3-Chloro-4-fluorophenylmagnesium bromide 0.5M solution in THF

Hazard statements (CLP)

H225, H314, H318, H335, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

Danger

Hazard statements

H314 Causes severe skin burns and eye damage. H225 Highly flammable liquid and vapour. H335 May cause respiratory irritation. H351 Suspected of causing cancer.

Supplemental label elements

Not Applicable

Prevention

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist/vapours/spray. P264 Wash all exposed external body areas thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges.

Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P310 Immediately call a POISON CENTER/doctor/physician/first aider. P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Storage

P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

Other hazards

Inhalation and/or ingestion may produce serious health damage*. REACH - Art.57-59 The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. Continued

2.1 Classification of the substance or mixture

Classification according to H314 - Skin Corrosion/Irritation Category 1B, H225 - Flammable Liquids Category 2, H318 - Serious Eye Damage/Eye Irritation regulation (EC) No Category 1, H335 - Specific Target Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H351 - 1272/2008 [CLP] and [1] Carcinogenicity Category 2 amendments Page 1 continued... Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI