DOLPHIN PU FOAM

Hazard statements (CLP)

H222, H315, H317, H319, H332, H334, H335, H351, H362, H373

Code

Statements

H222

Extremely flammable aerosol

CLP CLASSIFICATION

Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category

Hazard statements

FLAM. AEROSOL category 1 H222: Extremely flammable aerosol. CARC. category 2 H351: Suspected of causing cancer LACT. H362: May cause harm to breast-fed children ACUTE TOX. category 4 H332: Harmful if inhaled. STOT RE category 2 H373: May cause damage to organs through prolonged or repeated exposure if inhaled EYE IRRIT. category 2 H319: Causes serious eye irritation STOT SE category 3 H335: May cause respiratory irritation SKIN IRRIT. category 2 H315: Causes skin irritation. RESP. SENS. category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. SKIN SENS. category 1 H317: May cause an allergic skin reaction H222 Extremely flammable aerosol. H351 Suspected of causing cancer H362 May cause harm to breast-fed children. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure if inhaled. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.

EU Classification

Directive 67/548/EEC-1999/45/EC Classified as dangerous in accordance with the criteria of Directives 67/548/EEC and 1999/45/EC F+; R12 Extremely flammable. Carc. Cat. 3; R40 Limited evidence of a carcinogenic effect Xn; R20 - 48/20 Harmful by inhalation Harmful: danger of serious damage to health by prolonged exposure through inhalation. Xi; R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. R64 May cause harm to breastfed babies.

2.2 Label elements

Labelling according to Regulation EC No 1272/2008 (CLP)

Hazard pictograms

Contains polymethylene polyphenyl isocyanate, 4,4'-methylenediphenyl diisocyanate

Signal word

Danger

Precautionary statements

P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use P280 Wear protective gloves and eye protection/face protection P260 Do not breathe dust/fume/gas/mist/vapors/spray P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician P410 + P412 Protect from sunlight do no expose to temperatures exceeding 50 °C/ 122°F P501 Dispose of contents/container to manufacturer/competent authority

Additional information

Persons already sensitized to di isocyanates may develop allergic reactions when using this product.  Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product  This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Labelling according to Directive 67/548/EEC-1999/45/EC (DSD/DPD) Labels Extremely Flammable Harmful

Contains

polyethylene polyphenyl isocyanate, 4,4'-methylenediphenyl diisocyanate

R-phrase(s)

20 Harmful by inhalation 36/37/38 Irritating to eyes, respiratory system and skin 40 Limited evidence of a carcinogenic effect 42/43 May cause sensitisation by inhalation and skin contact 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation 64 May cause harm to breastfed babies

S-phrase(s)

23 Do not breathe spray 36/37 Wear suitable protective clothing and gloves 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label) 51 Use only in well-ventilated areas (63) (In case of accident by inhalation: remove casualty to fresh air and keep at rest) Additional recommendations  Keep away from sources of ignition - No smoking  Keep out of the reach of children.  Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C.  Do not pierce or burn, even after use.  Do not spray on a naked flame or any incandescent material.  Contains isocyanates. See information supplied by the manufacturer.  Persons already sensitised to diisocyanates may develop allergic reactions when using this product.  Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product  This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

2.3 Other hazards

DSD/DPD  Due to insufficient data no statement can be made whether the component(s) fulfil(s) the criteria of PBT and vPvB according to Annex XIII of Regulation (EC) No 1907/2006 May be ignited by sparks Gas/vapour spreads at floor level: ignition hazard Aerosol may explode under the effect of heat CLP  Due to insufficient data no statement can be made whether the component(s) fulfil(s) the criteria of PBT and vPvB according to Annex XIII of Regulation (EC) No 1907/2006  May be ignited by sparks  Gas/vapour spreads at floor level: ignition hazard  Aerosol may explode under the effect of heat