VESSEL (2 x 2.5 Gal.)

2.2 Label elements

Emergency Overview Danger

Hazard statements

Harmful if swallowed. Harmful in contact with skin. Causes serious eye damage. May cause an allergic skin reaction. Appearance Liquid Physical state Liquid Odor Amines

Prevention

e Wash face, hands and any exposed skin thoroughly after handling ¢ Do not eat, drink or smoke when using this product ¢ Wear protective gloves/protective clothing/eye protection/face protection ¢ Avoid breathing dust/fume/gas/mist/vapors/spray ¢ Contaminated work clothing should not be allowed out of the workplace ¢ Keep away from heat/sparks/open flames/hot surfaces. — No smoking ¢ Keep container tightly closed

Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing ¢ Calla POISON CENTER or doctor/physician if you feel unwell ¢ Wash contaminated clothing before reuse ¢ If skin irritation or rash occurs: Get medical advice/attention ¢ IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower ¢ IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell ¢ Rinse mouth

Storage

Store in a well-ventilated place. Keep cool Conditions Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated | place. Incompatible materials Acids. Control parameters Exposure Guidelines Chemical Name ACGIH TLV

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Have the product label with you when calling a poison control center or doctor or going in for treatment. You may also contact 1-877-800-5556 for emergency medical treatment advice. The low flash point of this product is due to a minor component in the mixture. Based on independent laboratory testing of similar products, this product would not sustain combustion as specified in DOT Regulation 49 CFR 173 Appendix H; however

Further information

ITORNA LEAP ee be aa, ee Peay es “ pet past oa rm ud id A Aas 4M, pt: age ras ory aa . a - 4 — rae ert eo o @} sal rE! i 4 - on ‘ef ’ » rie ‘ Ne AE Sd BON dg $ a Bee q fee” Bid od =A. ee ee & AS Bee it eee bee oe eee ag er S QAR * edt . al cet ‘ rw aa hl 3, ian sin ates Lets 2 eel OR ied Se kahies Chemical Name CAS No. Weight-% 2,4-D, dimethylamine salt 2008-39-1 _ 30.56 MCPP DMA Salt 66423-09-4 8.17 Dimethylamine dicamba 2300-66-5 2.17 * The exact percentage (concentration) of composition has been withheld as a trade secret ; CaS Re att Bb Ab oes ia pea SU Riek TARTS _ at, Vigsbics Re as he ae a iain a id na aeatee apt ‘ ra Ure oe Wah oe Se 4 i i trad PES pres ek pbc ag att ait apeneacels Srey ] nA =) = a aN ab ret S-_c Pu sean eS aaelt - aes Bee ancien iin Se b a: -IRST a gi cy A iF ) | MIE CF Sui y Pa Hi >| re ad a res at a Pin Seal Na te pipe eet ts i afr re ah ene ee AER Wee: Sureetks Pag vOn anne et Bsn Pe i oi ivi Bey wens ae os SERA, CSO gS, Aiba Sines Enos SRN Sheets First aid measures General advice In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). If symptoms persist, call a physician. Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Skin Contact Wash contaminated clothing before reuse. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Artificial respiration and/or oxygen may be necessary. Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a physician. Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician immediately. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians May cause sensitization of susceptible persons. Treat symptomatically. Suitable extinguishing media Use. Foam. Carbon dioxide (CO2). Dry chemical. Water spray (fog). Specific hazards arising from the chemical In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Personal precautions, protective equipment and emergency procedures Personal precautions Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Precautions for safe handling Advice on safe handling Ensure adequate ventilation, especially in confined areas. Take precautionary measures against static discharges. Use with local exhaust ventilation. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. Density 9.3812 pounds/gallon Reactivity No data available Chemical stability Stable. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Will not occur. Conditions to avoid Extremes of temperature and direct sunlight. incompatible materials Acids. Hazardous Decomposition Products May emit toxic fumes under fire conditions. Hydrogen chloride. Nitrogen oxides (NOx). Carbon monoxide. Information on likely routes of exposure Product Information Inhalation No data available. Eye contact No data available. Skin Contact See "Numerical measures of toxicity-product information" in this section. Ingestion See "Numerical measures of toxicity-product information" in this section. information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic toxicity Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. Target Organ Effects Eyes, Respiratory system, Skin. Aspiration hazard No information available. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 9% of the mixture consists of ingredient(s) of unknown toxicity Oral LD50 > 1500 mg/kg Dermal LD50 > 2000 mg/kg The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-gas) 94902 mg/L ATEmix (inhalation-dust/mist) 20.3 mg/L Ecotoxicity Toxic to aquatic life with long lasting effects 9% of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container, unless specified by the manufacturer. US EPA Waste Number U240 See Section 2: Hazards not otherwise classified (HNOC) DOT Proper shipping name For package sizes less than 41.32 gallons: product is non-regulated. For package sizes 41.32 gallons or greater: UN3082, Evironmentally Hazardous Substances, Liquid, N.O.S., 9, PGIII, RQ (2,4-D) Description The following guidelines apply for domestic ground transport. If shipping by air or ocean, please contact our Transportation Dept. PESTICIDES, NOI, INCLUDING DEFOLIANTS, FUNGICIDES, HERBICIDES, OR INSECTICIDES NMFC 155050-6 If shipped in bulk conatiners (greater than 119 gallons), this product is a Marine Pollutant. When shipped as a Hazardous Material, label required is Class 9 (Miscellaneous). Placards required on bulk shipments only. U.S. EPA Label Information EPA Pesticide Registration Number 2217-656-72112 Federal Insecticide, Fungicide, Rodenticide Act Regulations This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Pesticide Label Danger. Keep out of the reach of children. Corrosive. Causes irreversible eye damage. Harmful if swallowed. Harmful if absorbed through skin. Do not get in eyes, on skin, or on clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove and wash contaminated clothing before reuse. International Inventories TSCA Not Listed DSL/NDSL Not Listed EINECS/ELINCS Not Listed ENCS Not Listed IECSC Not Listed KECL Not Listed PICCS Not Listed AICS Not Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances Chemical Name TSCA DSL NDSL EINECS | ELINCS ENCS IECSC KECL PICCS AICS 2,4-D, dimethylamine salt x Xx X Dimethylamine dicamba X US Federal Regulations SARA 313 of Title IIl of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Dimethylamine dicamba - 2300-66-5 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 2,4-D, dimethylamine salt 100 Ib RQ 100 Ib final RQ 2008-39-1 RQ 45.4 kg final RQ US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Dimethylamine dicamba X 2300-66-5 International Regulations Mexico - Grade Moderate risk, Grade 2 NFPA Health hazards 2 Flammability 1 Instability 0

Appearance/Odor

Liquid Amines Color Brown Odor threshold No information available Property Values

Remarks

Method pH 7.5-8.5 Melting point/freezing point <0 °F Boiling point / boiling range 100 °C / 212 °F Flash point 54 °C / 129 °F Pensky-Martens Closed Cup (PMCC) Evaporation rate < Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure <17mm Hg Vapor density > Specific Gravity 1.1265 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Oxidizing properties No information available