TridolC6 S6

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment

Supplemental label elements

EUH210 - Safety data sheet available on request

PBT Substances

not relevant – no registration required

vPvB Substances

not relevant – no registration required

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display EUH-statements : EUH210 - Safety data sheet available on request 2.3. Other hazards PBT: not relevant – no registration required vPvB: not relevant – no registration required SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-(2-Butoxyethoxy)ethanol (CAS-No.) 112-34-5 4 - 10 Eye Irrit. 2, H319 (EC-No.) 203-961-6 (EC Index-No.) 603-096-00-8 (REACH-no) 01-2119475104-44 Full text of H-statements: see section 16 22/08/2017 EN (English) 1/8 A.1 P2141-OM-0334 R9 Appendix A SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed No additional information available 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : No specific measures are necessary. This product is a fire extinguishing medium. Unsuitable extinguishing media : Not applicable. 5.2. Special hazards arising from the substance or mixture Fire hazard : No fire hazard. 5.3. Advice for firefighters Firefighting instructions : Not applicable. Protection during firefighting : Not applicable. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections 8. Exposure controls/personal protection. 13. Disposal considerations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Wear recommended personal protective equipment. Read and follow manufacturer's recommendations. Handle in accordance with good industrial hygiene and safety procedures. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Keep container tightly closed. Store at temperatures not exceeding 60°C (140°F) (intermittent). Protect from freezing. Keep/Store away from incompatible materials. 7.3. Specific end use(s) Firefighting foam concentrate. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-(2-Butoxyethoxy)ethanol (112-34-5) EU Local name 2-(2-Butoxyethoxy)ethanol 22/08/2017 EN (English) 2/8 A.2 Appendix A P2141-OM-0334 R9 2-(2-Butoxyethoxy)ethanol (112-34-5) EU IOELV TWA (mg/m³) 67.5 mg/m³ EU IOELV TWA (ppm) 10 ppm EU IOELV STEL (mg/m³) 101.2 mg/m³ EU IOELV STEL (ppm) 15 ppm Belgium Limit value (mg/m³) 67.5 mg/m³ (2-(2-Butoxyéthoxy)éthanol; Belgium; Time-weighted average exposure limit 8 h) Belgium Limit value (ppm) 10 ppm (2-(2-Butoxyéthoxy)éthanol; Belgium; Time- weighted average exposure limit 8 h) Belgium Short time value (mg/m³) 101.2 mg/m³ (2-(2-Butoxyéthoxy)éthanol; Belgium; Short time value) Belgium Short time value (ppm) 15 ppm (2-(2-Butoxyéthoxy)éthanol; Belgium; Short time value) France Local name 2-(2-butoxyéthoxy)éthanol France VME (mg/m³) 67.5 mg/m³ France VME (ppm) 10 ppm France VLE (mg/m³) 101.2 mg/m³ France VLE (ppm) 15 ppm France Note (FR) Valeurs règlementaires indicatives Netherlands Grenswaarde TGG 8H (mg/m³) 50 mg/m³ (2-(2-butoxyethoxy)ethanol; Netherlands; Time-weighted average exposure limit 8 h; Public occupational exposure limit value) Netherlands Grenswaarde TGG 8H (ppm) 7.4 ppm (2-(2-butoxyethoxy)ethanol; Netherlands; Time-weighted average exposure limit 8 h; Public occupational exposure limit value) Netherlands Grenswaarde TGG 15MIN (mg/m³) 100 mg/m³ (2-(2-butoxyethoxy)ethanol; Netherlands; Short time value; Public occupational exposure limit value) Netherlands Grenswaarde TGG 15MIN (ppm) 15 ppm (2-(2-butoxyethoxy)ethanol; Netherlands; Short time value; Public occupational exposure limit value) United Kingdom WEL TWA (mg/m³) 67.5 mg/m³ 2-(2-Butoxyethoxy)ethanol; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) United Kingdom WEL TWA (ppm) 10 ppm 2-(2-Butoxyethoxy)ethanol; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) United Kingdom WEL STEL (mg/m³) 101.2 mg/m³ 2-(2-Butoxyethoxy)ethanol; United Kingdom; Short time value; Workplace exposure limit (EH40/2005) United Kingdom WEL STEL (ppm) 15 ppm 2-(2-Butoxyethoxy)ethanol; United Kingdom; Short time value; Workplace exposure limit (EH40/2005) USA - ACGIH ACGIH TWA (ppm) 10 ppm (Diethylene glycol monobutyl ether; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction and vapor) 8.2. Exposure controls Appropriate engineering controls: Ensure adequate ventilation. Follow the exposure limits given on this material safety data sheet. Personal protective equipment: Wear recommended personal protective equipment. Hand protection: Wear protective gloves (butyl rubber) Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment (A2/P2). 22/08/2017 EN (English) 3/8 A.3 P2141-OM-0334 R9 Appendix A Thermal hazard protection: Wear thermal protective clothing, when necessary. Environmental exposure controls: Contain spills. Prevent releases. Observe national regulations on emissions. Ensure all national/local regulations are observed. Other information: Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Amber. Odour : Characteristic. Odour threshold : No data available pH : 6.6 - 7.6 Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : -1 °C Boiling point : No data available Flash point : > 100 °C Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : Non flammable. Vapour pressure : No data available Relative vapour density at 20 °C : No data available Relative density : No data available Density : 0.99 - 1.03 Solubility : No data available Log Pow : No data available Viscosity, kinematic : 2 mm²/s Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity The product is stable and non reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Incompatible materials. Extremely high or low temperatures. 10.5. Incompatible materials Alkali metals. Oxidizing agent. Water reactive substances. 10.6. Hazardous decomposition products Carbon oxides. Sulphur oxides. Hydrogen fluoride. Nitrogen oxides (NOx). Sodium oxides. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 22/08/2017 EN (English) 4/8 A.4 Appendix A P2141-OM-0334 R9 2-(2-Butoxyethoxy)ethanol (112-34-5) LD50 oral rat 5660 mg/kg (Rat) LD50 dermal rabbit 2764 mg/kg (Rabbit; Experimental value; OECD 402 : acute dermal toxicity) Skin corrosion/irritation : Not classified pH: 6.6 - 7.6 Additional information : Based on available data, the classification criteria are not met Serious eye damage/irritation : Not classified pH: 6.6 - 7.6 Additional information : Based on available data, the classification criteria are not met Respiratory or skin sensitisation : Not classified Additional information : Based on available data, the classification criteria are not met Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified Additional information : Based on available data, the classification criteria are not met Reproductive toxicity : Not classified Additional information : Based on available data, the classification criteria are not met STOT-single exposure : Not classified Additional information : Based on available data, the classification criteria are not met STOT-repeated exposure : Not classified Additional information : Based on available data, the classification criteria are not met Aspiration hazard : Not classified Additional information : Based on available data, the classification criteria are not met TridolC6 S6 Viscosity, kinematic 2 mm²/s Potential adverse human health effects and : Based on available data, the classification criteria are not met. symptoms SECTION 12: Ecological information 12.1. Toxicity 2-(2-Butoxyethoxy)ethanol (112-34-5) LC50 fish 1 1300 mg/l (96 h; Lepomis macrochirus) LC50 fish 2 1805 mg/l (48 h; Leuciscus idus) LC50 other aquatic organisms 1 10 - 100 mg/l (96 h) EC50 Daphnia 1 2850 mg/l (24 h; Daphnia magna; GLP) EC50 Daphnia 2 > 100 mg/l (48 h; Daphnia magna) TLM fish 1 10 - 100,96 h; Pisces TLM other aquatic organisms 1 10 - 100,96 h Threshold limit other aquatic organisms 1 10 - 100,96 h Threshold limit algae 1 53 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 >= 100 mg/l (96 h; Scenedesmus subspicatus) 12.2. Persistence and degradability TridolC6 S6 Persistence and degradability The product is readily biodegradable. 2-(2-Butoxyethoxy)ethanol (112-34-5) Persistence and degradability Readily biodegradable in water. Biochemical oxygen demand (BOD) ���������������������� Chemical oxygen demand (COD) ���������������������� ThOD ����������������������� BOD (% of ThOD) 0.11 12.3. Bioaccumulative potential TridolC6 S6 Bioaccumulative potential The product is not expected to bioaccumulate. 22/08/2017 EN (English) 5/8 A.5 P2141-OM-0334 R9 Appendix A 2-(2-Butoxyethoxy)ethanol (112-34-5) BCF fish 1 0.46 (QSAR) Log Pow 0.56 (Experimental value) Bioaccumulative potential Low bioaccumulation potential. 12.4. Mobility in soil 2-(2-Butoxyethoxy)ethanol (112-34-5) Surface tension 0.034 N/m (25 °C) 12.5. Results of PBT and vPvB assessment TridolC6 S6 PBT: not relevant – no registration required vPvB: not relevant – no registration required 12.6. Other adverse effects Other adverse effects : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. European List of Waste (LoW) code : 16 03 05* - organic wastes containing dangerous substances SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) : Not applicable UN-No. (IMDG) : Not applicable UN-No. (IATA) : Not applicable UN-No. (ADN) : Not applicable UN-No. (RID) : Not applicable 14.2. UN proper shipping name Proper Shipping Name (ADR) : Not applicable Proper Shipping Name (IMDG) : Not applicable Proper Shipping Name (IATA) : Not applicable Proper Shipping Name (ADN) : Not applicable Proper Shipping Name (RID) : Not applicable 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : Not applicable IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : Not applicable ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (RID) : Not applicable 14.4. Packing group Packing group (ADR) : Not applicable Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable Packing group (ADN) : Not applicable 22/08/2017 EN (English) 6/8 A.6 Appendix A P2141-OM-0334 R9 Packing group (RID) : Not applicable 14.5. Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available 14.6. Special precautions for user - Overland transport No data available - Transport by sea No data available - Air transport No data available - Inland waterway transport No data available - Rail transport No data available 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with 2-(2-Butoxyethoxy)ethanol Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or 2-(2-Butoxyethoxy)ethanol categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 55. 2-(2-butoxyethoxy)ethanol (DEGBE) 2-(2-Butoxyethoxy)ethanol Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations Germany VwVwS Annex reference : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) 12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting : None of the components are listed giftige stoffen – Borstvoeding NIET-limitatieve lijst van voor de voortplanting : None of the components are listed giftige stoffen – Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting : None of the components are listed giftige stoffen – Ontwikkeling Denmark Recommendations Danish Regulation : Pregnant/breastfeeding women working with the product must not be in direct contact with the product 15.2. Chemical safety assessment No chemical safety assessment has been carried out 22/08/2017 EN (English) 7/8 A.7 P2141-OM-0334 R9 Appendix A SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation EUH210 Safety data sheet available on request SDS EU (REACH Annex II) - Angus Fire This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 22/08/2017 EN (English) 8/8 A.8 Appendix A P2141-OM-0334 R9