HFE-8200 3M (TM) Novec (TM) Engineered Fluid

SECTION 2: Hazards identification

OSHA Hazards 3.1 EMERGENCY OVERVIEW Specific Physical Form: liquid Odor, Color, Grade: Clear, colorless liquid. Faint odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards:

Potential health effects

Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Page I of 8 14 02n!0/2006 Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. lnhalntion: If thermal decomposition occurs: May be harmful if inhaled. Intentional concentration and inhalation may be harmful or fatal (see section 11) Ingestion: No health effects are expected. 3.3 POTENTIAL ENVIRONMIENT AL EFFECTS 171is substance has chemical moieties that are resistant to biodegradation and is likely to only undt:rgo pa al biodegradation in the environment. The high potential of this substance to move from water to the atmosphere means its potenti I to bioconcentrate is likely to disappear rapidly from aerobic environments. Take precautions to prevent direct release of this product o the environment. Bioassay. This substance is highly volatile and has a high Henry's Law constant and is thus expected tom ve rapidly through ! AQUATIC TOXICITY: Testing results indicate that this product has insignificant toxicity to aquatic org isms at its saturation point Lowest LC50, ECS0, IC50 >substance wa.ter solubility). (June 1997) Fathead Minnow (Pimephales pro elas) 96-hr LC50 >750 mg/L NOTE: This data point reflects the CA method which was used to satisfy the California (CA) Title Hazad Evaluation vaporization from solution in an aquatic comparnnent or from a soil surface in a terrestrial compartment to the atmosphere. ATMOSPHERJC FATE Zero Ozone Depletion Potential (ODP). Atmospheric Lifetime approxi,mately 0.8 yr. Global Warming I Potential (GWP) 55 ( I 00-yr ITH, WMO 1998 method). Atmospheric degradation products are e> pected include for ethyl nonafluoroisobutyl ether predominantly iso-perfluorobutyric acid. CO2, HF, and perhaps also CF3COOH for ethyl nonafluorobutyl ether; n-pertluorobutyric acid, CO2, and HF. I SECTION 4: FIRST AID MEASURES 4.1 FffiST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industri I hygiene practices are followed. Eye Contact: No need for first aid is anticipated. Skin Contact: No need for first aid is anticipated. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medi al attention. If Swallowed: No need for first aid is anticipated. 4.2 NOTE TO PHYSICIANS Exposures resulting from intentional misuse and abuse may cause.an increase in myocardial irritability. sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE FIGHTlfNG MEASURES 5.1 FLAMMABLE PROPERTil:S Page 2 of 8 15 02/20/2006 Autoignition temperature 375 ·c [Details: ASTM E659-78 Method Flash Point No Flash Point per ASTM 03278 meth Flammable Limits· LEL 210 g/m3 [Details: ASTM E681-94 MetlJ d) Flammable Limits· UEL I 070 g/m3 [Details: ASTM E68 l-94 Method) 5.2 EXTINGUISHING MEDIA Material will not bum. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Exposure lo extreme heat can give rise to thermal decomposition. ear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire a nd Explosion Hazards: No unusual fire or explosion hazards are anticipated. No unus al effects are anticipated during fire extinguishing operations. Avoid breathing the products and substances that may result from the thennal decomposition of the product or the other substances in the fire zone. Keep containers cool with water spray when exposed to fire to avoid rupture. I Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion a nd the mal decomposition I information. j SECTION 6: ACCIDENT AL RELEASE MEASURES I Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line ( 1-800-36 -3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from haza d area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Working from around he edges of the spill inward, cover with bentonite, vermiculite, or comme rcially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and wat~ . Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authoriti es. Dispose of collected material as soon as possible. I local, state, and federal ree:ulations. I In the event of a release of this material, the user should determine if the release qualifies as rep, rtable according to j SECTION 7: HANDLING AND STORAGE I 7.1 HANDLING For industrial or professional use only. Contents may be under pressure, open carefully. Avoid skin conta, t with hot material. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and I( ad to the fonnation of the hazardous decomposition products mentioned in the Reactivity Data section of this MSDS. Avoid continu ) US exposure of the material to extreme condidtions of heat, i.e., above !SOC (welding, open flame, misuse or equipment failur ~). Avoid exceeding a watt density of 50 wattslinch2 from a heater surface. Continuous exposure to I SOC results m a very slight deco!flposition of this product and, therefore, ,s a very conservative use temperature threshold. Do not breathe thermal decomposition prt ucts. For add11lonal information about applications involving exposure of the fluid to temperatures exceeding I 50C. please con ct 3M Technical Service.

