Vinylmagnesium chloride 1.9M solution in THF

Hazard statements (CLP)

H224, H228, H250, H260, H261, H314, H318

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H260 In contact with water releases flammable gases which may ignite spontaneously. H314 Causes severe skin burns and eye damage. H224 Extremely flammable liquid and vapour. H250 Catches fire spontaneously if exposed to air. H228 Flammable solid. H261 In contact with water releases flammable gases.

Supplemental label elements

Not Applicable

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231+P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P260 Do not breathe mist/vapours/spray. P264 Wash all exposed external body areas thoroughly after handling. P280 Wear protective gloves, protective clothing, eye protection and face protection. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P222 Do not allow contact with air. P223 Do not allow contact with water.

Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages. P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/physician/first aider. P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Storage

P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P402+P404 Store in a dry place. Store in a closed container.

Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. Continued...

Other hazards

REACH - Art.57-59 The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

2.1 Classification of the substance or mixture

Classification according to H260 - Substances and Mixtures which in Contact with Water Emit Flammable Gases Category 1, H314 - Skin regulation (EC) No Corrosion/Irritation Category 1B, H318 - Serious Eye Damage/Eye Irritation Category 1, H224 - Flammable Liquids Category 1, 1272/2008 [CLP] and H250 - Pyrophoric Liquids Category 1, H228 - Flammable Solids Category 1, H261 - Substances and Mixtures which in Contact amendments [1] with Water Emit Flammable Gases Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI Page 1 continued...