VF22Pro+ Part A

Hazard statements (CLP)

H317

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Classification of the hazardous chemical This product contains less than 1% respirable crystalline silica, so it does not require classification WHS Classification of this product has been carried out in accordance with Model Work Health and Safety Regulations(Hazardous Chemicals) Amendment 2022 Skin Sens. 1: Sensitisation, skin, Category 1, H317 2.2 Label elements, including precautionary statements: WHS: Warning

Hazard statements

Skin Sens. 1: H317 - May cause an allergic skin reaction.

Precautionary statements

P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection. P302+P352 IF ON SKIN Wash with plenty of soap and water P333+P313 If skin irritation or rash occurs Get medical advice/attention P501: Dispose of contents/ container in accordance with local/regional/national/international regulation.

Other hazards which do not result in classification

Non-applicable SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITH SCHEDULE 8

2.1 Classification of the substance or mixture

This product contains less than 1% respirable crystalline silica, so it does not require classification WHS: Classification of this product has been carried out in accordance with Model Work Health and Safety Regulations(Hazardous Chemicals) Amendment 2022 Skin Sens. 1: Sensitisation, skin, Category 1, H317 2.2 Label elements, including precautionary statements: WHS: Warning Hazard statements: Skin Sens. 1: H317 - May cause an allergic skin reaction. Precautionary statements: P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P501: Dispose of contents/ container in accordance with local/regional/national/international regulation. 2.3 Other hazards which do not result in classification: Non-applicable SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITH SCHEDULE 8 3.1 Substances: Non-applicable 3.2 Mixtures: Chemical description: Mixture composed of additives, pigments and resins Components: In accordance with Schedule 8 (WHS Regulations), the product contains: Identification Chemical name/Classification Concentration Quartz (RCS < 1 %) CAS: 14808-60-7 30 - <60 % SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITH SCHEDULE 8 (continued) Identification Chemical name/Classification Concentration Calcium Carbonate CAS: 471-34-1 10 - <30 % Methacrylic acid, monoester with propane-1,2-diol CAS: 27813-02-1 <10 % Eye Irrit. 2A: H319; Skin Sens. 1: H317 - Warning Vinyltoluene CAS: 25013-15-4 <10 % Flam. Liq. 3: H226; Skin Irrit. 2: H315 - Warning To obtain more information on the hazards of the substances consult sections 11, 12 and 16. SECTION 4: FIRST AID MEASURES 4.1 Description of necessary first aid measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist. By skin contact: May cause an allergic skin reaction. In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of changes on the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Safety Data Sheet By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2 Symptoms caused by exposure: Acute and delayed effects are indicated in sections 2 and 11. 4.3 Medical attention and special treatment: Non-applicable SECTION 5: FIREFIGHTING MEASURES 5.1 Suitable extinguishing equipment: Suitable extinguishing media: Product is non-flammable under normal conditions of storage, manipulation and use, but the product contains flammable substances. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. Unsuitable extinguishing media: IT IS RECOMMENDED NOT to use full jet water as an extinguishing agent. 5.2 Specific hazards arising from the chemical: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3 Special protective equipment and precautions for fire fighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) Additional provisions: SECTION 5: FIREFIGHTING MEASURES (continued) Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: For non-emergency personnel: Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal For emergency responders: Wear protective equipment. Keep unprotected persons away. See section 8. 6.2 Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water. 6.3 Methods and materials for containment and cleaning up: It is recommended: Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal 6.4 Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling: A.- General precautions for safe use Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights. Maintain order, cleanliness and dispose of using safe methods (section 6). B.- Technical recommendations for the prevention of fires and explosions Due to its non-flammable nature, the product does not present a fire risk under normal conditions of storage, manipulation and use. C.- Technical recommendations on general occupational hygiene Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.- Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2 Conditions for safe storage, including any incompatibilities: A.- Technical measures for storage Minimum Temp.: 5 ºC Maximum Temp.: 30 ºC Maximum time: 6 Months B.