Methyllithium, 1-2M in ether

Hazard statements (CLP)

H224, H250, H260, H302, H314, H318, H336

Code

Statements

H224

Extremely flammable liquid and vapour

Physical hazards

Flammable liquids Category 1 (H224) Substances/mixtures which, in contact with water, emit flammable gases Category 1 (H260) Pyrophoric liquids Category 1 (H250)

Health hazards

Acute oral toxicity Category 4 (H302) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Specific target organ toxicity - (single exposure) Category 3 (H336)

Environmental hazards

Based on available data, the classification criteria are not met

Hazard statements

see section 16 H224 - Extremely flammable liquid and vapor H250 - Catches fire spontaneously if exposed to air H260 - In contact with water releases flammable gases which may ignite spontaneously H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H336 - May cause drowsiness or dizziness EUH014 - Reacts violently with water EUH019 - May form explosive peroxides EUH066 - Repeated exposure may cause skin dryness or cracking

Signal word

Danger

Precautionary statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection P335 + P334 - Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P231 + P232 - Handle and store contents under inert gas. Protect from moisture. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

2.3 Other hazards

Toxic to terrestrial vertebrates