Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>=20-<25 >=5% >=5% >=5% >=0,1%
EC/CAS
262-967-7/61788-32-7
Name of the chemical
Terphenyl, hydrogenated
Concentration
=10-<12,5 >=1-<3
EC/CAS
920-107-4/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
=0,25-<0,5
EC/CAS
227-534-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
>=5% >=5% >=5% >=0,1%
General Information
Version
8.0
Revision date
2022-08-31
Product name
G 226
1.2.2. Uses advised against
on use
Emergency telephone
070 245 245
Icons in SDS
Company Information
company name
ASSYST bvba
e-mail address of the competent person responsible for the Safety Data Sheet
ao@assyst.org, vera.opsommer@assyst.org
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H304, H315, H317, H319, H332, H334, H335, H351, H373, H411
Hazard statements
Code
Statements
H304
May be fatal if swallowed and enters airways
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Directive (EC) No
Health hazards
Acute toxicity, Category 4 - H332: Harmful by inhalation. Skin corrosion/irritation, Category 2 - H315: Causes skin irritation. Eye irritation, Category 2 - H319: Causes serious eye irritation. Respiratory sensitisation, Category 1 - H334: May cause allergic or asthmatic symptoms or difficulty in breathing if inhaled. Skin sensitisation, Category 1 - H317: May cause an allergic skin reaction. Carcinogenicity, Category 2 - H351: Suspected of causing cancer. Specific target organ toxicity - single exposure, Category 3, Respiratory system - H335: May cause respiratory tract irritation. Specific target organ toxicity - repeated exposure, Category 2 - H373: May cause damage to organs through prolonged or repeated exposure. Danger of inhalation, Category 1 - H304: May be fatal if swallowed and enters airways. Chronic aquatic toxicity, Category 2 - H411: Toxic to aquatic life with long lasting effects. For the full text of H phrases mentioned in this section, see section 16.
2.2 Label elements
Labelling
Signal word
Danger. Hazardous ingredients which must be stated on the label DIPHENYLMETHANE DIISOCYANATE 4,4'-methylenediphenyl diisocyanate MDI modified with tripropylene glycol Bis(isopropyl)naphthalene o-(p-isocyanatobenzyl)phenylisocyanate
Hazard statements
H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful by inhalation. H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
Prevention
P260 Do not breathe dust/smoke/gas/vapour/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Action: P301 + P310 IF SWALLOWED: Call a POISON CENTER/physician immediately. P304 + P340 + P312 IF INHALED: Remove the person to fresh air and make sure he can breathe easily. If you feel unwell, call a POISON CENTER/physician. P308 + P313 IF exposed or liable to be exposed: Call a doctor. P331 DO NOT induce vomiting. P391 Clean up spillage/leakage.
Additional information
EUH204 .Contains isocyanates. May cause allergic reaction. "By 24 August 2023, appropriate training must be completed for industrial or professional use".
2.3 Other hazards
This substance/mixture does not contain any components that can be considered persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
