ISOPROPANOL 70% v/v in WFI Quality Water

Hazard statements (CLP)

H225, H319, H336

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture CLP: STOT SE 3, Flam. Liq. 2, Eye Irrit. 2

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapour. H336 - May cause drowsiness or dizziness. H319 - Causes serious eye irritation. EUH066 - Repeated exposure may cause skin dryness or cracking. Datasheet Number: 070 - v12.2.0 1

Precautionary statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P312 - Call a POISON CENTRE or doctor if you feel unwell. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P403+P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/container to an authorised waste collection point

2.1 Classification of the substance or mixture

- CLP: STOT SE 3, Flam. Liq. 2, Eye Irrit. 2 2.2 Label elements - Signal Word: Danger Hazard statements H225 - Highly flammable liquid and vapour. H336 - May cause drowsiness or dizziness. H319 - Causes serious eye irritation. EUH066 - Repeated exposure may cause skin dryness or cracking. Datasheet Number: 070 - v12.2.0 1 SECTION 2: Hazards identification (....) Precautionary statements P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P312 - Call a POISON CENTRE or doctor if you feel unwell. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P403+P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/container to an authorised waste collection point 2.3 Other hazards SECTION 3: Composition/information on ingredients 3.2 Mixtures propan-2-ol; isopropyl alcohol; isopropanol CAS Number: 67-63-0 EC Number: 200-661-7 Concentration: 60-75% Specific Concentration Limits: None assigned M factor: Not available Acute toxicity estimate: Not available Categories: Eye Irrit. 2; STOT SE 3; Flam. Liq. 2 H Statements: H225,H336,H319 SECTION 4: First aid measures 4.1 Description of first aid measures Contact with eyes P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. Contact with skin P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Ingestion Give plenty of water to drink Do not induce vomiting P313 - Get medical advice/attention. Datasheet Number: 070 - v12.2.0 2 SECTION 4: First aid measures (....) Inhalation P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 - Get medical advice/attention if you feel unwell. 4.2 Most important symptoms and effects, both acute and delayed - May cause severe irritation - May cause redness and irritation - May cause nausea/vomiting - H335 - May cause respiratory irritation. - May cause dizziness, confusion, headache or stupor 4.3 Indication of any immediate medical attention and special treatment needed - P314 - Get medical advice/attention if you feel unwell. SECTION 5: Firefighting measures 5.1 Extinguishing media - P370+P378 - In case of fire: Use light water spray, alcohol resistant foam, carbon dioxide to extinguish. - Do not use water jets 5.2 Special hazards arising from the substance or mixture - Flammable 5.3 Advice for firefighters - Wear Positive-Pressure Breathing Apparatus - P280 - Wear protective gloves/protective clothing/eye protection/face protection. SECTION 6: Accidental release measures Spillage causes slippery surface Vapours may ignite 6.1 Personal precautions, protective equipment and emergency procedures - Wear protective clothing as per section 8 - Shut off all ignition sources - Shut off source of leak if safe to do so 6.2 Environmental precautions - Do not allow to enter public sewers and watercourses 6.3 Methods and material for containment and cleaning up - P242 - Use non-sparking tools. - Absorb spillage in inert material and shovel up - Dispose of contents to a hazardous or special waste collection point 6.4 Reference to other sections - See Section 13 Datasheet Number: 070 - v12.2.0 3 SECTION 7: Handling and storage 7.1 Precautions for safe handling - Avoid contact with skin and eyes - Ensure adequate ventilation - P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. - P280 - Wear protective gloves/protective clothing/eye protection/face protection. 