Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
2.5-5%
General Information
Revision date
2015-01-08
Product name
MICROSEALER-50
Icons in SDS
Company Information
company name
ALCHIMICA S.A
e-mail address of the competent person responsible for the Safety Data Sheet
alchimica@alchimica.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
EC 67/548 or EC 1999/45
Classifications
R10 Carc. Cat. 3; R40 Xn; R20/21 Xi; R36/37/38 Xn ; R42/43
Hazard categories
Regulation EC 1272/2008 (CLP)
Health hazards
Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332 Skin irritation - Category 2 - Warning (CLP : Skin Irrit. 2) H315 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319 Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) H334 Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317 Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351 Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373
Physical hazards
Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3) H226 2. Hazards identification (continued)
2.2 Label elements
EC 67/548 or EC 1999/45 Regulation EC 1272/2008 (CLP)
Hazard pictograms
ê X : Xn : Harmful M “ M —
R-phrase(s)
R10 : Flammable. R20/21 : Harmful by inhalation and in contact with skin. R36/37/38 : Irritating to eyes, respiratory system and skin. R40 : Limited evidence of a carcinogenic effect. R42/43 : May cause sensitization by inhalation and skin contact.
S-phrase(s)
S2 : Keep out of the reach of children. S23 : Do not breathe the gas, fumes, vapours, spray. S25 : Avoid contact with eyes. S36/37 : Wear suitable protective clothing and gloves. S40 : To clean the floor and all objects contaminated by this material, use xylene. S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S51 : Use only in well-ventilated areas. S63 In case of accident by inhalation remove casualty to fresh air and keep at rest.
Contains
Xylene - methylenediphenyl diisocyanate isomers and homologues , <<Contains isocyanates. See information supplied by the manufacturer>>. : Xylene - methylenediphenyl diisocyanate isomers and homologues : EUH204: Contains isocyanates. May produce an allergic reaction
Signal word
Danger
Hazard statements
H226 : Flammable liquid and vapour. H351 : Suspected of causing cancer. H319 : Causes serious eye irritation. H315 : Causes skin irritation. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 : May cause an allergic skin reaction. H332 : Harmful if inhaled. H335 : May cause respiratory irritation. H373 : May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use. P201: Obtain special instructions before use. 2. Hazards identification (continued)
Prevention
P280: Wear eye protection, face protection. P280: Wear protective gloves, protective clothing, eye protection, face protection. P285: In case of inadequate ventilation wear respiratory protection. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace.
Response
P321: Specific treatment (see on this label). P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P370+P378 In case of fire Use all extinguishing media for extinction P304+P340 IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P308+P313 If exposed or concerned get medical advice P312: Call a POISON CENTER or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs Get medical advice P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor. P363: Wash contaminated clothing before reuse.
Storage
P403+P235: Store in well-ventilated place. Keep cool. P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. • Disposal considerations : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
2.3 Other hazards
The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.