RP026UV

Hazard statements (CLP)

H315, H317, H319, H361f, H400, H410, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Directive (EC) No

Health hazards

Warning, Skin Irrit. 2, Causes skin irritation. Warning, Eye Irrit. 2, Causes serious eye irritation. Warning, Skin Sens. 1, May cause allergic skin reaction. Aquatic Chronic 2, Toxic to aquatic life with long lasting effects. Adverse physicochemical effects, effects on human health and the environment: No other hazards

2.2 Label elements

Labelling

Signal word

Warning. Hazardous ingredients which must be stated on the label  reaction product: bisphenol-A- (epichlorohydrin); epoxy resin (average molecular weight <= 700)  oxirane, mono [(C12-14-alkyloxy) methyl] derivatives .: May cause allergic reaction.  Reaction mass of Bis (1,2,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2 ,: May cause allergic reaction.

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. H361f Suspected of damaging the unborn child. H400 Very toxic to aquatic organisms. H410 Very toxic to aquatic life with long lasting effects. Full text of other abbreviations Skin Irrit. 2 3.2 / 2 Skin irritation, category 2 Eye Irrit. 2 3.3 / 2 Eye irritation, category 2 Skin Sens.1 3.4.2 / 1 Skin sensitisation, category 1 Repr. 2 3.7/2 Reproductive toxicity, category 2 Aquatic Acute 1 4.1 / A1 Acute aquatic hazard category 1 Aquatic Chronic 1 4.1 / C1 Chronic (long-term) aquatic hazard, Category 1 Aquatic Chronic 2 4.1 / C2 Chronic (long-term) aquatic hazard, Category 2 Paragraphs modified from the previous revision: SECTION 1: Identification of the substance/mixture and of the company/undertaking

Prevention

P261 Avoid breathing dust / fumes / gas / vapour / spray. P264 Wash tools thoroughly after use. P273 Avoid release to the environment. P280 Wear protective gloves/clothing and eye/face protection. Action: P333 + P313 In case of skin irritation or rash: consult a doctor. P391 Collect spillages.

Special Provisions

EUH205 Contains epoxy compounds. May cause allergic reaction.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

None

2.3 Other hazards

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%

Other hazards

No other hazards SECTION 3: Composition and information on ingredients 3.2 Mixtures: Description: Hazardous components within the meaning of the CLP regulation and related classification: Chemical Name CAS No. Layout Concentration (%) EC No. (Regulation (EC) No Index No. 1272/008) Registration number reaction product: bisphenol- 1675-54-3 Eye Irrit. 2 H319 >= 80% 216-823-5 A- (epichlorohydrin); epoxy Skin Irrit. 2 H315 603-073-00-2 Skin Sens. 1 H317 resin (number average 01-2119456619-26 Aquatic Chronic 2 H411 molecular weight <= 700) Oxirane, mono [(C12-14- 68609-97-2 Skin Irrit. 2 H315 >= 10% - < 20% 271-846-8 alkyloxy) methyl] derivatives Skin Sens. 1,1A, 1B H317 603-103-00-4 01-2119485289-22 Reaction mass of Bis(1,2,6- 1065336-91-5 Repr. 2 H361f >= 0.5%- < 1% 915-687-0 pentamethyl-4-piperidyl) Skin Sens. 1, H317 - Aquatic Acute 1 H400 sebacate and methyl 1,2 01-2119491304-40 Aquatic Chronic 1 H410 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures: In case of skin contact: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose of safely. After contact with skin, wash immediately with soap and plenty of water. In case of eye contact: After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. Protect uninjured eye. In case of ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. In case of inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2 Most important symptoms and effects, both acute and delayed: Appearances: None. 4.3 Indication of any immediate medical attention and special treatment needed: In case of accident or feeling unwell, seek medical advice immediately (show the instructions for use or the Safety Data Sheet where possible). Treatment: None. SECTION 5: Fire-fighting measures 5.1 Extinguishing media: Suitable extinguishing media: CO2 or dry chemical fire extinguisher. Extinguishing media which must not be used for safety reasons: None in particular. 5.2 Special hazards arising from the substance or mixture Specific firefighting hazards: Do not inhale explosion gases or combustion gases. Burning produces heavy smoke. 5.3 Advice for firefighters: Special protective equipment for firefighters: Use suitable respiratory equipment. Collect contaminated extinguishing water separately. This must not be discharged into the sewage system. Move undamaged containers out of the immediate danger zone if this can be done safely. SECTION 6: Accidental release measures for the substance or mixture 6.1 Personal precautions, protective equipment and emergency procedures: Personal precautions: Wear personal protective equipment. Remove persons to safety. See protective measures under points 7 and 8. 6.2 Environmental precautions: Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand. 6.3 Methods and material for containment and cleaning up Wash with plenty of water. 6.4 Reference to other sections: See also section 8 and 13. SECTION 7: Handling and storage: 7.1 Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. See also section 8 for recommended protective equipment. Advice on general occupational hygiene: Contaminated clothing should be changed before entering eating areas. Do not eat or drink while working. 7.2 Conditions for safe storage, including any incompatibilities Store in original containers, dry, tightly closed, in a cool and well-ventilated area. Avoid contact with skin, eyes and clothing. Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3 Specific end use: None in particular. SECTION 8: Exposure controls/personal protection 8.1 Control parameters: No occupational exposure limit available DNEL exposure limits Substance name End use

