Chemical Characterization: EPOXY RESIN (IRRITANT) “COMPONENT-A”

Hazard statements (CLP)

H315, H317, H319

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2 H315: Causes skin irritation Skin sensitization, Category 1 H317: May cause an allergic skin reaction Eye irritation, Category 2A H319: Causes serious eye irritation GHS Label element: Hazard Pictograms Signal Word: Warning Hazard Statements: H315: Causes skin irritation H317: May cause an allergic skin reaction H319: Causes serious eye irritation Precautionary Statements: Prevention: P102: Keep out of reach of children. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear eye protection/face protection. P280: Wear protective gloves. P272: Contaminated work clothing should not be allowed out of the workplace. P281: Use protective equipment as required. Response: P301 + P315: IF SWALLOWED: Get immediate medical advice/attention. P302 + P352: IF ON SKIN: Wash with plenty of water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned, get medical advice/attention. P332 + P313: IF skin irritation occurs, get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Storage: P403 + P232: Store in a well-ventilated place. Protect from moisture. Disposal: P501: Dispose of contents/container to an approved waste disposal site. P502: Refer to manufacturer/supplier for information on recovery/recycling. Section 3 – Composition / Information on Ingredients Description: Solvent-free preparation based on bisphenol-A-epichlorhydrin resin molecular weight ≤700. COMPONENTS CAS NUMBER OSHA PEL ACGIH TLV WEIGHT % Bisphenol-A-epichlorhydrin 25068-38-6 Not Estab. 50-100% 1,6-bis(2,3-ethoxypropoxy)hexane 16096-31-4 Not Estab. 10-25% Diisopropylnaphthalene 38640-62-9 Not Estab. Not Eastab. 10-25% aliphatic trimethyol-propantriglydylether 30499-70-8 Not Estab. Not Eastab. 10-25% bisphenol-F-epoxy resin 9003-36-5 Not Estab. 2.5-10% Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 4 – First Aid Measures After Inhalation: Remove subject to fresh air. Administer oxygen if difficulty with breathing. Consult a physician. After Ingestion: Immediately seek medical attention. Do not induce vomiting. Drink plenty of water to dilute stomach contents. After Skin Contact: Instantly wash skin with plenty of soap and water for at least 15 minutes. Wash clothing before reuse. After Eye Contact: Rinse opened eye with plenty of running water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses. Consult physician. Section 5 – Fire Fighting Measures Extinguishing Media: Carbon dioxide (CO2), extinguishing powder, water fog. Do not use full water jet. Special Fire Fighting Procedures: As in any fire, wear full protective gear and NIOSH-approved self- contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode. Unusual Fire and Explosion Hazards: Bursting and explosion of container possible due to increase of pressure when exposed to increasing heat. In case of fire, cool nearby containers with water fog. Formation of poisonous gases during heating or in fires. Section 6 – Accidental Release Measures Person-related Safety Precautions: Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation of vapors. Wear personal protective equipment. Remove or eliminate all ignition sources. Emergency procedures are not required. Methods for Cleaning up: Contain and collect spillage with non-combustible, absorbent materials. I.e. sand, earth, vermiculate, diatomaceous earth, universal binders, sawdust and place in container for disposal. Waste Disposal Method: Dispose in accordance with local, state and federal regulations. Ecological Information: Do not allow product to reach ground water, bodies of water, or storm water or sewage systems. Section 7 – Handling and Storage Handling: Avoid eye and skin contact. Keep out of reach of children. Storage: Store in a cool, dry enclosed area off the ground in tightly closed containers. No special measures required against explosion and fires. Store away from foodstuffs. Provide fresh air when handling in closed rooms (open windows and doors). Section 8 – Exposure Controls / Personal Protection Engineering Controls: Use with adequate general and local exhaust ventilation. Washing of the skin in the working area must be possible. Eye-wash station or bottle must be available. Respiratory Protection: Respirator in well ventilated areas not necessary. Wear a properly fitted NIOSH approved respirator in poorly ventilated areas or spillage. Skin Protection: When installing, wear appropriate protective rubber or plastic gloves to prevent hand-skin exposure. Wear appropriate impervious clothing to prevent skin exposure (long sleeve shirt and long pants). Eye