ASTC 3003 , Part A

ASTC Polymers

Revision date : 2016-09-06

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

40-<50

General Information

Revision date

2016-09-06

Product name

ASTC 3003 , Part A

Emergency telephone

+1 714-552-6915 & +1 714-803-1274

Icons in SDS

GHS07 GHS08

Company Information

company name

ASTC Polymers

e-mail address of the competent person responsible for the Safety Data Sheet

info@astcpolymers.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 [CLP]]

2.1 Classification of the substance or mixture

Carc. 2: H351 Suspected of causing cancer. Skin Sens. 1: H317 May cause an allergic skin reaction. Resp. Sens. 1: H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Eye Irrit. 2: H319 Causes serious eye irritation. Skin Irrit. 2: H315 Causes skin irritation. Acute Tox. 4: H332 Harmful if inhaled. STOT SE 3: H335 May cause respiratory irritation. STOT RE 2: H373 May cause damage to organs through prolonged or repeated exposure through inhalation.

2.2 Label elements

The product is required to be labelled in accordance with regulation (EC) No 1272/2008 (CLP).

Signal word

DANGER

Contains

4,4'-Methylenediphenyl diisocyanate 4,4'-Methylenediphenyl diisocyanate, oligomers

Hazard statements

H351 Suspected of causing cancer. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure through inhalation.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P260 Do not breathe vapours. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves / eye protection / face protection. P284 In case of inadequate ventilation wear respiratory protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER / doctor. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to in accordance with local/regional/national/international regulation. Special labelling EUH204 Contains isocyanates. May produce an allergic reaction. Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

Other physicochemical hazards

Reactions with water, with formation of carbon dioxide.

Environmental hazards

Does not contain any PBT or vPvB substances.

Other hazards

Further hazards were not determined with the current level of knowledge.

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