Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
60-100% 2119457014-47-
General Information
Revision date
2020-06-23
Product name
P-MDI, MDI
CAS No.
101-68-8
supplier name
APOLLO CHEMICALS LTD
Icons in SDS
Company Information
company name
APOLLO CHEMICALS LTD
e-mail address of the competent person responsible for the Safety Data Sheet
compliance@apollo.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
Physical hazards
Not Classified
Health hazards
Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373
Environmental hazards
Not Classified Human health May cause sensitisation by inhalation. The liquid may be irritating to skin. Contains non- volatile isocyanate. Heating may generate vapours which irritate the respiratory system. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
2.2 Label elements
EC number 202-966-0
Signal word
Danger
Hazard statements
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
EUH204 Contains isocyanates. May produce an allergic reaction. P260 Do not breathe vapour/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P284 [In case of inadequate ventilation] wear respiratory protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P501 Dispose of contents/ container in accordance with national regulations. RCH004a Persons already sensitised to diisocyanates may develop allergic reactions when using this product. RCH004b Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. RCH004c This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
Contains
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE
2.3 Other hazards
This product does not contain any substances classified as PBT or vPvB.