Protection: Wear tightly sealed safety glasses with side shields or goggles. Face shield as necessary. Work/Hygienic Practices: Wash hands before breaks and after work, and before eating, drinking or smoking. Section 9 – Physical and Chemical Properties Physical State: Liquid Appearance/Color: Clear Odor: Weak, characteristic Solubility in water: Not or slightly miscible Boiling Point: Not determined Melting Point: Not determined o >100o C (>212 F) Flash Point: Flammability: Does not self-ignite Explosion: Does not explode Bulk Density: 1.12 kg/dm3 at 20oC (68oF) Viscosity: (dynamic) 495 cps (mPas) at 20oC (68oF) VOC Concentration: 0 g/l Section 10 – Stability and Reactivity Chemical Stability: Stable under normal conditions. Conditions to Avoid: Keep away from heat, ignition sources and incompatible materials. Hazardous Decomposition: Dangerous emissions of various decomposition products can be formed when exposed to heat. Incompatibilities: Avoid contact with acids and oxidizers. Section 11 – Toxicological Information Acute Toxicity: 25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) Oral LD50 >5000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rat) 16096-31-4 1,6-bis(2,3-ethoypropoxy)hexane Oral LD50 1400 mg/kg (rabbit) LD50 2900 mg/kg (rat) Inhalative LC50/4 h >100 mg/l (mouse) 9003-36-5 bisphenol F-epoxy resin Oral LD50 >5000 mg/kg (rat) Primary Irritation: - Skin: irritates skin and mucous membrane. - Eyes: irritating - Sensibility: sensibility through contact with skin possible. Section 12 – Ecological Information Aquatic toxicity: 25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) EC50 (24 h) 3.6 mg/l (Daphnia magna) LC50 (96 h) 1.5 mg/l (Rainbow trout) 9003-36-5 bisphenol F-epoxy resin EC50 2 mg/l (Daphnia (acute) toxicity)) LC50 (96 h) 2 mg/l (Fish toxicity) Persistence and degradability: 25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) 301B (Mod. Sturm) 12% (-) Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available. Remark: Toxic for fish. Do not allow product or large quantities to reach into waterways or drains. General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, bodies of water, or storm water or sewage systems. Section 13 – Disposal Considerations Waste Disposal Method: Dispose of in a manner consistent with federal, state and local regulations. This includes pails containing uncured material. Pails with cured/hardened remains of product can be sent for recycling. Recommendation: Product mixed with hardener and fully cured is ecologically save and can be disposed to local refuse deposit or recycling facility. Section 14 – Transport Information USDOT (Domestic Surface): UN 3082 Not regulated. IATA/ICAO (Air): UN 3082 Environmentally hazardous substance, liquid, NOS (bisphenol A-(epichlorhydrin), epoxy resin (number average molecular weight<700), 1,6- Hexandioldiglycidylether. 9, PG III. IMDG (Ocean): UN 3082 Environmentally hazardous substance, liquid, NOS (bisphenol A-(epichlorhydrin), epoxy resin (number average molecular weight<700), 1,6- Hexandioldiglycidylether. Marine pollutant. 9, PG III. Section 15 – Regulatory Information . All raw materials are on the U.S., EPA, TSCA Inventory. SARA Notification: Nothing in this product is subject to regulation under SARA 302, 313. It may be subject to SARA 312 reporting, depending upon the purchaser’s storage circumstances. CERCLA: No CERCLA chemicals exist in this product above reportable concentrations. Clean Air Act Ozone-Depletion Potential: This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section (40 CFR 61). Section 16 – Other Information (Hazard Rating: 0 = Minimal; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe; * = Chronic) HMIS III rating: Health: 2* Flammability: 1 Physical hazard: 1 Abbreviations and acronyms: USDOT: United States Department of Transportation. IMDG: International Maritime Code for Dangerous Goods. IATA: International Air Transport Association. CAS: Chemical Abstracts Service (Division of the American Chemical Society). LC50: Lethal concentration, 50 percent. LD50: Lethal dose, 50 percent. EC50: Median effective concentration. RQ: Reportable quantity. SDS prepared by: Aquafin product safety department. DISCLAIMER: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. END OF SDS (January 22, 2019) Chemical Characterization: EPOXY HARDENER (CORROSIVE) “COMPONENT-B” AQUAFIN, INC. 24 hr Emergency Phone: Chem-Tel (800) 255-3924 505 BLUE BALL RD NO. 160 Information Phone No: (410) 392-2300 ELKTON, MD 21921 info@aquafin.net www.aquafin.net Recommended use of the chemical and restriction on use: Refer to the product technical data sheet. For industrial and professional