Glycol Ether DPNB

Hazard statements (CLP)

H303, H305

Code

Statements

H303

May be harmful if swallowed

Classification (GHS-US)

Specific target organ H336 May cause drowsiness or dizziness toxicity (single exposure) Category 3 Dipropylene Glyco! Butyl Ether (CAS-No.) 2991 1-28-2 99.0 STOT SE 3, H336 (Main constituent)

Hazard statements

see section 16 H336 - May cause drowsiness or dizziness see section 16 3.2. Mixtures Not applicable 4.1. Description of first aid measures First-aid measures general Call a poison center/doctor/physician if you feel unwell. Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. Show this safety data sheet to the doctor in attendance. First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. In case of respiratory arrest, administer artificial respiration. Get medical advice/ attention. First-aid measures after skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Seek medical attention if discomfort persists. First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion Rinse mouth with lukewarm water. If large quantity is swallowed, give lukewarm water (pint % liter) if victim is completely conscious/ alert. Do NOT induce vomiting. Risk of damage to lungs exceeds poisoning risk. If vomiting does occur, have victim lean forward to reduce risk of aspiration. If unconscious, place in recovery position and seek medical advice. Obtain emergency medical attention. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects May cause drowsiness or dizziness. May be harmful if swallowed and enters airways. May be harmful if swallowed. Symptoms/effects after eye contact Eye irritation. 4.3. immediate medical attention and special treatment, if necessary Treat symptomatically. Treatment to overexposure should be directed at the control of symptoms and the clinical condition of the patient. SECTIO e-fighting measures S.A. Suitable (and unsuitable) extinguishing media Suitable extinguishing media SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam. LARGE FIRE: Use water spray, water fog or alcohol-resistant foam. Do Not use solid water stream. Specific hazards arising from the chemical Fine spray/ mists may be combustible at temperatures below normal flash point. Heat from fire can generate flammable vapor. Vapors may be heavier than air. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if it can be done without risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Always stay away from tanks engulfed in fire. Special protective equipment and precautions for fire-fighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. -cidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Emergency procedures Use personal protective equipment. Ensure adequate ventilation.Eliminate all sources of ignition. Evacuate personnel to safe areas. Ventilate spillage area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. 06/06/2018 / Monday, March 26, 2012 / Rules and Regulations Protective equipment Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material. Do not touch or watk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

2.2 Label elements

GHS-US labeling

Signal word

Warning

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P312 - Calla POISON CENTER/doctor if you feel unwell P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to an approved waste disposal plant.

Other hazards which do not result in classification

No additional information available. 2.4,

Ingredient(s) with unknown acute toxicity

Not applicable 34. Substances 06/06/2018 Page Name

Further information

Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. ndling and storage 741. Precautions for safe handling Ane os Precautions for safe handling For industrial use only. Keep container tightly closed when not in use. The potential for peroxide formation is enhanced when this solvent is used in processes such as distillation. Use only non-sparking tools.Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. Wear personal protective equipment. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Tide Conditions for safe storage, including any incompatibilities Storage conditions Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. ontrols/personal protection. 8.1. Geontrol parameters Consult local authorities for acceptable exposure limits. 6.2. Appropriate engineering controls Appropriate engineering controls Ensure good ventilation of the work station. Both local exhaust and general room ventilation are usually required. Environmental exposure controls Avoid release to the environment. 8.3. individual protection measures/Personai protective equipment. — Hand protection: Wear chemical resistant gloves such as Neoprene Eye protection: Eye protection such as chemical splash goggles and/ or face shield must be worn when possibility exists for eye contact due to splashing or spraying liquid, airborne particles, or vapor. Skin and body protection: Not normaily considered a skin hazard. Where use can result in skin contact, practice good personal hygiene. Skin should be washed after contact. Respiratory protection: in case of insufficient ventilation, wear suitable respiratory equipment al and chemical properties o4. information on basic physical and chemical properties . Physical state Liquid Color Clear, colorless Odor Ether-like odor Odor threshold No data available 06/06/2018 according to Federal Register No additional information available 40.4. Reactivity May react with oxygen to form peroxides. 16.2. Chemical stability Stabile under recommended storage conditions. occur 40.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Extended contact with air or oxygen. The potential for peroxide formation is enhanced when this solvent is used in processes such as distillation. Heat, sparks, open flame, other ignition sources, and oxidizing conditions. ignition may occur at temperatures below those published in the literature as autoignition or ignition temperatures. 410.8. Incompatible materials Air or oxygen. Strong acids. Strong oxidizing agents. 40.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SE ological information 441.4. information on toxicological effects Acute toxicity (oral) Oral: Not classified. Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified Glycol! Ether DPNB ( 29911-28-2) - LD50 oral rat 2000 mg/kg LD50 dermal rat 2000 mg/kg Skin corrosion/irritation Not classified Serious eye damage/irritation Not classified Respiratory or skin sensitization Not classified Germ cell mutagenicity Not classified EN (English US) Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity — single exposure: May cause drowsiness or dizziness. Specific target organ toxicity - repeated Not classified exposure Aspiration hazard Not classified Viscosity, kinematic 4.85 mm7/s Symptoms/effects May cause drowsiness or dizziness. Symptoms/effects after eye contact Eye irritation. ISECTION 12: Ecological information _ 12.1. Toxicity Ecology - general The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available isposal considerations _ 13.4. Disposal methods ; Waste treatment methods Dispose of contents/container in accordance with licensed collector's sorting instructions. sport information _ Department of Transportation (DOT) In accordance with DOT Not regulated for transport Transportation of Dangerous Goods Transport by sea Air transport CTI gulatory information 45.1, US Federal regulations Glycol Ether DPNB (29911-28-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes | Health hazard - Specific target organ toxicity (single or repeated exposure) All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory EN (English US) / Monday, March 26, 2012 / Rules and Regulations 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available National regulations No additional information available 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date 06/06/2018 Full text of H-phrases: H336 May cause drowsiness or dizziness NFPA heaith hazard 1- Materials that, under emergency conditions, can cause significant irritation. NFPA fire hazard 1- Materials that must be preheated before ignition can occur. NFPA reactivity Q- Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health 1 Slight Hazard - Irritation or minor reversible injury possible Flammability 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) Physical 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. Please be advised revisions to the Safety Data Sheet (SDS) may require a label update. In no event shall Whitaker Oil Company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Whitaker Oil Company has been advised of the possibility of such damages. The vendor assumes no responsibility for injury or damages resulting from the inappropriate alteration or maniputation of this SDS and its contents from that orginally submitted by Whitaker Oif Company. 06/06/2018