Storage

Keep container in well-ventilated area. Keep container tightly closed. Store away from heat. Store away om strong bases. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTIO Page 3 of 8 16 02/20/2006 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust when product is heated. For those situations where the fluid might bee, posed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient t( maintain levels of thermal decomposition products below their exposure guidelines. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection As a good industrial hygiene practice: Avoid eye contact. 8.2.2 Skin Protection Gloves are not required. Avoid skin contact with hot material. Wear appropriate gloves when handling hot material to prevent thermal bums. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respi atory protection. If thermal degradation products are expected, use fullface supplied air respirator. 8.2.4 Prevention of Swallowing Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient Authority ~ Limit

Additional information

ETHYL NONAFLUOROBUTYL ETI-IER 3M TWA. as total 200 ppm isomers ETHYL NONAFLUOROISOBUTYL ETHER 3M TWA, as total 200 ppm isomers SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) ' SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES I Specific Physical Form: liquid Odor, Color, Grade: Clear, colorless liquid. Faint odor. I General Physical Form: Liquid Autoignition temperature 375 °C [Derails: ASTM E659-78 Method] Flash Point No Flash Point per ASTM D3278 merhod Flammable Limits - LEL 2 10 g/m3 [Derails: ASTM E681-94 Metho ] Flammable Limits - UEL I 070 g/m3 [ Derails: ASTM E68 1-94 Meth d) Boiling point 76°C Density 1.43 g/ml I Vapor Density Approximately 9.1 [Re/Srd: A IR= I) Vapor Pressure I 09 mm Hg [@ 25 °CJ Specific Gravity 1.43 [Re/Srd: WATER= !] Page 4 of 8 17 OZ/2012006 pH Nol Applicable Melting point -138 ·c Solubility lo Water [Details: Insoluble] Evaporation rate 33 [Re/Sid: BUOAC= IJ Volatile Organic Compounds [ Details: Exempt] Percent volatile 100 % VOC Less H20 & Exempt Solvents [Details: Exempt] Viscosity 0.43 centistoke I SECTION 10: STABILITY AND REACTIVITY I Stability: Stable. Materials and Conditions to Avoid: Strong bases Hazardous Polymerization: Hazardous polymerization will not occur. I Hazardous Decomposition or By-Products I Substance Condition Hydrogen Fluoride At Elevated Temperatures• extreme conditions Q heat Pcrfluoroisobutylene {PFIB) At Elevated Temperatures• extreme conditions q • heat Hazardous Decomposition: Perfluorinated Acid Fluorides I Hydrogen Fluoride has an ACGIH Threshold Limit Value of3 parts per million (as fluoride) as a Ceiling L mil and an OSHA PEL of 3 ppm of fluoride as an eight hour Time_ Weighted Average and 6 ppm of fluoride as a Short Term Expost e Limit. ll1e odor threshold for HF is 0.04 ppm, providing good waming properties for exposure. Decomposition of this product at temperatures above 300 degrees C can form perfluoroisobutylcne (PFIB) but PFIB will only accumulate with continuous exposure to excessive heat in a sealed vessel. The fom1ation rate for PFIB is bout 1000 times less than the rate for primary thermal decomposition products such as HF. During normal use conditions, no health 1azard is associated with the use of this material due to PFIB exposure. I SECTION 11: TOXICOLOGICAL INFORMATION I Product-Based Toxicology Information: For a mixture of ethyl nonafluorobutyl ether and its isomer, a single positive response for cardiac sensitiz. ion was observed at an exposure level of 49,000 ppm. No adverse health effects are anticipated from normal handling and use. I SECTION 12: ECOLOGICAL INFORMATION I ECOTOXICOLOGICAL LNFORMA TION Test Ol]!anism Test Type Result Water Oca, Daphnia magna 48 hours EfTect Concentration 50% >2.55 mg/I Page S of 8 18 01/20/2006 I fathead Minnow, Pimephales promelas 96 hours Lethal Concentration 50"/o >2.75 mg/I Green algae, Selenastrum capricomutum 96 hours Effect Concentration 50"/o >2.32 mg/I CHEMICAL FATE INFORMATION I Test Type Result Protocol 28 days Biological Oxygen Demand Nil I SECTION 13: DISPOSAL CONSIDERATIONS I Waste Disposal Method: Reclaim if feasible. To reclaim or return, contact your 3M sales representative Incinerate uncured product in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, incinerate in an industrial or commercial facility in the presence ofa combustibl1 material. Combustion products will include HF. Facility must be capable of handling halogenated materials. To reclaim or return, check product label for contact. I EPA Hazardous Waste Number (RCRA): Not regulated I Since rce ulations varv. consult aoolicable ree ulations or authorities before disoosal I I SECTION 14:TRANSPORT INFORMATION I ID Number(s): 98-0212-2775-0, 98-0212-2776-8 I Please contact the emergency numbers listed on the first page of the MSDS for Transportation I formation for this material. I I SECTION 15: REGULATORY INFORMATION I US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements ofTSCA. One or more of the components of this product have been notified to NICNAS (National Industrial Chem id ~I Notification and Assessment Scheme) of Australia. Certain restrictions apply. Contact the selling division for additional i11 onnation. Contact 3M for more information. Page 6 of 8 19 02120/2006 I The components of this product are in compliance with the chemical notifica on requirements of ELfNCS, MET!, CICS and KECI. The product was notified to ERMA (New Zealand), and no further regj tration is necessary. INTERNATIONAL REGULA TIO NS Contact 3M for more information. The U.S. Environmental Protection Agency (EPA) has listed 3M(TM) HFE-8200 as an acceptable substit1 e for ozone depleting substances in specific solvent cleaning and aerosol industry applications under its Significant New Ahem ives Program (SNAP). Section 612 of the Clean Air Act requires the EPA to administer this program to evaluate and approve altetnatives for ozone depleting substances. I This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 hFR 1910.1200. I I SECTION 16: OTHER INFORMATION I NFPA Hazard Classification Health 3 Flammability I Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel lo ddress the hazards that are presented by short-tenn, acute exposure 10 a material under conditions of fire, spill, or similar emergencies. Hazard ra ngs are primarily based on the inherent physical and toxic properties ofthc material but also include the toxic propenies of combustion or decomposi ion products that are known to be generated in significant quantities. The hazard ratings assigned to this product are based on the propenies of comb st ion or decomposition products that can occur in an uncontrolled fire situation.

HMIS® ratings

Health 2 Flnmmability I Reaetivity: 0 Protection: X. See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed 10 infonn employees of chemical haz 1irds in the workplace. These ratings are based on the inherent propenies of the material under expected conditions of nonnal use and are not intend <l for use in emergency situations. HMIS® ratings are to be used with a fully implemented I IMIS® program. HMIS® is a registered mark oft e National Paint and Coatings Association (NPCA). Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO forn at. The potential hazards of the product have not changed. We encourage you 10 reread the MSDS and review the infom,ation. I Revision Changes: Not Applicable DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as ofl he date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, AJ\ t.' IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORiMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and su able for user's method of use or application. Given the variety of factors that can affect the use and application ofa 3M product, soi e of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine ' hether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility th1 electronic transfer may Page 7 of 8 20 3M MATERIAL SAFETY DATA SHEET HFE-8200 3M n Novec TM) En ineered fluid 02120/2006 have resulted in errors, omissions or alterations in this infom1ation, 3M makes no representations as to its ompleteness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS ailable directly from 3M. 3M MSDSs are available at www.3M.com Page 8 of 8 21 HCFC-225 22 Pagel of8 J nuary I, 2008 ASAHI LIN AK-225 U-1I00A-17 No. U-U00A-17 Identity (As Used on Label and List) Date Prepared August 18, 1992 Date / Revised: January I, 2008 ASAHIKLIN AK- 225 1. PRODUCT AND COMPANY INFORMATION Product Name: ASAHIKLIN AK-225 Synonym: HCFC-225 General Use: solvent MSDS Number: U-1 I00A Manufacturer Company Name: ASAHI GLASS CO., LTD. Chemicals Company Gas & Solvent Address: 1-12-1, Yurakucho, Chiyoda-ku, Tokyo, 100-8405, Japan Telephone No.: +8 I-3-3218-5479 Facsimile No.: +81-3-3218-7854 Supplier Company Name: AGC Chemicals Americas, Inc. Address: 55 E. Uwchlan Ave Suite 201, Exton, PA 19341 USA Telephone No: (704) 329-76 I 4 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC (US): 800-424-9300 24hours MEDICAL EMERGENCY: (800) 420-8479 Transportation Phone: (800) 424-9300 Customer Service: (704) 329-7614