Clethodim 120 g/L EC

Hazard statements (CLP)

H304, H336, H411

Code

Statements

H304

May be fatal if swallowed and enters airways

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects

Hazard pictograms

GHS07 GHS08 GHS09

Signal word

Danger

Contains

Hydrocarbons, C10, aromatics, <1% naphthalene, Hydrocarbons, C10-C13, aromatics, <1% naphthalene

Hazard statements

H304 - May be fatal if swallowed and enters airways. H336 - May cause drowsiness or dizziness. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing mist, spray. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 - Call a POISON CENTRE or doctor if you feel unwell. P331 - Do NOT induce vomiting. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Supplemental label elements

EUH401 - To avoid risks to human health and the environment, comply with the instructions for use. EUH066 - Repeated exposure may cause skin dryness or cracking. EUH208 - Contains Clethodim (ISO); (5RS)-2-{(1EZ)-1-[(2E)-3-chloroallyloxyimino]propyl}- 5-[(2RS)-2-(ethylthio)propyl]-3-hydroxycyclohex-2-en-1-one. May produce an allergic reaction.

Other hazards which do not result in classification

Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Component Clethodim (ISO); (5RS)-2-{(1EZ)-1-[(2E)-3- chloroallyloxyimino]propyl}-5-[(2RS)-2- (ethylthio)propyl]-3-hydroxycyclohex-2-en-1-one (99129-21-2) PBT/vPvB assessment not available as chemical safety assessment not conducted Component Hydrocarbons, C10-C13, aromatics, <1% naphthalene This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Specific target organ toxicity – Single exposure, Category 3, Narcosis H336 Aspiration hazard, Category 1 H304 Hazardous to the aquatic environment – Chronic Hazard, Category 2 H411 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects.