Phosphine

Air Products Plc

Revision date : 2017-01-25

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GHS02 GHS04 GHS05 GHS06 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

General Information

Revision date

2017-01-25

Product name

Phosphine

CAS No.

7803-51-2

REACH No

01-2120138413-64

1.2.1 Relevant identified uses

General Industrial

Emergency telephone

+44(0)8085 020202

Icons in SDS

Company Information

company name

Air Products Plc

e-mail address of the competent person responsible for the Safety Data Sheet

GASTECH@airproducts.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H220, H280, H314, H330, H400

Hazard statements

Code

Statements

H220

Extremely flammable gas

Section 2

2.1 Classification of the substance or mixture

Flammable gases - Category 1 H220:Extremely flammable gas. Gases under pressure - Liquefied gas. H280:Contains gas under pressure; may explode if heated. Acute toxicity - Inhalation Category 1 H330:Fatal if inhaled. Skin corrosion - Category 1B H314:Causes severe skin burns and eye damage. Acute aquatic toxicity. - Category 1 H400:Very toxic to aquatic life

Signal word

Danger

Hazard statements

H220:Extremely flammable gas. H280:Contains gas under pressure; may explode if heated. H314:Causes severe skin burns and eye damage. H330:Fatal if inhaled. H400:Very toxic to aquatic life

Prevention

P210:Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P284:Wear respiratory protection.

Response

P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P377 Leaking gas fire Do not extinguish, unless leak can be stopped safely. P381 :Eliminate all ignition sources if safe to do so.

Disposal

P501:Disposal of contents/container to be specified in accordance with regulations.

2.3 Other hazards

May ignite spontaneously in contact with air. Inhalation may be fatal. Use a back flow preventative device in the piping. Use only with equipment purged with and inert gas or evacuated prior to discharge. Use only with equipment of compatible materials of construction, rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. When returning cylinder install valve outlet cap or plug leak tight. Close valve after each use and when empty. Extremely flammable liquefied gas. May form explosive mixtures in air. Vapors may spread long distances and ignite. Immediate fire and explosion hazard exists when mixed with air at concentrations exceeding the lower flammability limit (LFL). Do not breathe gas. Direct contact with liquid can cause frostbite. Self contained breathing apparatus (SCBA) may be required.

Environmental effects

Dangerous for the environment.

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