SODIUM BISULFITE SOLUTION

AK-KİM KİMYA SAN. VE TİC. A.Ş

Revision date : 2012-07-30

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GHS07
Health risk rating 3
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

231-548-0/7631-90-5

Name of the chemical

Sodium hydrogensulphite; Sodium bisulphite

Concentration

15-40

EC/CAS

231-791-2/7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

65-60

General Information

Revision date

2012-07-30

Product name

SODIUM BISULFITE SOLUTION

Chemical name

Sodium Bisulfite Solution

CAS No.

7631-90-5

1.2.1 Relevant identified uses

Antichlore in bleaching fibers and mordant in textile industry

1.2.2. Uses advised against

See chapter 16 for a general overview

Icons in SDS

GHS07 M004

Company Information

company name

AK-KİM KİMYA SAN. VE TİC. A.Ş

e-mail address of the competent person responsible for the Safety Data Sheet

ali.ketir@akkim.com.tr

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H302

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

CLP CLASSIFICATION

Acute toxicity (oral), Category 4

2.1 Classification of the substance or mixture

According to Regulation to 67/548/EC ⋅ Xn;R22 ⋅ R31

2.2 Label elements

According to Regulation (EC) No 1272/2008 [CLP1/GHS2] According to Regulation to 67/548/EEC

Hazardous Ingredients

Sodium bisulfite · Sodium bisulfite solution

Signal word

WARNING

Hazard statements

H302 Harmful if swallowed. According to the EC Regulation No. 67/548/EEC This product is classified as follows: · Xn;R22 · R31 R22 Harmful if swallowed R31 Contact with acids liberates toxic gas

Precautionary statements

General ⋅ None S7/9 Keep container tightly closed and in a well-ventilated place. S25 Avoid contact with eyes. S36 Wear suitable protective clothing. S46 If swallowed, seek medical advice immediately and show this container or label.

Prevention

P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product.

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P330 Rinse mouth

Storage

None

Disposal

None

Supplemental label elements

Statements EUH031 Contact with acids liberates toxic gas.

Special rules for supplemental label elements for certain mixtures

None.

Additional information

Not Applicable 2.3.1. Skin Contact Directly skin contact or after time delayed may cause slight but significant inflammation. Repeated exposure may cause contact dermatitis which is characterized such as redness, swelling and blisters (blisters, blisters) symptoms. Open cuts, worn or irritated skin should not be exposed to this material. Entry ways to the bloodstream such as cuts, abrasions or lesions may cause create systemic damage with harmful effects. 2.3.2. Eye Contact Based on the available evidence or practical experience, suggested that, the material may cause eye irritation on significant number of people. Long-term eye contact may cause characterized as a temporary redness of the conjunctival inflammation (wind burn like). 2.3.3. Ingestion Accidental oral uptake of the material may be harmful. The experiments done on animals shows; less than 150 grams of oral intake amount may be fatal or cause serious damage to the person's health. Uptake of sulfide salts by mouth can cause irritation gastric (stomach). High doses can lead to severe colic (abdominal pain), diarrhea, circulatory disorders, depression and sometimes death of vital functions. 2.3.4. Inhalation Material may cause respiratory irritation in some people. Such a response to irritation of the body, can cause more lung damage. Inhalation of the steam or aerosols generated during the normal use of the material, can damage a person's health. 2.3.5. Long term effects Asthma-like symptoms, will continue months or even years after the end of exposure. The reason for this, reactive airways dysfunction syndrome (RADS) is non-allergic. The most important criteria for the diagnosis of RADS is a respiratory disease before and there a few minutes after exposure to irritants and non-atopic individuals with persistent asthma symptoms within hours, starts with a sudden. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchialy perreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma)following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production ⋅ None

Environmental effects

No data available

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