users. Section 2 – Hazards Identification GHS Classification: Acute toxicity, Category 4 (oral) H302: Harmful if swallowed. Skin corrosion/irritation, Category 1B H314: Causes severe skin burns and eye damage. Skin sensitization, Category 1 H317: May cause an allergic skin reaction. Serious eye damage, Category 1 H318: Causes serious eye damage. Reproductive toxicity, Category 2 H361: Suspected of damaging fertility or the unborn child. GHS Label element: Hazard Pictograms GHS05 GHS07 GHS08 Signal Word: Danger Hazard Statements: H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H361: Suspected of damaging fertility or the unborn child. Precautionary Statements: Prevention: P102: Keep out of reach of children. P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P272: Contaminated work clothing should not be allowed out of the workplace. P281: Use protective equipment as required. Response: P301 + P315: IF SWALLOWED: Get immediate medical advice/attention. P330 + P331: Rinse mouth. Do NOT induce vomiting. P302 + P352 = P361: IF ON SKIN: Remove/Take off immediately all contaminated clothing. Wash with plenty of water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned, get medical advice/attention. P332 + P313: IF skin irritation occurs, get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Storage: P403: Store in a well-ventilated place. P405: Store locked up. Disposal: P501: Dispose of contents/container to an approved waste disposal site. P502: Refer to manufacturer/supplier for information on recovery/recycling. Section 3 – Composition / Information on Hazardous Ingredients COMPONENTS CAS NUMBER WEIGHT 4-Tert-Butylphenol 98-54-4 2.5-10% m-phenylenebis(methylamine) 1477-55-0 2.5-10% 2,4,6-Tris-(dimethylaminomethyl)phenol 90-72-2 2.5-10% Trimethylhexane-1,6-diamine 25620-58-0 2.5-10% N’-(3-Aminopropyl)-N,N-dimethylpropane-1,3-diamine 10563-29-8 2.5-10% Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 4 – First Aid Measures General Advise: Immediately remove contaminated clothing. Exposure symptoms can appear after several hours. If contaminated consult medical advise up to 48 hours after exposure. First Aid: Wear protective equipment (i.e. protective gloves). If victim is unconscious: position and transport in “stable sideways position” to prevent asphyxiation if vomiting. Keep air passages open, remove dentures and vomit. Control breathing and pulse. If breathing and heart activity stops, administer CPR and call immediately emergency services. After Inhalation: Remove subject to fresh air. Administer oxygen if difficulty with breathing. Consult a physician. After Ingestion: Immediately seek medical attention. Do not induce vomiting. Drink plenty of water to dilute stomach contents. After Skin Contact: Instantly wash skin with plenty of soap and water for at least 15 minutes. Wash clothing before reuse. After Eye Contact: Rinse opened eye with plenty of running water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses. Consult physician. Section 5 – Fire Fighting Measures Extinguishing Media: Carbon dioxide (CO2), extinguishing powder, water spray. Do not use full water jet. Special Fire Fighting Procedures: As in any fire, wear full protective gear and NIOSH-approved self- contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode. Unusual Fire and Explosion Hazards: Bursting and explosion of container possible due to increase of pressure when exposed to increasing heat. In case of fire, cool nearby containers with water fog. Formation of poisonous gases during heating or in fires possible. Section 6 – Accidental Release Measures Person-related Safety Precautions: Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation of vapors. Wear personal protective equipment. Remove or eliminate all ignition sources. Methods for Cleaning up: Contain and collect spillage with non-combustible, absorbent materials. I.e. sand, earth, vermiculate, diatomaceous earth, universal binders, sawdust and place in container for disposal. Waste Disposal Method: Dispose in accordance with local, state and federal regulations. Ecological Information: Do not allow product to reach ground water, bodies of water, storm water or sewage systems. Section 7 – Handling and Storage Handling: Avoid eye and skin contact. Keep out of reach of children. Storage: Store in a cool, dry enclosed area off the ground in tightly closed containers. No special measures required against explosion and fires. Store away from foodstuffs. Provide fresh air when handling in closed rooms (open windows and doors). Materials to avoid: No data available. Section 8 – Exposure Controls / Personal Protection Engineering Controls: Use with adequate