Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2009-08-13
Product name
1,1"-METHANEDIYLBIS(4-ISOCYANATOBENZENE) 98%
Product Synonyms
(STABILISED WITH 450PPM BHT AND 450PPM TRIPHENYL PHOSPHITE)
CAS No.
101-68-8
Icons in SDS
Company Information
company name
Apollo Scientific Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
david.tideswell@apolloscientific.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H351, H371, H373, H400
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
Classification under CHIP
Xn R20; Xi R36/37/38; Xn R40; Sens. R42/43; Xn R48/20
CLP CLASSIFICATION
Resp. Sens. 1 H334; STOT RE 2 H373; Acute Tox. 4 H332; Aquatic Acute 1 H400; Carc 2 H351; Eye Irrit. 2 H319; Skin Irrit. 2 H315; Skin Sens. 1 H317; STOT SE 2 H371
Most important adverse effects
Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by inhalation and skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation.
2.2 Label elements
Label elements under CLP:
Hazard statements
H315 Causes skin irritation H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351: Suspected of causing cancer. H371: May cause damage to organs . H373: May cause damage to organs through prolonged or repeated exposure. H400: Very toxic to aquatic life. R20 Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin. R40: Limited evidence of a carcinogenic effect. R42/43: May cause sensitisation by inhalation and skin contact. R48/20 Harmful danger of serious damage to health by prolonged exposure through inhalation.
Signal word
Danger
Hazard pictograms
GHS07 Exclamation mark GHS08: Health hazard GHS09: Environmental Label elements under CHIP: Harmful
Precautionary statements
S1/2 Keep locked up and out of the reach of children S23: Do not breathe. S36/37: Wear suitable protective clothing and gloves. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.3 Other hazards
Lachrymatory
PBT Substances
This substance is not identified as a PBT substance