General Information
Version
2.1
Revision date
2018-07-31
Product name
Phosphine (9.906% - 50.0%) in SilaneProduct code
supplier name
Air Liquide USA LLC
Emergency telephone
1-800-424-9300
Icons in SDS
Company Information
company name
Air Liquide USA LLC
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H220, H250, H280, H314, H318, H330
Hazard statements
Code
Statements
H220
Extremely flammable gas
Section 2
SECTION 2: Hazards identification
Classification (GHS-US)
Pyrophoric Gas H250 Flammable gases Category H220 1 Gases under pressure H280 Compressed gas Catches fire spontaneously if exposed to air Extremely flammable gas Contains gas under pressure; may explode if heated Acute toxicity H330 Fatal if inhaled (inhalation:gas) Category 1 Skin corrosion/irritation H314 Causes severe skin burns and eye damage Category 1B Serious eye damage/eye H318 irritation Category 1 Causes serious eye damage
Hazard statements
see section 16 : H220 - Extremely flammable gas H250 - Catches fire spontaneously if exposed to air H280 - Contains gas under pressure; may explode if heated H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H330 - Fatal if inhaled CGA-HG04 - May form explosive mixtures with air CGA-HG11 - Symptoms may be delayed CGA-HG22 - Corrosive to the respiratory tract
2.2 Label elements
GHS-US labeling
Hazard pictograms
GHS02 GHS04 GHS05 GHS06
Signal word
Danger
Precautionary statements
P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P222 - Do not allow contact with air. P260 - Do not breathe gas. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective gloves, protective clothing. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse 07/31/2018 EN (English US) SDS ID: 906837 Page 1 skin with water/shower P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P403 - Store in a well-ventilated place. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local/regional/national/international regulations P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P381 - Eliminate all ignition sources if safe to do so. P307+P311 - If exposed: Call a poison center/doctor P284 - Wear respiratory protection. Consult respirator supplier´s product information for the selection of the appropriate respiratory protection. CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C/125 °F CGA-PG05 - Use a back flow preventive device in the piping CGA-PG06 - Close valve after each use and when empty CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG14 - Approach suspected leak area with caution CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug CGA-PG21 - Open valve slowly
Other hazards which do not result in classification
No additional information available
Ingredient(s) with unknown acute toxicity
Not applicable