G1969-85003

Hazard statements (CLP)

H225, H302, H302+H312+H332, H312, H319, H332

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]]

Product definition

1.0 M Ammonium Mixture formate in deionized, nanopure water 5mM Purine in Mixture Acetonitrile Solution 0.5 mM Tris Mixture (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Mixture Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Mixture 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Mixture 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Mixture 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

CLP CLASSIFICATION

5mM Purine in Acetonitrile Solution H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 0.5 mM Tris (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 0.1 mM Hexamethoxyphosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 0.2 mM Hexakis(1H,1H,4H- hexafluorobutyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 0.2 mM Hexakis(1H,1H,6H- decafluorohexyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 0.5 mM Hexakis(1H,1H,8H- tetradecafluorooctyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2 Ingredients of unknown : 1.0 M Ammonium formate Percentage of the mixture consisting of ingredient(s) of toxicity in deionized, nanopure unknown acute dermal toxicity: 1 - 10% water Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 1 - 10% Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity: 1 - 10%

Ingredients of unknown ecotoxicity

1.0 M Ammonium formate Percentage of the mixture consisting of ingredient(s) of in deionized, nanopure unknown hazards to the aquatic environment: 6.3% water See Section 16 for the full text of the H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

Hazard pictograms

5mM Purine in Acetonitrile Solution 0.5 mM Tris (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Signal word

1.0 M Ammonium No signal word. formate in deionized, nanopure water 5mM Purine in Danger Acetonitrile Solution 0.5 mM Tris Danger (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Danger Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Danger 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Danger 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Danger 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazard statements

1.0 M Ammonium No known significant effects or critical hazards. formate in deionized, nanopure water 5mM Purine in H225 - Highly flammable liquid and vapour. Acetonitrile Solution H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Tris H225 - Highly flammable liquid and vapour. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.1 mM H225 - Highly flammable liquid and vapour. Hexamethoxyphosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 4H-hexafluorobutyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 6H-decafluorohexyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation.

Prevention

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P280 - Wear protective gloves. Wear protective clothing. Acetonitrile Solution Wear eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 0.5 mM Tris P280 - Wear protective gloves. Wear protective clothing. (2,4,6-trifluoromethyl) Wear eye or face protection. -1,3,5 triazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 0.1 mM P280 - Wear protective gloves. Wear protective clothing. Hexamethoxyphosphazine Wear eye or face protection. in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 0.2 mM Hexakis(1H,1H, P280 - Wear protective gloves. Wear protective clothing. 4H-hexafluorobutyloxy) Wear eye or face protection. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 0.2 mM Hexakis(1H,1H, P280 - Wear protective gloves. Wear protective clothing. 6H-decafluorohexyloxy) Wear eye or face protection. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 0.5 mM Hexakis(1H,1H, P280 - Wear protective gloves. Wear protective clothing. 8H- Wear eye or face protection. tetradecafluorooctyloxy) phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Response

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P304 + P340 - IF INHALED: Remove person to fresh air and Acetonitrile Solution keep comfortable for breathing. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. 0.5 mM Tris P304 + P340 - IF INHALED: Remove person to fresh air and (2,4,6-trifluoromethyl) keep comfortable for breathing. -1,3,5 triazine in acetonitrile P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. 0.1 mM P304 + P340 - IF INHALED: Remove person to fresh air and Hexamethoxyphosphazine keep comfortable for breathing. in acetonitrile P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. 0.2 mM Hexakis(1H,1H, P304 + P340 - IF INHALED: Remove person to fresh air and 4H-hexafluorobutyloxy) keep comfortable for breathing. phosphazine in acetonitrile P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. 0.2 mM Hexakis(1H,1H, P304 + P340 - IF INHALED: Remove person to fresh air and 6H-decafluorohexyloxy) keep comfortable for breathing. phosphazine in acetonitrile P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. 0.5 mM Hexakis(1H,1H, P304 + P340 - IF INHALED: Remove person to fresh air and 8H- keep comfortable for breathing. tetradecafluorooctyloxy) phosphazine in acetonitrile P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.

Storage

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Disposal

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P501 - Dispose of contents and container in accordance Acetonitrile Solution with all local, regional, national and international regulations. 0.5 mM Tris P501 - Dispose of contents and container in accordance (2,4,6-trifluoromethyl) with all local, regional, national and international regulations. -1,3,5 triazine in acetonitrile 0.1 mM P501 - Dispose of contents and container in accordance Hexamethoxyphosphazine with all local, regional, national and international regulations. in acetonitrile 0.2 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 4H-hexafluorobutyloxy) with all local, regional, national and international regulations. phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 6H-decafluorohexyloxy) with all local, regional, national and international regulations. phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 8H- with all local, regional, national and international regulations. tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazardous Ingredients

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in - acetonitrile Acetonitrile Solution 0.5 mM Tris - acetonitrile (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM - acetonitrile Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, - acetonitrile 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, - acetonitrile 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, - acetonitrile 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Supplemental label elements

1.0 M Ammonium Safety data sheet available on request. elements formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile Annex XVII - Restrictions : 1.0 M Ammonium Not applicable. on the manufacture, formate in deionized, placing on the market nanopure water and use of certain 5mM Purine in Not applicable. dangerous substances, Acetonitrile Solution mixtures and articles 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Special packaging requirements

Tactile warning of 1.0 M Ammonium Not applicable. danger formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

2.3 Other hazards

Product meets the : 1.0 M Ammonium This mixture does not contain any substances that are criteria for PBT or vPvB formate in deionized, assessed to be a PBT or a vPvB. according to nanopure water Regulation (EC) No. 5mM Purine in This mixture does not contain any substances that are 1907/2006, Annex XIII Acetonitrile Solution assessed to be a PBT or a vPvB. 0.5 mM Tris This mixture does not contain any substances that are (2,4,6-trifluoromethyl) assessed to be a PBT or a vPvB. -1,3,5 triazine in acetonitrile 0.1 mM This mixture does not contain any substances that are Hexamethoxyphosphazine assessed to be a PBT or a vPvB. in acetonitrile 0.2 mM Hexakis(1H,1H, This mixture does not contain any substances that are 4H-hexafluorobutyloxy) assessed to be a PBT or a vPvB. phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, This mixture does not contain any substances that are 6H-decafluorohexyloxy) assessed to be a PBT or a vPvB. phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, This mixture does not contain any substances that are 8H- assessed to be a PBT or a vPvB. tetradecafluorooctyloxy) phosphazine in acetonitrile Other hazards which do : 1.0 M Ammonium None known. not result in formate in deionized,

2.1 Classification of the substance or mixture

nanopure water 5mM Purine in None known. Acetonitrile Solution 0.5 mM Tris None known. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM None known. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, None known. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, None known. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, None known. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile