A07504

APOLLO CHEMICALS LTD

Revision date : 2018-11-06

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

30-60% 2119457014-47- <1%

General Information

Revision date

2018-11-06

Product name

A07504

supplier name

APOLLO CHEMICALS LTD

Emergency telephone

+44 01827 69662 (NOT 24HRS - 8am-5pm mon-fri

Icons in SDS

GHS07 GHS08 M004 M008 M009 M010

Company Information

company name

APOLLO CHEMICALS LTD

e-mail address of the competent person responsible for the Safety Data Sheet

sds@apollo.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

Physical hazards

Not Classified

Health hazards

Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373

Environmental hazards

Not Classified Human health Contains non-volatile isocyanate. Heating may generate vapours which irritate the respiratory system. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing vapour/spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/ doctor if you feel unwell. P313 Get medical advice/ attention. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 If eye irritation persists: P362 Take off contaminated clothing. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

EUH204 Contains isocyanates. May produce an allergic reaction. P260 Do not breathe vapour/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required. P284 [In case of inadequate ventilation] wear respiratory protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/ attention if you feel unwell. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P501 Dispose of contents/ container in accordance with national regulations.

Contains

DIPHENYLMETHANE-4,4'-DI-ISOCYANATE

Supplemental label elements

P201 Obtain special instructions before use

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