Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
40-<50
General Information
Revision date
2016-09-06
Product name
ASTC 3003 , Part A
Emergency telephone
+1 714-552-6915 & +1 714-803-1274
Icons in SDS
Company Information
company name
ASTC Polymers
e-mail address of the competent person responsible for the Safety Data Sheet
info@astcpolymers.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 [CLP]]
2.1 Classification of the substance or mixture
Carc. 2: H351 Suspected of causing cancer. Skin Sens. 1: H317 May cause an allergic skin reaction. Resp. Sens. 1: H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Eye Irrit. 2: H319 Causes serious eye irritation. Skin Irrit. 2: H315 Causes skin irritation. Acute Tox. 4: H332 Harmful if inhaled. STOT SE 3: H335 May cause respiratory irritation. STOT RE 2: H373 May cause damage to organs through prolonged or repeated exposure through inhalation.
2.2 Label elements
The product is required to be labelled in accordance with regulation (EC) No 1272/2008 (CLP).
Signal word
DANGER
Contains
4,4'-Methylenediphenyl diisocyanate 4,4'-Methylenediphenyl diisocyanate, oligomers
Hazard statements
H351 Suspected of causing cancer. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure through inhalation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P260 Do not breathe vapours. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves / eye protection / face protection. P284 In case of inadequate ventilation wear respiratory protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER / doctor. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to in accordance with local/regional/national/international regulation. Special labelling EUH204 Contains isocyanates. May produce an allergic reaction. Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
Other physicochemical hazards
Reactions with water, with formation of carbon dioxide.
Environmental hazards
Does not contain any PBT or vPvB substances.
Other hazards
Further hazards were not determined with the current level of knowledge.