Diethyl azodicarboxylate solution

Hazard statements (CLP)

H226, H242, H304, H315, H319, H332, H335, H336, H361, H373, H401, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification (United States) GHS Classification (United States) Flammable liquids (Category 3) Self-reactive chemicals (Type C) Acute toxicity, Inhalation (Category 4) Skin irritation (Category 2) Eye irritation (Category 2A) Reproductive toxicity (Category 2) Specific target organ toxicity - single exposure (Category 3), Respiratory system, Central Specific target organ toxicity - repeated exposure (Category 2), Central nervous system

Aspiration hazard

(Category 1) Short-term (acute) aquatic hazard (Category 2) Long-term (chronic) aquatic hazard (Category 3)

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H242 Heating may cause a fire. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H373 Causes damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P220 Keep/Store away from clothing and other combustible materials. P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a poison center or doctor. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340+P312 If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF EXPOSED or concerned: Get medical advice/attention. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P370+P378 In case of fire: Use dry sand, dry chemical, CO2, water spray or alcohol-resistant foam for extinction. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P420 Store away from other materials. P501 Dispose of contents/container to an approved waste disposal plant.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Flammable liquids (Category 3) Self-reactive chemicals (Type C) Acute toxicity, Inhalation (Category 4) Skin irritation (Category 2) Eye irritation (Category 2A) Reproductive toxicity (Category 2) Specific target organ toxicity - single exposure (Category 3), Respiratory system, Central Specific target organ toxicity - repeated exposure (Category 2), Central nervous system Aspiration hazard (Category 1) Short-term (acute) aquatic hazard (Category 2) Long-term (chronic) aquatic hazard (Category 3) Pictogram(s) Signal word: Danger Hazard statement(s) H226 Flammable liquid and vapor. H242 Heating may cause a fire. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H373 Causes damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.