Polyurethane Adhesive

Hazard statements (CLP)

H316, H319, H332, H335, H351, H373

Code

Statements

H316

Causes mild skin irritation

SECTION 2: Hazards identification

1999/45/EC EMERGENCY OVERVIEW: This product is a brown liquid with a pasty odor.

Health hazards

This product may cause eye, skin and respiratory system irritation. May be a respiratory and skin sensitizer Flammability Hazards: This product is a nonflammable liquid with a flash point of 388.4F (198C). Reactivity Hazards: None.

Environmental hazards

The environmental effects of this product have not been investigated, however release may cause long term adverse environmental effects. US DOT Symbols: Not Regulated EU and GHS Symbols:

Signal word

Danger! 2.1 EU Labeling and Classification: This product meets the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC: Index Number: CAS#9016-87-9 is not listed in Annex VI EC# 271-091-4 is not listed in Annex VI EC# 202-966-0 is listed in Annex VI Index# 615-005-00-9 Substances not listed either individually or in group entries must be self-classified. 4,4-Diphenylmethane Diisocyanate, Polymeric Diphenylmethane Components Contributing to Classification: Benzenedicarboxylic Acid

Classification according to GHS

STOT SE Category 3 Eye Irritant Category 2 Skin Irritant Category 3 STOT RE Category 2 Skin Sensitizer Category 1 Respiratory Sensitizer Category 1 Acute Toxicity Category 4 (Inhalation) Carcinogenicity Category 2

Hazard statements

H335: May cause respiratory irritation. H319: Causes serious eye irritation H316: Causes mild skin irritation H373: May cause damage to organs through prolonged or repeated exposure. H332: Harmful if inhaled H351: Suspected of causing cancer

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P264: Wash thoroughly after handling. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection P284: [In case of inadequate ventilation] wear respiratory protection.

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P332+P313 If skin irritation occurs Get medical advice/attention P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. P314: Get medical advice/attention if you feel unwell. P312: Call a POISON CENTER/doctor if you feel unwell. P308+P313 IF exposed of concerned: Get medical advice/attention.

Storage

P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up.

Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulations 2.3 Health Hazards or Risks From Exposure: Symptoms of Overexposure by Route of Exposure: The most significant routes of overexposure for this product are by contact with skin or eyes. The symptoms of overexposure are described in the following paragraphs. Acute: Inhalation: Inhalation of vapors may cause respiratory irritation. Skin Contact: Skin contact may cause irritation. Eye Contact: Contact with eyes may cause serious irritation. Ingestion: Ingestion of this product may cause irritation. Chronic: May cause damage to organs through prolonged or repeated exposure. Target Organs: Acute: Eyes, Skin, Respiratory system Chronic: Internal organs