general and local exhaust ventilation. Washing of the skin in the working area must be possible. Eye-wash station or bottle must be available. CAS NUMBER OSHA PEL ACGIH TLV WEIGHT m-phenylenebis(methylamine): 1477-55-0 0.1 mg/m3 2.5-10% Respiratory Protection: Respirator in well ventilated areas not necessary. Wear a properly fitted NIOSH approved respirator in poorly ventilated areas or spillage. Skin Protection: When installing, wear appropriate impervious gloves (neoprene) to prevent hand- skin exposure. Wear appropriate impervious clothing (acid and alkaline resistant) to prevent skin exposure (long sleeve shirt and long pants). Eye Protection: Wear chemical splash goggles. Face shield as necessary. Work/Hygienic Practices: Wash hands before breaks and after work, and before eating, drinking or smoking. Know the locations of eye wash fountains and emergency showers. Section 9 – Physical and Chemical Properties Physical State: Liquid Appearance/Color: Yellowish Odor: Amine like Solubility in water: Not miscible or difficult to mix Flash Point: o >120o C (>248 F) Flammability: Product is not self-igniting Danger of explosion: Product is not explosive Boiling Point: Not determined Melting Point: Not determined Bulk Density: 0.99 g/cm3 at 20oC (68oF) Viscosity: (dynamic) 1400 cps (mPas) at 20oC (68oF) VOC Concentration: 0 g/l Section 10 – Stability and Reactivity Chemical Stability: Stable under normal conditions. Conditions to Avoid: Keep away from heat and ignition sources. Hazardous Decomposition: No dangerous decomposition or emission products known if product handled as per specifications. Incompatibilities: No dangerous reactions known. Section 11 – Toxicological Information Acute Toxicity: 98-54-4 4-tert-Butylphenole Oral LD50 2951 mg/kg (rat) Dermal LD50 2288 mg/kg (rabbit) Primary Irritation: - Skin: Corrosive on skin and mucous membrane. Irritates skin and mucous membrane. - Eyes: Strong corrosive reaction. - Sensibility: Sensibility through contact with skin possible. Additional Information: If ingested, highly corrosive to mouth and throat, as well as danger or perforation to esophagus and stomach. Section 12 – Ecological Information Environment: Toxic to aquatic systems. Do not allow product to reach into natural waterways, drains, storm water or wastewater systems. General notes: Water hazard class 2 (Self-assessment): hazardous for water. Section 13 – Disposal Considerations Waste Disposal Method: Dispose of in a manner consistent with federal, state and local regulations. This includes pails containing uncured material. Pails with cured/hardened remains of product can be sent for recycling. Recommendation: Product mixed with resin and fully cured is ecologically safe and can be disposed to local refuse deposit. Section 14 – Transport Information USDOT (Domestic Surface): UN 2735 Amines, liquid, corrosive, NOS, (trimethylhexanediamines, (m-phenylenebis (methylamine)) 8, PG III IMDG (Ocean): UN 2735 Amines, liquid, corrosive, NOS, (N’-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine, m-phenylenebis (methylamine)) 8, PG III IATA/ICAO (Air): UN 2735 Amines, liquid, corrosive, NOS, (trimethylhexanediamines, (m-phenylenebis (methylamine)) 8, PG III Section 15 – Regulatory Information All raw materials are on the U.S., EPA, TSCA Inventory. SARA Notification: Nothing in this product is subject to regulation under SARA 302, 313. It may be subject to SARA 312 reporting, depending upon the purchaser’s storage circumstances. CERCLA: No CERCLA chemicals exist in this product above reportable concentrations. Clean Air Act Ozone-Depletion Potential: This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section (40 CFR 61). Section 16 – Other Information (Hazard Rating: 0 = Minimal; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe; * = Chronic) HMIS III rating: Health: 3* Flammability: 0 Physical hazard: 1 Abbreviations and acronyms: USDOT: United States Department of Transportation. IMDG: International Maritime Code for Dangerous Goods. IATA: International Air Transport Association. CAS: Chemical Abstracts Service (Division of the American Chemical Society). LC50: Lethal concentration, 50 percent. LD50: Lethal dose, 50 percent. EC50: Median effective concentration. RQ: Reportable quantity. SDS prepared by: Aquafin product safety department. DISCLAIMER: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. END OF SDS (January 22, 2019) IDENTITY: As Used on Label and List: VAPORTIGHT COAT®-SG2/3-ACCELERATOR (SDS 1 of 1) Chemical Characterization: EPOXY ACCELERATOR (CORROSIVE) “COMPONENT-C” (Curing Agent for AQUAFIN-SG2 and SG3) AQUAFIN, INC. 24 hr Emergency Phone: Chem-Tel (800) 255-3924 