ECKOSIL Liquid fertilizer with micronutriens

ASFERTGLOBAL, LDA

Revision date : 2017-12-14

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2017-12-14

Product name

ECKOSIL Liquid fertilizer with micronutriens

Icons in SDS

M004 M009 M010 M011

Company Information

company name

ASFERTGLOBAL, LDA

e-mail address of the competent person responsible for the Safety Data Sheet

anapereira@asfert.pt

Section 2

SECTION 2: Hazards identification

No 1272/2008 Classification of the mixture

2.2 Label elements

P102: Keep out of the reach of children. P270: Do not eat, drink or smoke during use. Store at a temperature of not more than 30 ° C or less than 5 ° C. Keep away from sunlight. Keep away from food, drink and animal feeding stuffs. In case of contact with eyes and mucous membranes, rinse immediately with plenty of water and seek medical advice. In case of contact with skin, wash immediately with plenty of water. Wear suitable gloves. Wear eye / face protection. In case of accident or illness, seek medical advice immediately and show this product label. Use only in case of recognized need. Do not exceed recommended dosages. .

Supplemental label elements

EUH210 Safety data sheet available on request.

2.3 Other hazards

In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment.

2.1 Classification of the substance or mixture

The product is not classified as hazardous within the meaning of Regulation (EU) No 1272/2008. 2.2 Label elements. P102: Keep out of the reach of children. P270: Do not eat, drink or smoke during use. Store at a temperature of not more than 30 ° C or less than 5 ° C. Keep away from sunlight. Keep away from food, drink and animal feeding stuffs. In case of contact with eyes and mucous membranes, rinse immediately with plenty of water and seek medical advice. In case of contact with skin, wash immediately with plenty of water. Wear suitable gloves. Wear eye / face protection. In case of accident or illness, seek medical advice immediately and show this product label. Use only in case of recognized need. Do not exceed recommended dosages. . EUH statements: EUH210 Safety data sheet available on request. 2.3 Other hazards. In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS. 3.1 Substances. Not Applicable. 3.2 Mixtures. This mixture does not contain substances that represent a health or environmental hazard according to Regulation (EC) No. 1272/2008, are assigned a community exposure limit in the workplace, nor are they classified as PBT / vPvB or included in the Candidate List. SECTION 4: FIRST AID MEASURES. 4.1 Description of first aid measures. Due to the composition and type of the substances present in the product, no particular warnings are necessary. Inhalation. Take the victim into open air; keep them warm and calm. If breathing is irregular or stops, perform artificial respiration. Do not administer anything orally. If unconscious, place them in a suitable position and seek medical assistance. Eye contact. If wearing contact lenses, remove them. Wash eyes with plenty of clean and cool water for at least 10 minutes while pulling eyelids up, and seek medical assistance. Skin contact. Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. NEVER use solvents or thinners. Ingestion. If accidentally ingested, seek immediate medical attention. Keep calm. NEVER induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed. No known acute or delayed effects from exposure to the product. 4.3 Indication of any immediate medical attention and special treatment needed. In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons who are unconscious. SECTION 5: FIREFIGHTING MEASURES. 5.1 Extinguishing media. Recommended extinguishing methods. Extinguisher powder or CO2. In case of more serious fires, also alcohol-resistant foam and water spray. Do not use a direct stream of water to extinguish. 5.2 Special hazards arising from the mixture. Special risks. Fire can cause thick, black smoke. As a result of thermal decomposition, dangerous products can form: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products can be harmful to your health. 5.3 Advice for firefighters. Use water to cool tanks, cisterns, or containers close to the heat source or fire. Take wind direction into account. Prevent the products used to fight the fire from going into drains, sewers, or waterways. Fire protection equipment. According to the size of the fire, it may be necessary to use protective suits against the heat, individual breathing equipment, gloves, protective goggles or facemasks, and gloves. SECTION 6: ACCIDENTAL RELEASE MEASURES. 6.1 Personal precautions, protective equipment and emergency procedures. For exposure control and individual protection measures, see section 8. 6.2 Environmental precautions. Product not classified as hazardous for the environment, avoid spillage as much as possible. 6.3 Methods and material for containment and cleaning up. Pick up the spill with non-combustible absorbent materials (soil, sand, vermiculite, diatomite, etc.). Pour the product and the absorbent in an appropriate container. The contaminated area should be immediately cleaned with an appropriate de- contaminator. Pour the decontaminator on the remains in an opened container and let it act various days until no further reaction is produced. 6.4 Reference to other sections. For exposure control and individual protection measures, see section 8. For later elimination of waste, follow the recommendations under section 13. SECTION 7: HANDLING AND STORAGE. 7.1 Precautions for safe handling. The product does not require special handling measures, the following general measures are recommended: For personal protection, see section 8. Never use pressure to empty the containers. They are not pressure-resistant containers. In the application area, smoking, eating, and drinking must be prohibited. Follow legislation on occupational health and safety. Keep the product in containers made of a material identical to the original. 