- General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3 Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1 Exposure control measures: Substances whose occupational exposure limits have to be monitored in the workplace: SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION (continued) Workplace Exposure Standards for Airborne Contaminants 01/10/2022: Identification Occupational exposure limits Quartz (RCS < 1 %) TWA 0.05 mg/m³ CAS: 14808-60-7 STEL Calcium Carbonate TWA 10 mg/m³ CAS: 471-34-1 STEL Vinyltoluene TWA 50 ppm 242 mg/m³ CAS: 25013-15-4 STEL 100 ppm 483 mg/m³ Nuisance dust: Inhalable dust 10 mg/m3 // Respirable dust 4 mg/m3 8.2 Engineering controls: A.- Individual protection measures, for example personal protective equipment (PPE) As a preventative measure it is recommended to use basic Personal Protection Equipment. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B.- Respiratory protection Pictogram PPE Remarks Replace when there is a taste or smell of the contaminant inside the face mask. If Filter mask for gases and vapours the contaminant comes with warnings it is recommended to use isolation Mandatory equipment. respiratory tract protection C.- Specific protection for the hands Pictogram PPE Remarks Replace gloves in case of any sign of damage. For prolonged periods of exposure Protective gloves against minor risks to the product for professional users/industrials, we recommend using chemical protection gloves Mandatory hand protection As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application. D.- Eye and face protection Pictogram PPE Remarks Clean daily and disinfect periodically according to the manufacturer´s instructions. Panoramic glasses against splash/projections. Use if there is a risk of splashing. Mandatory face protection E.- Bodily protection Pictogram PPE Remarks Work clothing Replace before any evidence of deterioration. Anti-slip work shoes Replace before any evidence of deterioration. F.- Additional emergency measures Emergency measure Standards Emergency measure Standards ANSI Z358-1 DIN 12 899 ISO 3864-1:2011, ISO 3864-4:2011 Emergency shower Eyewash stations SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION (continued) Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 ºC: Solid Appearance: Paste Color: Cream Odor: Aromatic Odour threshold: Non-applicable * Volatility: Boiling point at atmospheric pressure: Non-applicable * Vapour pressure at 20 ºC: Non-applicable * Vapour pressure at 50 ºC: Non-applicable * Evaporation rate at 20 ºC: Non-applicable * Product description: Density at 20 ºC: Non-applicable * Relative density at 20 ºC: 1.65 Dynamic viscosity at 20 ºC: Non-applicable * Kinematic viscosity at 20 ºC: Non-applicable * Kinematic viscosity at 40 ºC: >20.5 mm²/s Concentration: Non-applicable * pH: Non-applicable * Vapour density at 20 ºC: Non-applicable * Partition coefficient n-octanol/water 20 ºC: Non-applicable * Solubility in water at 20 ºC: Non-applicable * Solubility properties: Non-applicable * Decomposition temperature: Non-applicable * Melting point/freezing point: Non-applicable * Flammability: Flash Point: Non-applicable Flammability (solid, gas): Non-applicable * Autoignition temperature: 355 ºC Lower flammability limit: Non-applicable * Upper flammability limit: Non-applicable * Explosive (Solid): Lower explosive limit: Non-applicable * Upper explosive limit: Non-applicable * Particle characteristics: Median equivalent diameter: Non-applicable * 9.2 Other information: *Not relevant due to the nature of the product, not providing information property of its hazards. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Information with regard to physical hazard classes: Explosive properties: Non-applicable * Oxidising properties: Non-applicable * Corrosive to metals: Non-applicable * Heat of combustion: Non-applicable * Aerosols-total percentage (by mass) of flammable Non-applicable * components: Other safety characteristics: Surface tension at 20 ºC: Non-applicable * Refraction index: Non-applicable * *Not relevant due to the nature of the product, not providing information property of its hazards. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2 Chemical stability: Chemically stable under the indicated conditions of storage, handling and use. 10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4 Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Precaution Not applicable 10.5 Incompatible materials: Acids Water Oxidising materials Combustible materials Others Avoid strong acids Not applicable Avoid direct impact Not applicable Avoid alkalis or strong bases 10.6 Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO ), carbon monoxide and other organic compounds. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A- Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for consumption. For more information see section 3 - Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances classified as hazardous for this effect. For more information see section 3. B- Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for inhalation. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. C- Contact with the skin and the eyes (acute effect): SECTION 11: TOXICOLOGICAL INFORMATION (continued) - Contact with the skin: Based on available data, the classification criteria are not met. However, it contains substances classified as hazardous for skin contact. For more information see section 3. - Contact with the eyes: Based on available data, the classification criteria are not met. However, it does contain substances classified as hazardous for this effect. For more information see section 3. D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for the effects mentioned. For more information see section 3. IARC: Vinyltoluene (3); Titanium dioxide (2B) - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. - Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous with sensitising effects. For more information see section 3. - Skin: Prolonged contact with the skin can result in episodes of allergic contact dermatitis. F- Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. H- Aspiration hazard: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. Other information: Non-applicable Specific toxicology information on the substances: Identification Acute toxicity Genus Methacrylic acid, monoester with propane-1,2-diol LD50 oral 11200 mg/kg Rat CAS: 27813-02-1 LD50 dermal >5000 mg/kg Rabbit LC50 inhalation >20 mg/L Vinyltoluene LD50 oral >5000 mg/kg Rat CAS: 25013-15-4 LD50 dermal >5000 mg/kg LC50 inhalation 1.5 mg/L (ATEi) Calcium Carbonate LD50 oral >5000 mg/kg Rat CAS: 471-34-1 LD50 dermal >5000 mg/kg LC50 inhalation >5 mg/L Quartz (RCS < 1 %) LD50 oral >5000 mg/kg CAS: 14808-60-7 LD50 dermal >5000 mg/kg LC50 inhalation >5 mg/L SECTION 12: ECOLOGICAL INFORMATION The experimental information related to the eco-toxicological properties of the product itself is not available 12.1 Ecotoxicity: Acute toxicity: Identification Concentration Species Genus Calcium Carbonate LC50 56000 mg/L (96 h) Gambussia afinis Fish CAS: 471-34-1 EC50 Non-applicable EC50 Non-applicable SECTION 12: ECOLOGICAL INFORMATION (continued) Identification Concentration Species Genus Methacrylic acid, monoester with propane-1,2-diol LC50 833 mg/L (96 h) Scophthalmus maximus Fish CAS: 27813-02-1 EC50 210 mg/L (48 h) Acartia tonsa Crustacean EC50 Non-applicable Vinyltoluene LC50 7.6 mg/L (96 h) Salmo gairdneri Fish CAS: 25013-15-4 EC50 1.3 mg/L (48 h) Daphnia magna Crustacean EC50 2.6 mg/L (72 h) Selenastrum capricornutum Algae Chronic toxicity: Identification Concentration Species Genus Methacrylic acid, monoester with propane-1,2-diol NOEC Non-applicable CAS: 27813-02-1 NOEC 45.2 mg/L Daphnia magna Crustacean Vinyltoluene NOEC 1.16 mg/L N/A Fish CAS: 25013-15-4 NOEC 0.32 mg/L Daphnia magna Crustacean 12.2 Persistence and degradability: Substance-specific information: Identification Degradability Biodegradability Methacrylic acid, monoester with propane-1,2-diol BOD5 Non-applicable Concentration Non-applicable CAS: 27813-02-1 COD Non-applicable Period Non-applicable BOD5/COD Non-applicable % Biodegradable 81 % 12.3 Bioaccumulative potential: Substance-specific information: Identification Bioaccumulation potential Methacrylic acid, monoester with propane-1,2-diol BCF 3 CAS: 27813-02-1 Pow Log 0.97 Potential Low Vinyltoluene BCF 5 CAS: 25013-15-4 Pow Log 3.44 Potential Low 12.4 Mobility in soil: Identification Absorption/desorption Volatility Methacrylic acid, monoester with propane-1,2-diol Koc 80 Henry 9E-4 Pa·m³/mol CAS: 27813-02-1 Conclusion High Dry soil Non-applicable Surface tension Non-applicable Moist soil Non-applicable Vinyltoluene Koc Non-applicable Henry Non-applicable CAS: 25013-15-4 Conclusion Non-applicable Dry soil Non-applicable Surface tension 3.2E-2 N/m (20 ºC) Moist soil Non-applicable 12.5 Results of PBT and vPvB assessment: Non-applicable 12.6 Other adverse effects: Not described SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Disposal methods: Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations. In case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non- dangerous residue. Waste should not be disposed of to drains. See epigraph 6.2. Regulations related to waste management: Legislation related to waste management: SECTION 13: DISPOSAL CONSIDERATIONS (continued) Basel Convention (Hazardous Waste) Hazardous Waste (Regulation of Exports and Imports) Act 1989 and Amendments SECTION 14: TRANSPORT INFORMATION This product is not regulated for transport. SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations: Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Industrial Chemicals Act 2019: Industrial Chemicals (Notification and Assessment) Act 1989 SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with WHS regulations and Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals. Texts of the legislative phrases mentioned in section 2: H317: May cause an allergic skin reaction. Texts of the legislative phrases mentioned in section 3: The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3 WHS: Eye Irrit. 