7.2 Conditions for safe storage, including any incompatibilities - Keep container tightly closed, in a cool, well ventilated place - P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 7.3 Specific end use(s) - See Section 1.2 SECTION 8: Exposure controls/personal protection 8.1 Control parameters - Hazardous Material: Propan-2-ol; isopropyl alcohol; isopropanol - TLV (TWA): 400 ppm, 999 mg/m³ - TLV (STEL): 500 ppm 1250 mg/m³ 8.2 Exposure controls - P280 - Wear protective gloves/protective clothing/eye protection/face protection. - Ensure adequate ventilation - Eyewash bottles should be available SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties - Physical state: Liquid - Colour: Colourless - Odour: Alcohol odour - Melting point/Range: Not available - Boiling Point/Range: Not available - Flammability: Flammable - Flashpoint: 20.5 C c.c. (closed cup) - pH: 6.0-9.0 - Solubility in water: Completely soluble in water - Density: 0.872-0.883 g/cm³ at 20 °C - Viscosity: Non-viscous 9.2 Other information - None Datasheet Number: 070 - v12.2.0 4 SECTION 10: Stability and reactivity 10.1 Reactivity - No hazardous reactions known if used for its intended purpose 10.2 Chemical stability - This article is considered stable under normal conditions 10.3 Possibility of hazardous reactions - No hazardous reactions known if used for its intended purpose 10.4 Conditions to avoid - P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 10.5 Incompatible materials - Strong oxidising agent - Avoid contact with acid 10.6 Hazardous decomposition products - No hazardous decomposition products known SECTION 11: Toxicological information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Hazardous Material: Propan-2-ol; isopropyl alcohol; isopropanol LD₅₀ (oral, rat): >2000 mg/kg LD₅₀ (dermal, rabbit): >2000 mg/kg Skin corrosion/irritation See Section 4.1.2 Serious eye damage/irritation See Section 4.1.1 Respiratory or skin sensitisation See Section 4.1 Germ cell mutagenicity No evidence of mutagenic effects Carcinogenicity No information available Reproductive toxicity No information available STOT (specific target organ toxicity) - single exposure No information available Datasheet Number: 070 - v12.2.0 5 SECTION 11: Toxicological information (....) STOT (specific target organ toxicity) - repeated exposure No information available Aspiration hazard See Section 4.1.4 11.2 Information on other hazards - No information available SECTION 12: Ecological information 12.1 Toxicity - Hazardous Material: Propan-2-ol; isopropyl alcohol; isopropanol - LC₅₀ (golden orfe (Leuciscus idus)): >100 mg/l (48 hr) - EC₅₀ (Daphnia magna): >100 mg/l (48 hr) - EC50 (algae) >100 mg/l (72 hr) 12.2 Persistence and degradability - Biodegradable 12.3 Bioaccumulative potential - Bioaccumulation is insignificant 12.4 Mobility in soil - miscible with water 12.5 Results of PBT and vPvB assessment - Not a PBT according to REACH Annex XIII 12.6 Endocrine disrupting properties 12.7 Other adverse effects - No information available SECTION 13: Disposal considerations 13.1 Waste treatment methods - Dispose of this material and its container at hazardous or special waste collection point - Disposal should be in accordance with local, state or national legislation SECTION 14: Transport information 14.1 UN number or ID number - UN No.: 1219 14.2 UN proper shipping name Datasheet Number: 070 - v12.2.0 6 SECTION 14: Transport information (....) - Proper Shipping Name: ISOPROPANOL (ISOPROPYL ALCOHOL SOLUTION) 14.3 Transport hazard class(es) - Hazard Class: 3 - ADR Hazard Class: 3 - ADR Classification Code: F1 - IMDG Hazard Class: 3 14.4 Packing group - Packing Group: II 14.5 Environmental hazards - On available data, substance is not harmful to the environment 14.6 Special precautions for user - Limited Quantity 1L - IMDG EmS: F-E, S-D - Tunnel Code: D/E 14.7 Maritime transport in bulk according to IMO instruments - No information available SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture - This Safety Data Sheet is provided in compliance with the EC Regulation 1907/2006- 2015/830 - and CLP (Regulation 1272/2008) 15.2 Chemical safety assessment - A chemical safety assessment (CSA) for this product has not yet been completed SECTION 16: Other information Text not given with phrase codes where they are used elsewhere in this safety data sheet:- H225: Highly flammable liquid and vapour. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. Legal Disclaimer - The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. --- end of safety datasheet --- Datasheet Number: 070 - v12.2.0 7