7.2 Conditions for safe storage, including any incompatibilities. The product does not require special storage measures. As general storage measures, sources of heat, radiation, electricity and contact with food should be avoided. Keep away from oxidising agents and from highly acidic or alkaline materials. Store the containers between 5 and 35º C, in a dry and well-ventilated place. Store according to local legislation. Observe indications on the label. The product is not affected by Directive 2012/18/EU (SEVESO III). 7.3 Specific end use(s). Fertilizer. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. 8.1 Control parameters. The product does NOT contain substances with Professional Exposure Environmental Limit Values.The product does NOT contain substances with Biological Limit Values. 8.2 Exposure controls. Measures of a technical nature: Provide adequate ventilation, which can be achieved by using good local exhaust-ventilation and a good general exhaust system. HAND PROTECTION: PPE: Protective gloves. Characteristics: CE marking, category II. CEN standards: EN 374-1, En 374-2, EN 374-3, EN 420 Maintenance: Keep in a dry place, away from any sources of heat, and avoid exposure to sunlight as much as possible. Do not make any changes to the gloves that may alter their resistance, or apply paints, solvents or adhesives. Observations: Gloves should be of the appropriate size and fit the user's hand well, not being too loose or too tight. Always use with clean, dry hands. Material: PVC (polyvinyl chloride) Breakthrough time (min.): > 480 Material thickness (mm): 0,35 EYE PROTECTION: PPE: Protective goggles with built-in frame. Characteristics: CE marking, category II. Eye protector with built-in frame for protection against dust, smoke, fog and vapour. CEN standards: EN 165, EN 166, EN 167, EN 168 Maintenance: Visibility through lenses should be ideal. Therefore, these parts should be cleaned daily. Protectors should be disinfected periodically following the manufacturer's instructions. Observations: Some signs of wear and tear include: yellow colouring of the lenses, superficial scratching of the lenses, scraping etc. SKIN PROTECTION: PPE: Protective clothing. Characteristics: CE marking, category II. Protective clothing should not be too tight or loose in order not to obstruct the user's movements. CEN standards: EN 340 Maintenance: In order to guarantee uniform protection, follow the washing and maintenance instructions provided by the manufacturer. Observations: The protective clothing should offer a level of comfort in line with the level of protection provided in terms of the hazard against which it protects, bearing in mind environmental conditions, the user's level of activity and the expected time of use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES. 9.1 Information on basic physical and chemical properties. Appearance:Liquid Colour: Dark RED Odour:Characteristic Odour threshold:N.A./N.A. pH:3.5 (1/10) Melting point:N.A./N.A. Boiling Point: >=111 ºC Flash point: >562 ºC Evaporation rate: N.A./N.A. Inflammability (solid, gas): N.A./N.A. Lower Explosive Limit: N.A./N.A. Upper Explosive Limit: N.A./N.A. Vapour pressure: 23,422 Vapour density:N.A./N.A. Relative density:1,20 g/cm3 Solubility:Soluble Liposolubility: N.A./N.A. Hydrosolubility: N.A./N.A. Partition coefficient (n-octanol/water): N.A./N.A. Auto-ignition temperature: N.A./N.A. Decomposition temperature: N.A./N.A. Viscosity: 100 Explosive properties: N.A./N.A. Oxidizing properties: N.A./N.A. N.A./N.A.= Not Available/Not Applicable due to the nature of the product 9.2 Other information. Pour point: N.A./N.A. Blink: N.A./N.A. Kinematic viscosity: N.A./N.A. N.A./N.A.= Not Available/Not Applicable due to the nature of the product SECTION 10: STABILITY AND REACTIVITY. 10.1 Reactivity. The product does not present hazards by their reactivity. 10.2 Chemical stability. Stable under the recommended handling and storage conditions (see section 7). 10.3 Possibility of hazardous reactions. The product does not present possibility of hazardous reactions. 10.4 Conditions to avoid. Avoid any improper handling. 10.5 Incompatible materials. Keep away from oxidising agents and from highly alkaline or acidic materials in order to prevent exothermic reactions. 10.6 Hazardous decomposition products. No decomposition if used for the intended uses. SECTION 11: TOXICOLOGICAL INFORMATION. 11.1 Information on toxicological effects. There are no tested data available on the product. Repeated or prolonged contact with the product can cause the elimination of oil from the skin, giving rise to non-allergic contact dermatitis and absorption of the product through the skin. Splatters in the eyes can cause irritation and reversible damage. a) acute toxicity; Not conclusive data for classification. Acute Toxicity Estimate (ATE): Mixtures: ATE (Oral) > 10.000 mg/kg b) skin corrosion/irritation; Not conclusive data for classification. c) serious eye damage/irritation; Based on available data, the classification criteria are not met. d) respiratory or skin sensitisation; Not conclusive data for classification. e) germ cell mutagenicity; Not conclusive data for classification. f) carcinogenicity; Not conclusive data for classification. g) reproductive toxicity; Not conclusive data for classification. h) STOT-single exposure; Not conclusive data for classification. i) STOT-repeated exposure; Not conclusive data for classification. j) aspiration hazard; Not conclusive data for classification. SECTION 12: ECOLOGICAL INFORMATION. 12.1 Toxicity. No information is available regarding the ecotoxicity of the substances present. 12.2 Persistence and degradability. No information is available about persistence and degradability of the product.

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