Phosphine

Hazard statements (CLP)

H220, H280, H314, H330, H400

Code

Statements

H220

Extremely flammable gas

Hazard categories

Code Regulation EC 1272/2008 (CLP)

Physical hazards

Flammable gases - Category 1 - Danger (H220) Gases under pressure - Liquefied gas - Warning (H280) : Spontaneously flammable in air.

Health hazards

Acute toxicity, Inhalation - Category 1 - Danger (H330) Skin corrosion - Category 1B - Danger (H314)

Environmental hazards

Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning ( H400)

2.1 Classification of the substance or mixture

EC 67/548 or EC 1999/ F+; R12 45 R17 T+; R26 C; R34 N; R50 2 Hazards identification (continued)

2.2 Label elements

Regulation EC 1272/2008 ( CLP) EC 67/548 or EC 1999/45

Hazard pictograms

M Á M — M » M « M Å : GHS06 - GHS02 - GHS05 - GHS04 - GHS09 ê T ê F ê C ê N : T+ : Very toxic F+ : Extremely flammable C : Corrosive N : Dangerous for the environment

Signal word

Danger

Hazard statements

H330 : Fatal if inhaled. H220 : Extremely flammable gas. H314 : Causes severe skin burns and eye damage. H280 : Contains gas under pressure; may explode if heated. H400 : Very toxic to aquatic life.

Supplemental label elements

Spontaneously flammable in air.

Prevention

P260 : Do not breathe gas, vapours. P280 : Wear protective gloves/protective clothing/eye protection/face protection. P210 : Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P273 : Avoid release to the environment.

Response

P304+P340+P315 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice / attention. P303+P361+P353+P315 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Get immediate medical advice / attention. P305+P351+P338+P315 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice / attention. P377 Leaking gas fire Do not extinguish, unless leak can be stopped safely P381 : Eliminate all ignition sources if safe to do so.

Storage

P405 : Store locked up. P403 : Store in a well-ventilated place.

R-phrase(s)

R12 : Extremely flammable. R17 : Spontaneously flammable in air. R26 : Very toxic by inhalation. R34 : Causes burns. R50 : Very toxic to aquatic organisms.

S-phrase(s)

S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 : After contact with skin, wash immediately with S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection. 2 Hazards identification (continued) S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.