Pendant Herbicide

Hazard statements (CLP)

H227, H302, H315, H317, H320, H335, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. R22, R43, R36/37/38, R50/53. Harmful if swallowed. May cause sensitisation by skin contact Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H227: Combustible liquid. H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H335: May cause respiratory irritation. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S2, S20, S23, S28, S38, S51, S60, S61, S62, S24/25, S37/39. Keep out of reach of children When using, do not eat or drink. Do not breathe vapours or mists. After contact with skin, wash immediately with plenty of soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this SDS. Avoid contact with skin and eyes. Wear suitable gloves and eye/face protection.

SUSMP Classification

S5

ADG classification

None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.

UN Number

None allocated

Signal word

WARNING

Prevention

P102: Keep out of reach of children. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Yellow liquid. Odour: Aromatic solvent odour.

Health hazards

Pendimethalin is slightly to practically nontoxic by ingestion, with reported oral LD50 values of 1050 mg/kg to greater than 5000 mg/kg in rats. It is slightly to practically nontoxic by skin exposure, with reported dermal LD50 values of greater than 2000 mg/kg. It is not a skin irritant or sensitizer in rabbits or guinea pigs, but it causes mild eye irritation in rabbits. The inhalation 4-hour LC50 for technical Pendimethalin in rats is 320 mg/L, indicating practically no toxicity via this route. Some formulated products may show slight toxicity by inhalation, and may have a greater capacity to cause skin irritation. Inhalation of dusts or fumes may be mildly to moderately irritating to the linings of the mouth, nose, throat, and lungs. This product is irritating to eyes, respiratory system and skin, is harmful if swallowed, and is a possible skin sensitiser.