Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
10-30%
General Information
Version
20
Revision date
2022-06-13
Product name
A07561
1.2.1 Relevant identified uses
Adhesive
supplier name
APOLLO CHEMICALS LTD
Emergency telephone
+44 01827 69662
Icons in SDS
Company Information
company name
APOLLO CHEMICALS LTD
e-mail address of the competent person responsible for the Safety Data Sheet
compliance@apollo.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
SI 2019 No. 720)
Physical hazards
Not Classified
Health hazards
Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373
Environmental hazards
Not Classified Human health Contains non-volatile isocyanate. Heating may generate vapours which irritate the respiratory system. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
EUH204 Contains isocyanates. May produce an allergic reaction. P260 Do not breathe vapour/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P284 [In case of inadequate ventilation] wear respiratory protection. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/ attention. P501 Dispose of contents/ container in accordance with national regulations. RCH004a Persons already sensitised to diisocyanates may develop allergic reactions when using this product. RCH004b Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. RCH004c This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
Supplemental label elements
As from 24 August 2023, adequate training is required before industrial or professional use
Contains
DIPHENYLMETHANE-4,4'-DI-ISOCYANATE
