Note: Ingredients listed on restricted chemical lists
EC/CAS
7664-39-3
Name of the chemical
Hydrofluoric acid, its normal salts, its complexes and hydrofluorides with the exception of those given in Annex III
Concentration
N/A
General Information
Revision date
2025-12-04
Product name
Hydrogen Fluoride
Chemical name
Hydrogen fluoride
CAS No.
7664-39-3
supplier name
Airgas USA, LLC
Icons in SDS
Company Information
company name
Airgas USA, LLC
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301+H331, H310, H314
Hazard statements
Code
Statements
H301+H331
Toxic if swallowed or if inhaled
Section 2
SECTION 2: Hazards identification
Signal word
Danger
Hazard statements
H301 + H331 - Toxic if swallowed or if inhaled. H310 - Fatal in contact with skin. H314 - Causes severe skin burns and eye damage. Corrosive to the respiratory tract. Symptoms may be delayed.
Precautionary statements
General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction.
Prevention
P280 - Wear protective gloves, protective clothing and eye or face protection. P271 - Use only outdoors or in a well-ventilated area. P262 - Do not get in eyes, on skin, or on clothing. P261 - Avoid breathing vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling.
Response
P304 + P340, P310 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. P301 + P310, P330, P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353, P310 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. P302 + P310 - IF ON SKIN: Immediately call a POISON CENTER or doctor. P363 - Wash contaminated clothing before reuse. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage
P405 - Store locked up.
Disposal
P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.
2.3 Other hazards
None known. Hazards identified when used : No known significant effects or critical hazards.
2.1 Classification of the substance or mixture
ACUTE TOXICITY (dermal) - Category 1 ACUTE TOXICITY (inhalation) - Category 3 SKIN CORROSION - Category 1A SERIOUS EYE DAMAGE - Category 1