Acifaz 505 EC

SECTION 2: Hazards identification

Flammable. Harmful if swallowed. Risk of serious damage to eyes. Irritating to skin. Very toxic to aquatic organisms. Toxic to bees. FIRST-AID MEAUSRES: Never give fluids or induce vomiting if patient is unconscious or is having convulsions. Ingestion Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. The decision of whether to induce vomiting or not should be made by an attending physician Eye Contact Immediate and continuous irrigation with flowing water for at least 15 minutes is imperative. Prompt medical consultation is essential. Skin Contact Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Wash contaminated clothing before reuse. Inhalation Remove to fresh air. Consult a physician. Note to Physician This material contains both a cholinesterase inhibitor and a solvent. Signs of poisoning may include dizziness, nausea, vomiting, intestinal spasms, diarrhea, contracted pupils and difficulty in breathing. Atropine by intravenous administration is the antidote of choice. Oximes may or may not be therapeutic but it is recommended that they should not be used in place of atropine. If lavage is performed, suggest endotracheal and/or oesophageal control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. Supportive care. Treatment based on judgement of physician in response to symptoms of patient. FIRE-FIGHING MEASURES: - Extinguishing Media Water fog or fine spray. Carbon dioxide. Dry chemical. Foam. Hazardous Combustion Products Hydrogen chloride, Sulphur oxides, Nitrogen oxides, Hydrogen cyanide, dependant on the intensity of the fire. Protection of Firefighters Wear protective clothing and use self-contained breathing apparatus.

Additional information

Violent eruption of containers may occur under fire conditions. Keep containers cool by spraying with water. Contain runoff to prevent entry into water or drainage systems. ACCIDENTAL RELEASE: Personal Precautions Wear appropriate safety clothing and eye/face protection Environmental Precautions Do not wash into sewers or into any body of water. Advise water authority if spillage has entered water course or drainage system Methods of Cleaning Up Soak up with sand or other non-combustible absorbent material and place into containers for disposal. For large spills, barricade area and consult manufacturer. If further assistance is required, telephone the emergency contact number. Eliminate all ignition sources. HANDLING AND STORAGE: Handling Use good personal hygiene. Do not consume or store food in the work area. Wash hands and exposed skin before eating, drinking or smoking and after work. Avoid breathing vapours. Avoid eye contact.

Storage

Product should be stored in compliance with local regulations. Store in a cool, dry, well-ventilated place in the original container. Protect from excessive heat and cold. Do not store near food, drink, animal feeding stuffs, pharmaceuticals, cosmetics or fertilisers. Keep out of reach of children. PERSONAL PROTECTION/SAFTETY: Exposure Guidelines None established for the preparation. Chlorpyrifos: ACGIH Threshold Limit Value (TLV) is 0.2 mg/m3 TWA-8 hours (skin). Supplier recommendation for solvent is 100 ppm Engineering Controls Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Respiratory Protection When airborne exposure guidelines and/or comfort levels may be exceeded, use an approved air-purifying respirator. For emergency conditions, use an approved positive-pressure selfcontained breathing apparatus. Hand/Skin Protection For brief contact, no precautions other than clean body-covering clothing and chemical resistant gloves should be needed. When prolonged or frequently repeated contact could occur, use protective clothing impervious to this material. For emergency conditions: Use protective clothing impervious to this material. Selection of specific items will depend on operation. Eye/Face Protection Use chemical goggles. If vapour exposure causes eye discomfort, use a full- face supplied-air respirator PHYSICAL AND CHEMICAL PROPERTIES: Appearance : clear liquid Colour : yellow Density : 1.09 g/ml ± 0.05 Water solubility : emulsifiable Flash point : 45 oC STABILITY AND REACTIVITY: Chemical Stability Is stable under normal storage conditions. Conditions to Avoid Avoid high temperatures (at or near flash point), open flame, sparks and direct sunlight. Contains petroleum derivative solvent - will burn. Materials to Avoid Strong basic, acidic or oxidising materials. Hazardous Decomposition Products None under normal conditions of storage and use. Additional Information Chlorpyrifos: Product undergoes exothermic decomposition which can lead to high temperatures and violent decomposition if heat developed is not removed.