Phenylmagnesium bromide, 3M in ether

Hazard statements

C Corrosive F+ Extremely flammable Information pertaining to particular dangers for man and environment R 12 Extremely flammable. R 14/15 Reacts violently with water, liberating extremely flammable gases. R 19 May form explosive peroxides. R 22 Harmful if swallowed. R 35 Causes severe burns. R 66 Repeated exposure may cause skin dryness or cracking R 67 Vapours may cause drowsiness and dizziness

Classification system

HMIS ratings (scale 0-4) (Hazardous Materials Identification System) HEALTH 3 Health (acute effects) = 3 FIRE 4 Flammability = 4 Reactivity = 3 REACTIVITY 3

2.2 Label elements

Danger 2.6/1 - Extremely flammable liquid and vapour. 2.12/2 - In contact with water releases flammable gas. Danger 3.1/3 - Toxic if swallowed. 3.8/3 - May cause drowsiness or dizziness. Danger 3.2/1A - Causes severe skin burns and eye damage.

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

Response

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Rinse mouth. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire Use for extinction CO2, powder or water spray

Storage

Store in a dry place. Store in a closed container. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.