������ Dioxide

Physical hazards

Gases under pressure Liquefied gas

Health hazards

Acute toxicity, inhalation Category 3 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Germ cell mutagenicity Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation

Environmental hazards

This mixture does not meet the classification criteria according to OSHA HazCom 2012. OSHA defined hazards This mixture does not meet the classification criteria according to OSHA HazCom 2012.

Signal word

Danger

Hazard statements

Contains gas under pressure; may explode if heated. Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation. Suspected of causing genetic defects.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe gas. Use only outdoors or in a well-ventilated area. Wash hands and face thoroughly after handling. Wear protective gloves/clothing and eye/face protection.

Response

IF SWALLOWED Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see this label). Wash contaminated clothing before reuse. Material name: ������ Dioxide SDS US ������ Version # 01 Issue date 03-15-2015 86

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise No OSHA defined hazard classes. Other hazards which do not result in classification:

Classified (HNOC)

Toxic fumes, gases or vapours may evolve on burning. Severe, short-term exposures may cause long-lasting respiratory effects, e.g. Reactive Airways Dysfunction (RADS), due to the material's severe irritating properties. Contact with liquefied gas might cause frostbites, in some cases with tissue damage. Direct contact with liquefied gas may cause frostbite and corrosive injury to the eyes.

Additional information

Keep away from heat. Make sure valves on gas cylinders are fully opened when gas is used. Open cylinder valve slowly to prevent rapid decompression and damage to valve seat. Use smallest possible amounts in designated areas with adequate ventilation. Shut flow off at cylinder valve and not just at the regulator after use. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Secure cylinders in an upright position at all times, close all valves when not in use. Establish written emergency plan and special training where chlorine is used. Regularly inspect and test piping and containers used for ������ dioxide service.