Methylmagnesium chloride 3M solution in THF

Hazard statements (CLP)

H225, H228, H250, H261, H315, H318, H335

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H318 Causes serious eye damage. H335 May cause respiratory irritation. H315 Causes skin irritation. H250 Catches fire spontaneously if exposed to air. H228 Flammable solid. H261 In contact with water releases flammable gases.

Supplemental label elements

Not Applicable

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231+P232 Handle and store contents under inert gas. Protect from moisture. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing mist/vapours/spray. P222 Do not allow contact with air. P223 Do not allow contact with water. P264 Wash all exposed external body areas thoroughly after handling.

Response

P302+P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages. P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/physician/first aider. P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P302+P352 IF ON SKIN: Wash with plenty of water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.

Storage

P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P402+P404 Store in a dry place. Store in a closed container.

Precautionary statements

Disposal Continued P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

Other hazards

REACH - Art.57-59 The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

2.1 Classification of the substance or mixture

Classification according to H225 - Flammable Liquids Category 2, H318 - Serious Eye Damage/Eye Irritation Category 1, H335 - Specific Target Organ regulation (EC) No Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H315 - Skin Corrosion/Irritation Category 2, H250 - Pyrophoric 1272/2008 [CLP] and Liquids Category 1, H228 - Flammable Solids Category 1, H261 - Substances and Mixtures which in Contact with Water Emit amendments [1] Flammable Gases Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI Page 1 continued...