2A: H319 - Causes serious eye irritation. Flam. Liq. 3: H226 - Flammable liquid and vapour. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. Advice related to training: Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: http://www.safeworkaustralia.gov.au/ Abbreviations and acronyms: ADG: Australian Code for the Transport of Dangerous Goods by Road and Rail IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 CL50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon IARC: International Agency for Research on Cancer The information contained in this safety data sheet is based on sources, technical knowledge and current Australian legislation, without being able to guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified. END OF SAFETY DATA SHEET SECTION 1: IDENTIFICATION 1.1 Product identifier: VF22Pro+ Part B Other means of identification: Non-applicable 1.2 Recommended use of the chemical and restrictions on use: Relevant uses: Adhesive for construction Uses advised against: All uses not specified in this section or in section 7.3 1.3 Details of manufacturer or importer: Allfasteners PTY LTD 78 – 84 Logistics Street VIC 3042 Keilor Park - Austrailia Phone: 03 9330 0555 - Fax: 03 9338 6434 support@allfasteners.com.au 1.4 Emergency phone number: 03 9330 0555 (AUS 13 11 26 / NZ 0800 764 766) SECTION 2: HAZARD(S) IDENTIFICATION 2.1 Classification of the hazardous chemical: WHS: Classification of this product has been carried out in accordance with Model Work Health and Safety Regulations(Hazardous Chemicals) Amendment 2022 Eye Irrit. 2A: Eye irritation, Category 2A, H319 Skin Sens. 1: Sensitisation, skin, Category 1, H317 2.2 Label elements, including precautionary statements: WHS: Warning Hazard statements: Eye Irrit. 2A: H319 - Causes serious eye irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. Precautionary statements: P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P501: Dispose of contents/ container in accordance with local/regional/national/international regulation. 2.3 Other hazards which do not result in classification: Non-applicable SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITH SCHEDULE 8 3.1 Substances: Non-applicable 3.2 Mixtures: Chemical description: Mixture composed of additives, pigments and resins Components: In accordance with Schedule 8 (WHS Regulations), the product contains: - CONTINUED ON NEXT PAGE - SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITH SCHEDULE 8 (continued) Identification Chemical name/Classification Concentration Glycerol CAS: 56-81-5 30 - <60 % Dibenzoyl peroxide CAS: 94-36-0 10 - <30 % Eye Irrit. 2A: H319; Org. Perox. B: H241; Skin Sens. 1: H317 - Danger Zinc distearate CAS: 557-05-1 <10 % To obtain more information on the hazards of the substances consult sections 11, 12 and 16. Other information: Identification M-factor Dibenzoyl peroxide Acute 10 CAS: 94-36-0 Chronic 10 Identification Specific concentration limit Dibenzoyl peroxide % (w/w) >=52: Org. Perox. B - H241 CAS: 94-36-0 35<= % (w/w) <52: Org. Perox. D - H242 SECTION 4: FIRST AID MEASURES 4.1 Description of necessary first aid measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist. By skin contact: May cause an allergic skin reaction. In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of changes on the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Safety Data Sheet By eye contact: Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product. By ingestion/aspiration: In case of consumption, seek immediate medical assistance showing the SDS of this product. 4.2 Symptoms caused by exposure: Acute and delayed effects are indicated in sections 2 and 11. 4.3 Medical attention and special treatment: Non-applicable SECTION 5: FIREFIGHTING MEASURES 5.1 Suitable extinguishing equipment: Suitable extinguishing media: Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. Unsuitable extinguishing media: IT IS RECOMMENDED NOT to use full jet water as an extinguishing agent. 5.2 Specific hazards arising from the chemical: - CONTINUED ON NEXT PAGE - SECTION 5: FIREFIGHTING MEASURES (continued) As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3 Special protective equipment and precautions for fire fighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: For non-emergency personnel: Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal For emergency responders: Wear protective equipment. Keep unprotected persons away. See section 8. 6.2 Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and underground water. 6.3 Methods and materials for containment and cleaning up: It is recommended: Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal 6.4 Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling: A.- General precautions for safe use Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights. Maintain order, cleanliness and dispose of using safe methods (section 6).