New S.P.I.F. II

SECTION 2: Hazards identification

(29 CFR 1910.1200) Flammable Liquid, Category 4 Eye Damage/Irritation, Category 2A Acute Toxicity- Inhalation, Category 4 Specific Target Organ Toxicity (Single Toxicity), Category 3

Signal word

Warning

Hazard statements

Combustible liquid Causes serious eye irritation Harmfiul if inhaled May cause drowsiness or dizziness

Precautionary statements

Keep away from flames and hot surfaces. – No smoking. Avoid breathing dust/fume/gas/mist/ vapors/spray. Use only outdoors or in a well- ventilated area. Wash hands thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical advice/attention If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor/.../if you feel unwell. In case of fire: Use water spray, alcohol resistant foam, carbon dioxide (CO2), dry extinguishing powder to extinguish. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards which do not result in classification

Exposure to the concentration higher than TLV may cause critical effects such as CNS impairment. 2.4. Unknown acute toxicity Not applicable 3.1. Substances Not applicable 3.2. Mixture Name

Product definition

Ethene, 1,2-dichloro-, (1E)- (CAS No) 156-60-5 90 - 100 (Z)-1-chloro-2,3,3-trifluoropropene (CAS No) 1263679-68-0 5 - 10 2-Propanol, 1-methoxy-, 2-acetate (CAS No) 108-65-6 The specific chemical\ component identities and/or the exact component percentages of this material may be withheld as trade secrets.

Further information

Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). 6.1. Personal precautions, protective equipment and emergency procedures General measures Stop leak if safe to do so. Remove ignition sources. Use special care on handling. Avoid source of ignition and heat. No open flames. No smoking. Danger of slipping by leaking/spilling product. Avoid contact with eyes. Avoid breathing mist, spray and vapors. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Equip cleanup crew with proper protection. Emergency procedures Evacuate unnecessary personnel. Depending on the condition, adequate ventilation might be required. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in confined and low areas. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect all waste in suitable and labelled containers and dispose according to local legislation. Store away from other materials. Ensure all national/local regulations are observed. 6.4. Reference to other sections Refer to section 8 and 13. 7.1. Precautions for safe handling Additional hazards when processed Handle empty containers with care because residual vapors may be flammable. Precautions for safe handling Read label before use. Obtain special instructions before use. Obtain special instructions before use. No smoking, open flames or sources of ignition in handling and storage area. Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Containes even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar opertaions on or near empty containes. Storage conditions Keep only in the original container in a cool well-ventilated place. Keep container closed when not in use. Keep away from incompatible materials. Keep away from sources of ignition, heat and open flames. Incompatible materials Oxidizing agents. Strong acids. Bases. Incompatible condition Avoid sources of ignition, heat and open flames. 7.3. Specific end use(s) No additional information available 8.1. Control parameters trans- Dichloroethylene (156-60-5) ACGIH ACGIH TWA (ppm) 200 ppm ACGIH Do not eat, drink or smoke during use. 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear Color Colorless Odor Pleasant Odor threshold No data available pH No data available Relative evaporation rate (butyl acetate=1) No data available Melting point Not applicable Freezing point No data available Boiling point > 104 ºF (40 ºC) Flash point 115.7ºF (46.5 ºC) Auto-ignition temperature No data available Decomposition temperature No data available Flammability (solid, gas) Not applicable Vapor pressure 35 – 45 kPa (at 25 ºC) Relative vapor density at 20 °C No data available Relative density 1.30 – 1.40 (water=1) Solubility ca 6 g/l (at ambient temperature) Log Pow No data available Log Kow No data available Viscosity, kinematic No data available Viscosity No data available Explosive properties No data available Oxidising properties No data available Explosive limits No data available No additional information available 10.1. Reactivity No additional information available 10.2. Chemical stability The product is stable at normal handling and storage condition 10.3. Possibility of hazardous reactions Under normal condition of use and storage, hazardous polymerization will not occur. Contact with caustic soda, caustic potash or oxidizing materials may form shock-sensitive compounds. 10.4. Conditions to avoid Exposure to high temperature may produce hazardous decomposition material. 10.5. Incompatible materials Oxidizing agents. Strong acids. Bases. 10.6. Hazardous decomposition products Thermal decomposition products: Carbon oxides, Hydrogen chloride, and phosgene gases

Remarks

Central Nervous System impairment Eye irritation 8.2. Exposure controls Appropriate engineering controls Ensure good ventilation of the work station. Eyewash fountains are suggested near any potential exposure. Use process enclosure, local exhaust ventilation or other engineering controls to keep workers exposure to the airborne contaminant below ant recommended limits. Personal protective equipment Handle in accordance with good industrial hygiene and safety practices. Avoid all unnecessary exposure. For certain operations, additional Personal Protection Equipment (PPE) may be required. Hand protection In case of repeated or prolonged contact wear gloves. Eye protection Wear goggles if splashing or spraying is anticipated. Skin and body protection In case of repeated or prolonged exposure Personal protective clothing should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.