BLUE BALL RD NO. 160 Information Phone No: (410) 392-2300 ELKTON, MD 21921 info@aquafin.net Recommended use of the chemical and restriction on use: Refer to the product technical data sheet. For industrial and professional users. Section 2 – Hazards Identification OSHA/HCS status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Classification: Acute toxicity, Category 4 (oral) H302: Harmful if swallowed. Skin corrosion/irritation, Category 1B H314: Causes severe skin burns and eye damage. Skin sensitization, Category 1 H317: May cause an allergic skin reaction. Serious eye damage, Category 1 H318: Causes serious eye damage. Reproductive toxicity, Category 2 H361: Suspected of damaging fertility or the unborn child. GHS Label element: Hazard Pictograms GHS05 GHS07 GHS08 Signal Word: Danger Hazard Statements: H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H361: Suspected of damaging fertility or the unborn child. Precautionary Statements: Prevention: P102: Keep out of reach of children. P260: Do not breathe dust/fume/gas/mist/vapors/spray. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P272: Contaminated work clothing should not be allowed out of the workplace. P281: Use protective equipment as required. Response: P301 + P315: IF SWALLOWED: Get immediate medical advice/attention. P330 + P331: Rinse mouth. Do NOT induce vomiting. P302 + P352 = P361: IF ON SKIN: Remove/Take off immediately all contaminated clothing. Wash with plenty of water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned, get medical advice/attention. P332 + P313: IF skin irritation occurs, get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Storage: P403: Store in a well-ventilated place. P405: Store locked up. Disposal: P501: Dispose of contents/container to an approved waste disposal site. P502: Refer to manufacturer/supplier for information on recovery/recycling. Section 3 – Composition / Information on Ingredients Substance: Mixture. HAZARDOUS COMPONENTS CAS NUMBER WEIGHT 2,4,6-tris-(dimethylaminomethyl)phenol 90-72-2 60 - 100% bis[(dimethylamino)methyl]phenol 71074-89-0 13 - 30 Section 4 – First Aid Measures General Advise: Immediately remove contaminated clothing. Exposure symptoms can appear after several hours. If contaminated consult medical advise up to 48 hours after exposure. First Aid: Wear protective equipment (i.e. protective gloves). If victim is unconscious: position and transport in “stable sideways position” to prevent asphyxiation if vomiting. Keep air passages open, remove dentures and vomit. Control breathing and pulse. If breathing and heart activity stops, administer CPR and call immediately emergency services. After Inhalation: Remove subject to fresh air. Administer oxygen if difficulty with breathing. Consult a physician immediately. The exposed person may need to be kept under medical surveillance for 48 hours. After Ingestion: Immediately seek medical attention. Do not induce vomiting. Drink plenty of water to dilute stomach contents. Stop if the exposed person feels sick as vomiting may be dangerous. After Skin Contact: Instantly wash skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Chemical burns must be treated promptly by a physician. After Eye Contact: Rinse opened eye with plenty of running water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses. Chemical burns must be treated promptly by a physician. Consult physician immediately. Protection of First Aid Personnel: If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to Physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 5 – Fire Fighting Measures Flash Point: Closed cup: 110 - 120o C (230 - 248 F). [DIN 51758; EN 22719 (Pensky- o Martens Closed Cup)]. Flammability: In a fire or heated, a pressure increase will occur and the container may burst. Hazardous Thermal Decomposition Products: Decomposition products may include the following materials: Carbon dioxide; carbon monoxide; nitrogen oxides. Extinguishing Media: Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special Fire Fighting Procedures: As in any fire, wear full protective gear and NIOSH-approved self- contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode. Unusual Fire and Explosion Hazards: Bursting and explosion of container possible due to increase of pressure when exposed to increasing heat. In case of fire, cool nearby containers with water fog. Formation of poisonous gases during heating or in fires possible. Section 6 – Accidental Release Measures Personal Precautions: Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation of vapors. Wear appropriate personal protective equipment. Remove or eliminate all ignition sources. Do not touch or walk through spilled material. Methods for Cleaning up: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Contain and collect spillage with non-combustible, absorbent materials. I.e. sand, earth, vermiculate, diatomaceous earth, universal binders, sawdust and place in container for disposal. Waste Disposal Method: Dispose in accordance with local, state and federal regulations. Ecological Information: Do not allow product to reach ground water, bodies of water, storm water or sewage systems. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Section 7 – Handling and Storage Handling: Avoid eye and skin contact. Keep out of reach of children. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage: Storage temperature: 2 - 40o C (35 - 104o F). Store in original container protected from direct sunlight in a dry, cool and well ventilated area in tightly closed containers. Store away from foodstuffs. Provide fresh air when handling in closed rooms (open windows and doors). Do not store in unlabeled containers. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Section 8 – Exposure Controls / Personal Protection Engineering Controls: Use only with adequate general and local exhaust ventilation. Washing of the skin in the working area must be possible. Eye-wash station or bottle must be available. Respiratory Protection: Respirator in well ventilated areas not necessary. Wear a properly fitted NIOSH approved respirator in poorly ventilated areas or spillage. Skin Protection: When installing, wear appropriate impervious gloves (neoprene) to prevent hand- skin exposure. Wear appropriate impervious clothing (acid and alkaline resistant) to prevent skin exposure (long sleeve shirt and long pants). Hand Protection: Chemical-resistant, impervious gloves complying with an approve standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Material of gloves for long term application (BTT>480 min): - butyl rubber - ethyl vinyl alcohol laminate (EVAL) - gauntlet type. Material of gloves for short term/splash application (10 min<BTT<480 min): - nitrile rubber - gauntlet type. Eye Protection: Wear chemical splash goggles. Face shield as necessary. Work/Hygienic Practices: Wash hands before breaks and after work, and before eating, drinking or smoking. Know the locations of eye wash fountains and emergency showers. Section 09 – Physical and Chemical Properties Physical State: Liquid Appearance/Color: Light yellow Odor: Amine like Solubility in water: Soluble Boiling Point: N/A Melting Point: N/A Flash Point: o Closed cup: 110 - 120o C (230 - 248 F). [DIN 51758; EN 22719 (Pensky- Martens Closed Cup)] Vapor Pressure: Less than 1 Pa at 20oC (68oF) Bulk Density: 0.97 kg/dm3 at 20oC (68oF) Evaporation Rate: N/A pH: 11 Viscosity: (room temperature) 120 – 250 mPa*s (120 – 250 cPs) VOC: 0% (0 g/L) Section 10 – Stability and Reactivity Chemical Stability: The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions to Avoid: Strong oxidizer. Keep away from heat and ignition sources. Materials to avoid: Strong acids, strong bases, strong oxidizing agents. Hazardous Decomposition: Under normal conditions of storage and use, hazardous decomposition products should not be produced. Decomposition products may include the following materials: nitrogen oxides, carbon monoxide, other organic compounds. Section 11 – Toxicological Information Acute Toxicity: 2,4,6-tris((dimethylaminomethyl)phenol: Oral LD50 2169 mg/kg (rat-female) Dermal LD50 >971 mg/kg (rat-male) Irritation/Corrosion: 2,4,6-tris((dimethylaminomethyl)phenol: Dermal Skin Corrosive (rabbit) Eyes Corrosive (rabbit) Bis[(dimethylamino)methyl]phenol: Dermal Skin Irritant (rabbit) Eyes Irritant (rabbit) Potential Acute Health Effects: - Inhalation: May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. - Ingestion: Harmful if swallowed. May cause burns to mouth, throat and stomach. - Skin: Causes severe burns.. - Eyes: Causes serious eye damage. Additional Information: If ingested, highly corrosive to mouth and throat, as well as danger or perforation to esophagus and stomach. Section 12 – Ecological Information Environment: Toxic to aquatic systems. Do not allow product to reach into natural waterways, drains, storm water or wastewater systems. Section 13 – Disposal Considerations Waste Disposal Method: Dispose of in a manner consistent with federal, state and local regulations. This includes pails containing uncured material. Pails with cured/hardened remains of product can be sent for recycling. Recommendation: Product mixed with hardener and resin and fully cured is ecologically save and can be disposed to local refuse deposit. Section 14 – Transport Information DOT (Domestic Surface & Air): UN 2735 Polyamines, liquid, corrosive, N.O.S. (2,4,6-Tris(Dimethylaminomethyl)Phenol) 8, PG II IMO (Ocean): UN 2735 Polyamines, liquid, corrosive, N.O.S. (2,4,6-Tris(Dimethylaminomethyl)Phenol) 8, PG II IATA/ICAO (Air): UN 2735 Polyamines, liquid, corrosive, N.O.S. (2,4,6-Tris(Dimethylaminomethyl)Phenol) 8, PG II Section 15 – Regulatory Information U.S. Federal Regulations HCS Classification: Corrosive material. U.S. Federal Regulations: U.S. Inventory (TSCA 8b): All components are listed or exempted. SARA Notification: SARA 302/304/311/312: Immediate (acute) health hazard. Delayed (chronic) health hazard. SARA 311/312 SDS distribution – chemical inventory – hazard identification: No ingredient listed. Clean Air Act – Ozone Depleting Substances (ODS): This product does not contain nor is it manufactured with ozone depleting substances. State Regulations: Massachusetts, New Jersey & Pennsylvania RTK Hazardous Substances: No ingredients listed. California Prop 65: None required. Canada: WHMIS (Canada): Class D-2B: Material causing other toxic effects (Toxic). CEPA DSL: This material is listed or exempted. Section 16 – Other Information (Hazard Rating: 0 = Minimal; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe; * = Chronic) HMIS III rating: Health: 3 Flammability: 1 Physical hazard: 0 Personal Protection: B Abbreviations and acronyms: USDOT: United States Department of Transportation. IMDG: International Maritime Code for Dangerous Goods. IATA: International Air Transport Association. CAS: Chemical Abstracts Service (Division of the American Chemical Society). LC50: Lethal concentration, 50 percent. LD50: Lethal dose, 50 percent. EC50: Median effective concentration. RQ: Reportable quantity. . SDS prepared by: Aquafin product safety department. DISCLAIMER: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. END OF SDS (January 22, 2019) Chemical Characterization: EPOXY RESIN (IRRITANT) “COMPONENT-A” AQUAFIN, INC. 24 hr Emergency Phone: Chem-Tel (800) 255-3924 505 BLUE BALL RD., NO. 160 Information Phone No: (410) 392-2300 ELKTON, MD 21921 info@aquafin.net www.aquafin.net Recommended use of the chemical and restriction on use: Refer to the product technical data sheet. For industrial and professional users. Section 2 – Hazards Identification GHS Classification: Skin irritation, Category 2 H315: Causes skin irritation. Sensitization, Skin, Category 1 H317: May cause an allergic skin reaction. Eye irritation, Category 2A H319: Causes serious eye irritation. Hazard-determining components of labelling: Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) 1,6-bis(2,3-ethoxypropoxy)hexane 1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-, polymer with 2-(chloromethyl)oxirane bisphenol-F-epoxy resin GHS Label element: Hazard Pictograms GHS07 Signal Word: Warning Hazard Statements: H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. Precautionary Statements: Prevention: P102: Keep out of reach of children. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear eye protection/face protection. P280: Wear protective gloves. P281: Use protective equipment as required. Response: P301 + P315: IF SWALLOWED: Get immediate medical advice/attention. P302 + P352: IF ON SKIN: Wash with plenty of water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned, get medical advice/attention. P332 + P313: IF skin irritation occurs, get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Storage: P403 + P232: Store in a well-ventilated place. Protect from moisture. Disposal: P501: Dispose of contents/container to an approved waste disposal site. Section 3 – Composition / Information on Ingredients Description: Solvent-free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤700. COMPONENTS

Signal word

Warning

Hazard statements

H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation

Prevention

P102 Keep out of reach of children. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear eye protection/face protection. P280 Wear protective gloves. P272 Contaminated work clothing should not be allowed out of the workplace. P281 Use protective equipment as required.

Response

P301 + P315 IF SWALLOWED: Get immediate medical advice/attention. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned, get medical advice/attention. P332 + P313 IF skin irritation occurs, get medical advice/attention. P362 Take off contaminated clothing and wash before reuse.

Storage

P403 + P232 Store in a well-ventilated place. Protect from moisture.

Disposal

P501 Dispose of contents/container to an approved waste disposal site. P502 Refer to manufacturer/supplier for information on recovery/recycling.