Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
202-966-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
General Information
Revision date
2021-01-06
Product name
P-MDI, MDI
CAS No.
101-68-8
REACH No
01-2119457014-47-0000
supplier name
APOLLO CHEMICALS LTD
Icons in SDS
Company Information
company name
APOLLO CHEMICALS LTD
e-mail address of the competent person responsible for the Safety Data Sheet
compliance@apollo.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
Physical hazards
Not Classified
Health hazards
Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373
Environmental hazards
Not Classified Human health Contains non-volatile isocyanate. Heating may generate vapours which irritate the respiratory system. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
2.2 Label elements
EC number 202-966-0
Signal word
Danger
Hazard statements
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing vapour/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTRE/doctor if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statements
P260 Do not breathe vapour/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P501 Dispose of contents/ container in accordance with national regulations.
Supplemental label elements
EUH204 Contains isocyanates. May produce an allergic reaction. information P201 Obtain special instructions before use
Contains
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE
2.3 Other hazards
This product does not contain any substances classified as PBT or vPvB.
