AFM-67 (ERCuNi)

Hazard statements (CLP)

H317, H350, H372, H400, H412

Code

Statements

H317

May cause an allergic skin reaction

2.2 Label elements

• Hazard Symbol – No symbol required

Signal word

No signal word required Danger

Hazard statements

No applicable H317 - May cause an allergic skin reaction H350 - May cause cancer H372 - Causes damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects

Precautionary statements

Not Applicable P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapours/spray P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P264 - Wash thoroughly after handling P270 - Do not eat, drink or smoke when using this product P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P308+P313 - IF exposed or concerned: Get medical advice/attention P314 - Get medical advice and attention if you feel unwell P321 - Specific treatment (see label) P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P391 - Collect spillage P405 - Store locked up P405 - Store locked up P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. Warning! ‐ Avoid breathing welding fumes and gases, they may be dangerous to your health. Always use adequate ventilation. Always use appropriate personal protective equipment.

Hazardous Ingredients

CAS EINCSr Regulatory Hazard Classification/Designation 67/548/EEC△ IARCE NTPZ OSHAH Chromium 7440-47-3 231-157-5 O - R9; Carc 1Φ - R45; Muta 2 - R46; Repr 3 - R62; T+ - R26; T - R24/25, 1ΣΣ, 3Σ KΣΣ XΣΣ R48/23; C - R35, R42/43; N - R50, R53ΣΣΣ Copper 7440-50-8 231-159-6 None - Iron 7439-89-6 231-096-4 None - Manganese 7439-96-5 231-105-1 Xn-R20/22Y - Molybdenum 7439-98-7 231-107-2 Xn-R48/20/22;Xi-R36/37X - Nickel 7440-02-0 231-111-4 Carc3Φ-R40;T-R43,R48/23 1 K X Silicon 7440-21-3 231-130-8 None - (Amorphous Silica Fume) 69012-64-2 273-761-5 None 3 K - Titanium 7440-32-6 231-142-3 None - Tungsten 7440-33-7 231-143-9 None - Vanadium 7440-62-2 231-171-1 Xn ‐ R20, R48/22; Xi ‐ R41; N ‐ R51, R53Ω 2B ΩΩ - Γ – European Inventory of ExisMng Chemical Substances Number Δ - European Union DirecMve 67/548/EEC – Annex 1 Ε – InternaMonal Agency for Research on Cancer (1 – Human Carcinogen, 2A – Probably Carcinogenic to Humans, 2B – Possibly Carcinogenic to Humans, 3 – Unclassifiable as to Carcinogenicity in Humans, 4 Probably Not Carcinogenic to Humans) Ζ –

Principle Routes of Exposure

Respiratory System, Eyes and/or Skin Arc Rays: The welding arc can injure eyes and burn skin. • Electrick Shock: Arc welding and associated processes can kill. See Section 8. Fumes and Gases: Can be dangerous to your health. Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedures and electrodes used. Most fume ingredients are present as complex oxides and compounds and not as pure metals. When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section 3. Decomposition products of normal operation include those originating from the volatilization, reaction or oxidation of the materials shown in this section, plus those from the base metal and coating, etc., as noted above. Monitor for the materials identified in the list within this section. Fumes from the use of this product may contain complex oxides or compounds of the following elements and molecules: amorphous silica fume, beryllium, chromium, manganese and nickel. Other reasonably expected constituents of the fume would also include complex oxides of iron and silicon. Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating or galvanizing), the number of welders and the volume of the work area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder's helmet if worn or in the worker's breathing zone. See ANSI/AWS F1.1, available from the "American Welding Society", P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3 "Evaluating Contaminants in the Welding

2.1 Classification of the substance or mixture

This product is not classified as hazardous according to applicable GHS hazard classification criteria.