5-Amino-4H-1,2,4-triazole-3-carboxylic acid

Hazard statements (CLP)

H302, H315, H317, H319, H334, H335

Code

Statements

H302

Harmful if swallowed

H315

Causes skin irritation

H317

May cause an allergic skin reaction

H319

Causes serious eye irritation

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335

May cause respiratory irritation

SECTION 2: Hazards identification

Directive 67/548/EEC: Classification of the substance or mixture

Signal word

Danger

Hazard statements

H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P330 Rinse mouth. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P362 Take off contaminated clothing and wash before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to in accordance with local regulation 2.3 Associated risk phrases according to european directive 67/548/EEC

R-phrase(s)

R22 Harmful if swallowed. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R42 May cause sensitization by inhalation. R43 May cause sensitization by skin contact.

S-phrase(s)

S1 Keep locked up. S20/21 When using do not eat, drink or smoke. S23 Do not breathe gas/fumes/vapour/spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 Take off immediately all contaminated clothing. S28 After contact with skin, wash immediately with plenty of water. S28B After contact with skin, wash immediately with plenty of water and soap. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S44 If you feel unwell, seek medical advice (show the label where possible). S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets. S7/9 Keep container tightly closed and in a well-ventilated place

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Acute toxicity, oral(Category 4) H302 Skin corrosion/irritation(Category 2) H315 Sensitisation, skin(Category 1A) H317 Serious eye damage/eye irritation(Category 2A ) H319 Sensitisation, respiratory(Category 1A) H334 STOT- single exposure(Category 3) H335 No Resource File