No additional information available 24.

Ingredient(s) with unknown acute toxicity

No data available 3.1. Substance Not applicable 3.2. Mixture 0412712015 EN (Engish US) 119

Classification (GHS-US)

Water (CAS No) 7732-18-5 Not classified Dodecylbenzenesulfonic acid (CAS No) 27176-87-0 AcuteTox.4(Oral), H302 SkinCorr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 2, H401 Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.- (CAS No) 9004-82-4 3.02 AcuteTox.4(Oral), H302 (dodecyloxy)-, sodium salt Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 Amines, N,N,N'-trimethyl-N'-tallow (CAS No) 313688-92-5 0.96 AcuteTox.4(Oral), H302 alkyltrimethylenedi-, reaction products with Skin Irrit. 2, H315 sodium 2-chloroacetate (1:1) Eye Dam. 1, H318 AquaticChronic2,H411 Sodium hydroxide (CAS No) 1310-73-2 0.57 Met. Corr. 1, H290 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 3, H402 Alanine, N,N-bis(carboxymethyl)-, trisodium salt (CAS No) 164462-16-2 0.36 Not classified Terpenes and Terpenoids, sweet orange-oil (CAS No) 68647-72-3 0.08215 Flam. Lig. 3, H226 Skin Irrit. 2, H315 SkinSens. 1,H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Terpene hydrocarbons, n.o.s. (CAS No) 68956-56-9 0.076125 Flam. Liq. 2, H225 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Skin Sens. 1B, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Terpenes and Terpenoids, lemon-oil (CAS No) 68917-33-9 0.0741075 Flam. Lig. 3, H226 Skin Irrit. 2, H315 SkinSens. 1,H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Sodium sulfate (CAS No) 7757-82-6 0.06 Not classified Sodium chloride (CAS No) 7647-14-5 0.04 Not classified 6-Octenenitrile, 3,7-dimethyl- (CAS No) 51566-62-2 0.01 Eye Irrit. 2A, H319 AquaticChronic3,H412 Citral (CAS No) 5392-40-5 0.002975 Flam. Liq. 4, H227 Skin Irrit. 2, H315 EyeIrrit. 2A, H319 SkinSens.1B,H317 Aquatic Acute 2, H401 7-Octen-2-ol, 2-methyl-6-methylene-, dihydro (CAS No) 53219-21-9 0.0015 Eye Irit. 2A, H319 derivative 1,4-Cyclohexadiene, 1-methyl4-(1-methylethyl)- (CAS No) 99-854 0.000796 Not classified 2,6-Di-tert-butyl-p-cresol (CAS No) 128-37-0 0.0005995 AquaticAcute1,H400 AquaticChronic1,H410 041272015 EN (Engish US) 29

Storage

Conditions Storeinadry, cooland well-ventilated place. Keep container closed whennotinuse Incompatible Products: strong acids. Strong oxidizers. 7.3. SpecificEnd Use(s) General Cleaning in Food Service and Hospitality. For professional use only. 8.1. Control Parameters For substances listed in section 3 that are notlisted here, there are no established exposure limits from the manufacturer,

Further information

When using, do not eat, drink or smoke. SECTION 9: PHYSICAL Al EMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State Liquid Noadditionalinformation available 10.1. Reactivity: Reactsexothermicallywith (some)acids. 10.2. ChemicalStability: Stableunderrecommendedhandiingandstorage conditions(seesection7). 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. ConditionstoAvoid: Directsunlight. Extremely high orlowtemperatures. 10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. 10.6. Hazardous Decomposition Products: Carbon oxides (CO, CO;). Nitrogen compounds. Sodium oxides. Sulfur compounds. 11.1. Information On Toxicological Effects Acute Toxicity: Not classified Water ( 7732-18-5) LD50 Oral Rat ‘ > 90000 mg/kg Citral ( 5392-40-5) LD50 Oral Rat 4950 mgkg LD50 Dermal Rabbit 2250 mglkg Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.-(dodecyloxy)-, sodium salt ( 9004-82-4) LD50 Oral Rat [ 1600 mgkg Sodium sulfate ( 7757-82-6) LD50 Oral Rat ‘ > 10000 mg/kg Dodecylbenzenesulfonic acid ( 27176-87-0) LD50 Oral Rat [ 1260 mgkg Amines, N,N,N'-trimethyl-N"-tallow alkyltrimethylenedi-, reaction products with sodium 2-chloroacetate (1:1) ( 313688-92-5) ATE (Oral) ‘ 500.00 mg/kg body weight Sodium chloride ( 7647-14-5) LD50 Oral Rat 3 glkg LC50 Inhalation Rat > 42 g/m® (Exposure time: 1 h) 2,6-Di-tert-butyl-p-cresol ( 128-37-0) LD50 Oral Rat > 2930 mg/kg (Species: Sprague-Dawley) LD50 Dermal Rat > 2000 mgkg Skin Corrosion/Irritation: Causes skin irritation. pH: 8 (max) Serious Eye Damagellrritation: Causes serious eye irritation. pH: 8 (max) Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified 0412712015 EN (Engish US) 509 According to Federal Register /Vol. 77, No. 58 /Monday, March 26,2012/ Rules and Regulations Carcinogenicity: Not classified 2,6-Di-tert-butyl-p-cresol ( 128-37-0) IARC group [3 Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: C: auses skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/injuries After Ingestion: Ing estion is likely to be harmful or have adverse effects. Chroni Symptoms: None expected under normal conditions of use. CTION 12:EC GICALINFORMATION Toxicity Ecology - General Harmful to aquatic life. Citral ( 5392-40-5) EC50 Daphnia 1 [ mgll (Exposure time 48 h - Species Daphnia magna) Terpene hydrocarbons, n.o.s. (68956-56- 9) LC50 Fish 1 5.07 mg/l EC50 Daphnia 1 2.7 mg/l ErC50 (algae) 3.081 mg/l Sodium hydroxide ( 1310-73-2) LC50 Fish 1 45.4 mg/l (Exposure time 96 h - Species Oncorhynchus mykiss [static]) EC50 Daphnia 1 40 mg/ Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.om: ega.-(dodecyloxy)-, sodium salt ( 9004-82-4) EC50 Other Aquatic Organisms 1 '3 12(2.43 - 4.01) mgl (Species Ceriodaphnia, exposure time 48 hr) Sodium sulfate ( 7757-82-6) LC50 Fish 1 13500 (13500 - 14500) mg/l (Exposure time 96 h - Species Pimephales promelas) EC50 Daphnia 1 2564 mg/l (Exposure time 48 h - Species Daphnia magna) LC 50 Fish 2 6800 mg/l (Exposure time 96 h - Species Pimephales promelas [static]) Dodecylbenzenesulfonic acid ( 27176-87-0) LC50 Fish 1 10.8 mg/I (Exposure time 96 h - Species Oncorhynchus mykiss [static]) EC50 Daphnia 1 5.88 mg/l (Exposure time 48 h - Species Daphnia magna) LC 50 Fish 2 3.5 mg/l (Exposure time 96 h - Species Brachydanio rerio [static]) Sodium chloride ( 7647-14-5) LC50 Fish 1 5560(5560 -6080)mg/l (Exposuretime: 96 h - Species: Lepomis macrochirus[flow- through]) EC50 Daphnia 1 1000 mg/l (Exposure time 48 h - Species Daphnia magna) LC 50 Fish 2 12946 mg/l (Exposure time 96 h - Species Lepomis macrochirus [static]) EC50 Daphnia 2 340.7 (340.7 - 469.2) mg/I (Exposure time: 48 h - Species: Daphnia magna [Static]) 2,6-Di-tert-butyl-p-cresol ( 128-37-0) EC50 Other Aquatic Organisms 2 0.43 mg/l (Exposure time 72 h - Species Desmodesmus subspicatus) 12.2. Persistence and Degradability Foaming Hand Soap Persistence and Degradability [ Not established. 12.3. Bioaccumulative Potential Foaming Hand Soap Bioaccumulative Potential [ Not established. Citral ( 5392-40-5) Log Pow [2.76 (at 25 °C) Dodecylbenzenesulfonic acid ( 27176-87-0) BCF fish 1 [ 130 041272015 EN (Engish US) 6/9 Accordingto Federal Register/Vol. 77, No. 58 /Monday, March 26, 2012/ Rules and Regulations Sodium chloride ( 7647-14-5) BCF fish 1 l (no bioaccumulation) 2,6-Di-tert-butyl-p-cresol ( 128-37-0) BCF fish 1 230 - 2500 Log Pow 4.17 124. Mobility in Soil No additionalinformation available

Appearance/Odor

Clear Mild Odor Threshold No data available 0412712015 EN (Engish US) 419

2.1 Classification of the substance or mixture

Substance orMixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2A H319 Aquatic Acute 3 H402 Aquatic Chronic 3 H412 Full text of H-phrases: see section 16