ISOSET® WD3 A322 ADHESIVE

Ashland

Revision date : 2008-02-29

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Note: Ingredients listed on restricted chemical lists

EC/CAS

14464-46-1

Name of the chemical

Cristobalit (s. u. TRGS 906)

Concentration

>=0.1-<0.5%

General Information

Version

1.4

Revision date

2008-02-29

Product name

ISOSET® WD3 A322 ADHESIVE

1.2.2. Uses advised against

No data

Emergency telephone

(1-800-274-5263

Icons in SDS

Company Information

company name

Ashland

Section 2

SECTION 2: Hazards identification

Emergency Overview Appearance: liquid CAUTION! MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE EYE IRRITATION.

Principle Routes of Exposure

Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion Eye contact Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes. Skin contact Can cause skin irritation. Symptoms may include redness and burning of skin, and other skin damage. May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, drying and cracking of skin, and skin burns. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get 33490 into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury. Inhalation Breathing of vapor or mist is possible. It is possible to breathe this material under certain conditions of handling and use (for example, during heating, spraying, or stirring). Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.). Prolonged or repeated breathing of dust may result in progressive and permanent lung disease (fibrosis) which may cause death from respiratory and/or heart failure. Symptoms include coughing and difficult breathing which becomes worse with physical activity. Another form of fibrosis, acute silicosis, can occur with exposures to very high concentrations of respirable silica over shorter periods of time, sometimes as short as a few months. Symptoms of acute silicosis include progressive shortness of breath, fever, cough and weight loss. Acute silicosis is fatal.

Medical Conditions Generally Aggravated by Exposure

Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, upper respiratory tract, Skin, lung (for example, asthma-like conditions), kidney, Central nervous system, auditory system, Individuals with preexisting heart disorders maybe more susceptible to arrhythmias (irregular heartbeats) if exposed to high concentrations of this material., Silicosis predisposes the individual to the development mycobacterial infections including tuberculosis or to fungal infections. This is most likely to occur after the age of 50 and in association with moderate to severe silicosis. Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, metallic taste, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), central nervous system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, temporary changes in mood and behavior, weakness, lack of coordination, confusion, irregular heartbeat, coma, and death Target Organs Prolonged intentional toluene abuse may lead to damage to many organ systems having effects on: central and peripheral nervous systems, vision, hearing, liver, kidneys, heart and blood. Such abuse has been associated with brain damage characterized by 33490 disturbances in gait, personality changes and loss of memory. Comparable central nervous system effects have not been shown to result from occupational exposure to toluene., Prolonged intentional toluene abuse may lead to hearing loss progressing to deafness. In addition, while noise is known to cause hearing loss in humans, it has been suggested that workers exposed to organic solvents, including toluene, along with noise may suffer greater hearing loss than would be expected from exposure to noise alone., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, mild, reversible liver effects, mild, reversible kidney effects, respiratory tract damage (nose, throat, and airways), effects on hearing, central nervous system damage, Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans:, chronic bronchitis, emphysema, kidney damage Carcinogenicity The International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP) have determined that there is sufficient evidence in humans for the carcinogenicity of inhaled crystalline silica in the form of quartz or cristobalite. In addition, IARC has determined that there is sufficient evidence for the carcinogenicity of quartz and cristobalite in experimental animals. Among individuals with silicosis, lung cancer occurs more frequently in those who smoke. Reproductive hazard There are no data available for assessing risk to the fetus from maternal exposure to this material.

Further information

Breathing spray from emulsions may cause deposition in the lung. Respirators should be provided if engineering controls are not adequate. Residual monomer content under conditions of normal handling present no problem; however, high levels of monomer vapors can be released into workroom air when emulsions are heat cured or dried (rollers, ovens, infrared lamp, etc.). There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of immunological disorders and autoimmune diseases such as scleroderma (a disorder manifested by fibrosis of the lungs, skin and other internal organs), systemic lupus erythematosis and sarcoidosis (chronic inflammatory diseases).

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