Phosphine (1.09% - 1.99%) in Helium

Hazard statements (CLP)

H220, H250, H280, H315, H319, H331

Code

Statements

H220

Extremely flammable gas

Classification (GHS-US)

Pyr. Gas H250 - Catches fire spontaneously if exposed to air Flam. Gas 1 H220 - Extremely flammable gas Compressed gas H280 - Contains gas under pressure; may explode if heated Acute Tox. 3 (Inhalation:gas) H331 - Toxic if inhaled Skin Irrit. 2 H315 - Causes skin irritation Eye Irrit. 2A H319 - Causes serious eye irritation

Hazard statements

see section 16 : H220 - Extremely flammable gas H250 - Catches fire spontaneously if exposed to air H280 - Contains gas under pressure; may explode if heated H315 - Causes skin irritation H319 - Causes serious eye irritation H331 - Toxic if inhaled CGA-HG04 - May form explosive mixtures with air CGA-HG11 - Symptoms may be delayed

2.2 Label elements

GHS-US labeling

Hazard pictograms

GHS02 GHS04 GHS06 GHS07

Signal word

Danger

Precautionary statements

P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P222 - Do not allow contact with air P261 - Avoid breathing gas P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective gloves, protective clothing P284 - Wear respiratory protection. Consult respiratory device supplier´s product information for the selection of the appropriate device. P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P307+P311 - If exposed: Call a poison center/doctor P362 - Take off contaminated clothing and wash it before reuse P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely 08/27/2015 EN (English US) P381 - Eliminate all ignition sources if safe to do so P403 - Store in a well-ventilated place P405 - Store locked up P501 - Dispose of contents/container in accordance with local/regional/national/international regulations CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F) CGA-PG05 - Use a back flow preventive device in the piping CGA-PG06 - Close valve after each use and when empty CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG14 - Approach suspected leak area with caution CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug CGA-PG21 - Open valve slowly

2.3 Other hazards

No additional information available 2.4.

Ingredient(s) with unknown acute toxicity

Not applicable