Principle Routes of Exposure

Possible health condition Value reaction product: Consumer Human Oral Long-term - systemic effects 0.75 mg/kg bisphenol-A- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) - CAS: 1675-54-3 Consumer Human Oral Short-term - systemic effects 0.75 mg/kg Worker Human Dermal Long-term - systemic effects 8.33 mg/kg Professional Consumer Human Dermal Long-term - systemic effects 3.571 mg/kg Worker Human Dermal Short-term - systemic effects 8.33 mg/kg Professional Consumer Human Dermal Short-term - systemic effects 3.571 mg/kg Worker Human Inhalation Short-term - systemic effects 12.25 mg/m³ Professional oxirane, mono[(C12-14 - Worker Human Inhalation Short-term – local effects 9.8 mg/m3 alkyloxy)methyl] derivs. - Professional CAS: 68609-97-2 Consumer Human Inhalation Short-term – local effects 2.9 mg/m3 Worker Human Dermal Short-term – local effects 68 mg/kg Professional Consumer Human Dermal Short-term – local effects 40 mg/kg Worker Human Inhalation Long-term - systemic effects 29 mg/m3 Professional Consumer Human Inhalation Long-term - systemic effects 7.6 mg/m3 Worker Human Dermal Long-term - systemic effects 17 mg/kg Professional Consumer Human Dermal Long-term - systemic effects 10 mg/kg Reaction mass of Consumer Human Oral Long-term - systemic effects 0.5 mg/kg Bis(1,2,2,6,6-pentamethyl- bw/d 4-piperidyl) sebacate and Methyl 1,2, - CAS: 1065336- 91-5 Worker Human Inhalation Long-term - systemic effects 3.53 mg/m³ Professional Consumer Human Inhalation Long-term - systemic effects 0.87 mg/m³ Worker Human Dermal Long-term - systemic effects 2 mg/kg bw/d Professional Consumer Human Dermal Long-term - systemic effects 1 mg/kg bw/d PNEC exposure limits Substance name Environmental compartment Value reaction product: bisphenol-A- Fresh water 3 mg/l (epichlorhydrin); epoxy resin (number average molecular weight <= 700) - CAS: 1675-54-3 Marine water 0.3 mg/l Freshwater sediments 0.5 mg/l Marine water sediments 0.5 mg/l oxirane, mono[(C12-14 -alkyloxy)methyl] Fresh water 0.72 mg/l derivs. - CAS: 68609-97-2 Marine water 0.00072 mg/l Freshwater sediments 66.77 mg/kg Marine water sediments 6.677 mg/kg Reaction mass of Bis(1,2,2,6,6- Fresh water 0.0022 mg/l pentamethyl-4-piperidyl) sebacate and Methyl 1,2, - CAS: 1065336-91-5 Marine water 0.00022 mg/l Freshwater sediments 1.05 mg/kg Marine water sediments 0.11 mg/kg 8.2 Exposure controls: Eye protection: Wear safety goggles (ref. Standard EN 166). Protection for the skin: Safety shoes. Wear work clothes with long sleeves and safety footwear for professional use of category I (REF. Dir. 89/686/EEC and EN 344). Protection for hands: Protect your hands with work gloves (ref. Directive 89/686 / EEC and its amendments and EN 374/2003). Respiratory protection: Use adequate protective respiratory equipment. (Ref. Dir. 89/686 / EEC, as amended – UNI PROTECTED / 1998 - UNI EN 529/2006). Thermal hazards: None. Environmental exposure controls: Prevent from entering sewers, basements or any place where its accumulation can be dangerous. Appropriate engineering controls: None. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties: Physical state: Liquid Colour: Colourless Odour: Low Melting point/freezing point: Not Relevant Boiling point or initial boiling point and boiling range: > 200°C Flammability: Not Relevant Lower and upper explosion limit: Not Relevant Flash point: > 150°C Auto-ignition temperature: Not Relevant Decomposition temperature: Not Relevant pH: 7 Kinematic viscosity: Not Relevant Solubility in water: Insoluble Solubility in oil: Not Relevant Partition coefficient n-octanol/water (log value): Not Relevant Vapour pressure: Not Relevant Density and/or relative density: 1.12 gr/ml (25°C) Relative vapour density: Not Relevant Particle characteristics: Particle size: Not Relevant

Further information

No other relevant information. SECTION 10: Stability and reactivity 10.1 Reactivity: There are no particular risks of reaction with other substances under normal conditions of use. 10.2 Chemical Stability: The product is stable under normal use and storage conditions. 10.3 Potentially hazardous reactions: None. 10.4 Conditions to avoid Stable under normal conditions. 10.5 Chemically Interacting Materials: None in particular. 10.6 Hazardous decomposition products: None.

TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects: Toxicological information of the product N/A Toxicological information of the main substances contained in the product: reaction product bisphenol-A- (epichlorohydrin); epoxy resin (average molecular weight <= 700) - CAS 25068- 38-6 (a) acute toxicity: Test LD50 - Route Oral - Species Rat = 30,000 mg / kg (i) STOT on repeated exposure: Test NOAEC - Route Oral - Species Rat = 50 mg / kg Test NOAEC - Route Skin - Species Rat = 100 mg / kg oxirane, mono[(C12-14 -alkyloxy)methyl] derivs. - CAS: 68609-97-2 a) acute toxicity: Test LD50 - Route Oral - Species Rat > 26.800 mg/kg Test LC50 - Route Inhalation - Species Rat = 0.15 mg/l - Duration 7H Reaction mass of Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and Methyl 1,2, - CAS: 1065336-91-5 a) acute toxicity: Test LD50 - Route Oral - Species Rat > 3.230 mg/kg If not otherwise specified the information required by Regulation (EU)

ECOLOGICAL INFORMATION

12.1 Toxicity: Apply good working practices so that the product does not end up in the environment. Reaction mass of Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and Methyl 1,2, - CAS: 1065336-91-5 a) Aquatic acute toxicity: Endpoint LC50 - Species Fish 0.9 mg/l - Duration h 96 e) Plant toxicity: Endpoint EC50 - Species Algae 0.22 mg/l - Duration h 72 i) Chronic Daphnia toxicity Endpoint NOEC - Species Daphnia 6.3 mg/l 12.2 Persistence and Degradability: RP 026 UV Biodegradability: No data available. reaction product bisphenol-A- (epichlorohydrin); epoxy resin (average molecular weight <= 700) - CAS 25068- 38-6 Biodegradability: not biodegradable Oxirane, mono [(C12-14-alkyloxy) methyl] derivatives - CAS: 68609-97-2 Biodegradability: Readily biodegradable Reaction mass of Bis(1,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2, - CAS: 1065336-91-5 Biodegradability: No data available. 12.3 Bioaccumulation: RP 026 UV Bioaccumulation: Information not available reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) - CAS: 1675-54-3 Bioaccumulation: Information not available Oxirane, mono [(C12-14-alkyloxy) methyl] derivatives - CAS: 68609-97-2 Bioaccumulation: Information not available Reaction mass of Bis(1,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2, - CAS: 1065336-91-5 Bioaccumulation: Information not available 12.4 Mobility in Soil: RP 026 UV Mobility in soil: No data available reaction product bisphenol-A- (epichlorohydrin); epoxy resin (average molecular weight <= 700) - CAS 25068- 38-6 Mobility in soil: No data available Oxirane, mono [(C12-14-alkyloxy) methyl] derivatives - CAS: 68609-97-2 Mobility in soil: No data available Reaction mass of Bis(1,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2, - CAS: 1065336-91-5 Mobility in soil: No data available

vPvB Substances

None - PBT Substances None 12.6 Endocrine disrupting properties: No endocrine disruptors present in concentration> = 0.1%. 12.7. Other adverse effects None. SECTION 13: Instructions for disposal 13.1 Waste treatment methods: Recover if possible. In so doing, comply with the local and national regulations currently in force.. SECTION 14: Information relating to carriage

UN Number

ADR/RID/ADN: UN 3082 IMDG: UN 3082 IATA: UN 3082 14.2 Proper load name according to UN Model Regulations ADR/RID/ADN: LIQUID DANGEROUS FOR THE ENVIRONMENT, N.O.S. (Epoxy resin) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) IATA: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin) 14.3 Transport hazard class(es) ADR Class: 9 ADR label: 9 ADR - Hazard identification number 90 IATA Class: 9 IATA label: 9 IMDG Class: 9 14.4 Packing group ADR packing group: III IATA Packing group: III IMDG Packing group: III

Environmental hazards

Marine pollutant: Marine pollutant IMDG-EMS: F-S, S-F 14.6 Special precautions for the user ADR Tunnel Restriction Code: E IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS LIQUID, N.O.S. (Epoxy resin) 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code N.A. SECTION 15: Legally required information 15.1 Safety, health and environmental regulations and legislation specific to the substance or mixture Dir. 98/24 / EC (Risks related to chemical agents at work) Dir. 2000/39 / EC (occupational exposure limits)