PLIOBOND 2820 TPO BONDING ADHESIVE 634340

SECTION 2: Hazards identification

Emergency Overview Appearance: liquid,, amber DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY BE HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN, CAUSE IRRITATION AND BURNS.

Principle Routes of Exposure

Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye uritation. Symptoms include stinging, tearing, redness, and swelling of eyes. Skin contact Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, and drying and cracking of skin, burns and other skin damage. Ingestion -> 802 375 1369 Page 3 of 14 ASHLARID Page: 2 Safety data sheet revision date 11/19/2008 Print Date: 9/1/2010 MSDS Number: 00000009743 1 PLIOBOND® 2820 TPO BONDING Version: 2.0 ADHESIVE 634340 Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury. Inhalation Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).

Medical Conditions Generally Aggravated by Exposure

Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Upper respiratory tract, Skin, lung (for example, asthma-like conditions), Liver, kidney, Central nervous system, blood-forming system, male reproductive system, auditory system, Individuals with preexisting heart disorders maybe more susceptible to arrhythmias (irregular heartbeats) if exposed to high concentrations of this material. Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, metallic taste, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), runny nose, discomfort in the chest, high blood sugar, central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, Weakness, temporary changes in mood and behavior, loss of appetite, Lack of coordination, confusion, narcosis (dazed or sluggish feeling), respiratory depression (slowing of the breathing rate), irregular heartbeat, anesthesia, coma Target Organs Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans., This material (or a component) shortens the time of onset or worsens the liver and kidney damage induced by other chemicals., Prolonged and repeated exposure to n-hexane may cause peripheral neuropathy by damaging peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of sensation., Prolonged intentional toluene abuse may lead to hearing loss progressing to deafness. In addition, while noise is known to cause hearing loss in humans, it has been suggested that workers exposed to organic solvents, -> 802 375 1360 Page 4 of 14 SAFETY DATA SHEET Safety data sheet revision date 11/19/2008 Print Date: 9/1/2010 MSDS Number: 00000009743 1 PLIOBOND® 2820 TPO BONDING Version: 2.0 ADHESIVE 634340 including toluene, along with noise may suffer greater hearing loss than would be expected from exposure to noise alone., Prolonged intentional toluene abuse may lead to damage to many organ systems having effects on: central and peripheral nervous systems, vision, hearing, liver, kidneys, heart and blood. Such abuse has been associated with brain damage characterized by disturbances in gait, personality changes and loss of memory. Comparable central nervous system effects have not been shown to result from occupational exposure to toluene., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, blood abnormalities, effects on hearing, nasal damage, respiratory tract damage (nose, throat, and airways), nervous system damage, liver damage, liver abnormalities, kidney damage, kidney abnormalities, testis damage, central nervous system damage, lung damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, kidney damage, visual impairment, central nervous system effects Carcinogenicity Ethylbenzene has been shown to cause cancer in laboratory animals. The relevance of this finding to humans is uncertain. The International Agency for Research on Cancer ([ARC) has classified ethylbenzene as a possible human carcinogen. Reproductive hazard Toluene may be harmful to the human fetus based on positive test results with laboratory animals. Case studies show that prolonged intentional abuse of toluene during pregnancy can cause birth defects in humans.