Crotonaldehyde

Hazard statements (CLP)

H225, H301, H311, H315, H318, H330, H335, H341, H373, H400

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Directive 67/548/EEC: This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation, GHS).***

2.1 Classification of the substance or mixture

Category Flammable liquid Category 2 Acute oral toxicity Category 3 Acute dermal toxicity Category 1 Acute inhalation toxicity Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Germ cell mutagenicity Category 2 Specific target organ systemic toxicity (single exposure) Category 3 Specific target organ systemic toxicity (repeated exposure) Category 2 Acute aquatic toxicity Category 1

Hazard statements

H225 - Highly flammable liquid and vapor H301 - Toxic if swallowed H311 – Toxic if there is contact with skin H330 - Fatal if inhaled H315 - Causes skin irritation H318 - Causes serious eye damage H341 - Suspected of causing genetic defects H335 - May cause respiratory irritation H373 - May cause damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life *** Mutagenic. CAT. 3 Highly flammable Very Toxic Dangerous for the environment R48/22 -Harmful: danger of serious damage to health by prolonged

Precautionary statements

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P273 - Avoid release to the environment P281 - Use personal protective equipment as required P284 - Wear respiratory protection P308 + P313 - IF exposed or concerned: Get medical advice/ attention ***

2.3 Other hazards

The substance does not meet the criteria for PBT / vPvB according to REACH, Annex XIII Classification and labelling (according to Directive 67/548/EWG or 1999/45/EC) This substance is classified and labelled according to Annex I of Directive 67/548/EEC, as amended***

R-phrase(s)

R11 -Highly flammable. R24/25 -Toxic in contact with skin and if swallowed. R26 -Very toxic by inhalation. R37/38 -Irritating to respiratory system and skin. R41 -Risk of serious damage to eyes. R50 exposure If swallowed. -Very toxic to aquatic organisms. R68 -Possible risks of irreversible effects.

S-phrase(s)

S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28.2 - After contact with skin, wash immediately with plenty of soap and water. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets***