L040-TNVG-LV

Hazard statements (CLP)

H315, H317, H319, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315: Causes skin irritation. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation.

Precautionary statements

General P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children.

Prevention

P261: Do not breathe vapor or mist. P270: Do not eat, drink or smoke when using this product. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. L040-TNVG-LV

Response

P302+P352 IF ON SKIN Wash with plenty of soap and water P333+P313: If skin irritation occurs, get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do Continue rinsing. P337+P313: If eye irritation persists, get medical advice/attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P391: Collect spillage.

Storage

P403 + P235: Store in a well-ventilated place. Keep cool. P233: Keep container tightly closed. P405: Store locked up.

Disposal

P501: Dispose of contents and container in accordance with all local, regional, national and international regulations.

2.3 Other hazards

None known.

2.1 Classification of the substance or mixture

SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 2 – H319 SENSITIZATION (Skin) – Category 1 – H317 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory system) – Category 3 – H335 GHS label elements Hazard pictograms Signal word Warning Hazard statements H315: Causes skin irritation. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation. Precautionary statements General P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. Prevention P261: Do not breathe vapor or mist. P270: Do not eat, drink or smoke when using this product. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. L040-TNVG-LV Section 2. Hazards identification Response P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation occurs, get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists, get medical advice/attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P391: Collect spillage. Storage P403 + P235: Store in a well-ventilated place. Keep cool. P233: Keep container tightly closed. P405: Store locked up. Disposal P501: Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified None known. Section 3. Composition/information on ingredients Substance/mixture Mixture. Ingredient name CAS number % (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate 42978-66-5 ≥25 - ≤50 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Use of buffered baby shampoo will aid in removal. If irritation persists, get medical attention. Inhalation Move the victim to a safe area as soon as possible. Allow the victim to rest in a well-ventilated area. If breathing is difficult, give oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Skin contact In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If irritation persists, seek medical attention. Wash contaminated clothing before reuse. Clean shoes thoroughly before reuse. Ingestion Wash out mouth with water. Remove dentures if any. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Seek immediate medical attention. Most important symptoms/effects, acute and delayed Eye contact Causes serious eye irritation. Inhalation May cause respiratory irritation. Skin contact May cause allergic skin reactions with repeated exposure. Ingestion Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact Adverse symptoms may include the following: pain or irritation, watering, redness. L040-TNVG-LV Section 4. First aid measures Inhalation Adverse symptoms may include the following: respiratory tract irritation, coughing. Skin contact Adverse symptoms may include the following: irritation, redness. Ingestion Adverse symptoms may include the following: Irritating to mouth, throat and stomach.. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Use dry chemical, CO₂, water spray (fog) or foam. Unsuitable extinguishing media Do not use water jet. Specific hazards arising from the chemical No specific fire or explosion hazard. Hazardous thermal decomposition products No specific data. Special protective actions for fire-fighters Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. See also the information in "For non-emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. L040-TNVG-LV Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Segregate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Refer to the product label and/or technical data sheet for further information. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working